排序方式: 共有217条查询结果,搜索用时 16 毫秒
71.
The title compound mesityl acetic acid 3-mesityl-2-oxo-1-oxaspiro[4,4]non-3-en-4-yl ester (5, C28H32O4, Mr = 432.56), as a spiromesifen derivative, has been synthesized by the conden- sation reaction of 2,4,6-trimethylphenylacetic chloride with 4-hydroxyl-3-mesityl-1-oxa-spiro[4,4]- non-3-en-2-one (4), and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group P1 with a = 7.9261(7), b = 8.2802(8), c = 18.7604(18) , α = 91.576(3), β = 93.277(2), γ = 95.306(12)o, V = 1223.3(2) 3, Z = 2, Dc = 1.174 g/cm3, F(000) = 464, μ = 0.077 mm-1, S = 1.001, the final R = 0.0624 and wR = 0.1415 for 2809 observed reflections with I 2σ(I) and 290 variable parameters. The crystal analysis results show that the five-membered cyclopentyl ring displays an envelope conformation with C(25) atom at the flap position, 0.537(3) out of the mean plane formed by the other four atoms. The dihedral angles between the two benzene and furan rings are 70.0(2) and 80.67(3)o, respectively. 相似文献
72.
A novel 1-D iodoplumbate hybrid,2(Pb3I9)3-·3(C14H18N2)2+ 1,has been hydrothermally synthesized and characterized by IR spectra,TGA and single-crystal X-ray diffraction.Complex 1 crystallizes in monoclinic,space group P21/c,with a=12.057(2),b=14.024(3),c=24.742(5) ,β=90.48(3)°,V=4183.6(14)3,Z=4,R=0.0477 and wR=0.0800.The title compound consists of 1-D chains(Pb3I9)n3n-parallel to the [100] direction and stacks of alkylated 4,4'-bipyridium cations running along the [011] direction.Each anionic chain is surrounded by six arrays of alkylated 4,4'-bipyridium cations through extensive C-H…I atypical hydrogen-bonding interactions to afford an interesting 3-D supramolecular network.Significant fluorescent property of the compound was observed at room temperature. 相似文献
73.
The title compound 2-(spirobifluorene-2-yl)-3,4-diaza-spirobifluorene(C48H28N2,Mr = 632.72) has been synthesized and characterized by 1H NMR,13C NMR and single-crystal X-ray diffraction.The crystal crystallizes in the monoclinic system,space group Cc with a = 13.8523(6),b = 29.3297(13),c = 8.6397(4) ,β = 111.8760(10)°,V = 3257.4(3) 3,Z = 4,Dc = 1.290 mg/m3,μ = 0.075 mm-1,F(000) = 1320,the final R = 0.0425 and wR = 0.1110 for 5288 observed reflections(Ⅰ 2σ(Ⅰ)). 相似文献
74.
The title compound 10-(4,5-dibenzylthio-1,3-dithiol-2-ylidene)anthracen-9(10H)- one (C31H22OS4) has been synthesized, and its crystal structure was prepared by crystallization from CH2Cl2-MeOH. The crystal belongs to the triclinic system, space group Pi with a = 10.9758(3), b = 11.4241(4), c = 11.7460(2)A^°, α = 62.379(2), β = 81.227(3), γ = 80.321(2)°, Mr = 538.73, V = 1281.69(7) A^°^3, Z = 2, Dc = 1.396 g/cm^3, F(000) = 560,μ = 0.395 mm^-1, the final R = 0.0291 and wR = 0.0739. The molecular structure is severely distorted from planarity. The central ring of anthraquinone moiety adopts a boat conformation, while the two outer benzene rings are tilted in the opposite direction to form a dihedral angle of 23.65°. The photocurrent generation was measured and an anodic photocurrent response was obtained. The electronic spectrum was studied by using TDDFr method on the basis of optimized geometries with B3LYP method. The obtained results are in good agreement with the experimental values. 相似文献
75.
The title compound 3-(2,4-dichlorophenyl)-4-dydroxy-3-(2,4-dichlorophenyl)-4- dydroxy-5-cyclohexanyl-A3-dihydrofuran-2-one 5 has been synthesized by the cyclization of methyl O-(2,4-dichlorophenyl-acetyl)-1-hydroxycyclo-hexane-carboxylate 4, and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group Pi with a = 6.8192(3), b = 10.5053(5), c = 10.5811(5)A,α = 71.681(10), β = 78.905(12), γ = 81.036(12)°, C15H14C1203, Mr = 313.18, V= 702.44(6)A3, Z = 2, De= 1.481 g/cm^3, F(000) = 324,μ = 0.465 mm^-1, S = 1.006, the final R = 0.0331 and wR = 0.1363 for 2505 observed reflections with I 〉 2σ(I) and 183 variable parameters. The crystal analysis shows that the cyclohexene unit of the title compound has a quasi-chair conformation, and a one-dimensional chain structure is formed via the intermolecular hydrogen bond O(1)-H(101)…O(2). 相似文献
76.
Synthesis and Crystal Structure of 2,6-Bis(benzimidazo(1,2-c)- quinazolin-6-yl)pyridine Tetrahydrate
The title compound, 2,6-bis(benzimidazo(1,2-c)quinazolin-6-yl)pyridine tetrahydrate, was synthesized by simple condensation of 2-(2-sminophenyl) benzimidazole with pyfidine- 2,6-dicarboxylic acid and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2/c with a = 22.226(8), b = 16.730(7), c = 16.820(5)A, β = 115.796(13)°, V = 5631(4)A^3, C33H27NTO4, Mr = 585.62, Z = 8, Dc = 1.381 g/cm^3, λ(MoKα) = 0.71073 A, F(000) = 2448 and μ = 0.09 mm^-1. The structure was refined to the final R = 0.0730 and wR = 0.1573 for 6346 independent reflections (Rint = 0.0801) and 3384 observed reflections (I 〉 2σ(I)). In the crystal, the molecules are linked through intermolecular O-H…O and O-H…N hydrogen bonds. Intermolecular π-π interactions (with distances of about 3.45 A) are pronounced in the crystal structure. 相似文献
77.
SONG Xiu-Mei WANG Zhao-Yang MO Yang-Qing MAO Zheng-Zhou 《结构化学》2009,(5):537-540
The title compound, N,N'-bis-[3-chloro-5-S-(l-menthyloxy)-2(5H)-4-furanon-yl]- propane-l,3-diamine (C31H48Cl2N2O6, Mr = 615.61), has been synthesized and characterized by IR, 1H NMR, MS, elemental analysis and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group C2 with a = 16.1091(4), b = 11.1880(3), c = 19.2854(5) A, β = 106.297(2)°, V = 3336.12(15) A3, Z = 4, Dc = 1.226 mg/m3,μ = 0.237 mm^-1, F(000) = 1320, the final R = 0.0531 and wR = 0.0700 for 2760 observed reflections (I 〉 2σ(I)). X-ray analysis reveals that the title compound possesses four rings: two chiral five-membered furanone rings and two six-membered cyclohexane rings with chair conformation, containing eight chiral centers: C2(S), C3(R), C5(R), C10(S), C18(S), C21(R), C22(S) and C25(R). The structure is stabilized by N-H…O hydrogen bonding interaction. 相似文献
78.
HUANG Hua-Ming BIAN Xiu-Zhu DU Qiao-Yun 《结构化学》2009,(7):859-863
A novel ionic compound [Fe(CN)6·(PhCHeNC9H7)4]·12H2O
(C70H80FeN10O12, Mr = 1309.29) has been synthesized and its structure was characterized by I-R, elemental analysis and X-ray diffraction. The compound crystaUizes in triclinic, space group P1, with a = 10.968(7), b = 11.466(7), c = 14.077(8)A, α= 87.014(7), β= 78.124(7), γ = 72.708(7)°, V = 1654.1(17)A3, Z = 1, Dc = 1.314 g·cm^-3, F(000) = 692, p = 0.298 mm^-1, the final R = 0.0519 and wR = 0.1355. The building unit of the title compound consists of four (PhCH2N+C9H7) ions, one [Fe(CN)6]4- anion, and a dozen water molecules. According to the structural analysis, [Fe(CN)6]4- ions are linked together by O-H…O and O-H…N hydrogen bonds, while (PhCH2N+C9HT) and [Fe(CN)6]4- ions interact with each other by electrostatic force to form an ionic compound. 相似文献
(C70H80FeN10O12, Mr = 1309.29) has been synthesized and its structure was characterized by I-R, elemental analysis and X-ray diffraction. The compound crystaUizes in triclinic, space group P1, with a = 10.968(7), b = 11.466(7), c = 14.077(8)A, α= 87.014(7), β= 78.124(7), γ = 72.708(7)°, V = 1654.1(17)A3, Z = 1, Dc = 1.314 g·cm^-3, F(000) = 692, p = 0.298 mm^-1, the final R = 0.0519 and wR = 0.1355. The building unit of the title compound consists of four (PhCH2N+C9H7) ions, one [Fe(CN)6]4- anion, and a dozen water molecules. According to the structural analysis, [Fe(CN)6]4- ions are linked together by O-H…O and O-H…N hydrogen bonds, while (PhCH2N+C9HT) and [Fe(CN)6]4- ions interact with each other by electrostatic force to form an ionic compound. 相似文献
79.
80.
《宁波大学学报(理工版)》2016,(4):135
正本刊是宁波大学主办的综合性自然科学和工程技术学术期刊,创刊于1988年,现为季刊,国内外公开发行,主要刊登理、工、农、林、医等学科的学术论文和研究成果,欢迎各方学人来稿.1投稿要求1.1文稿书写要求:文章论点明确、论据充分、层次分明,文字简练,图表清晰,篇幅(含图表)一般不超过6000字.1.2文稿书写顺序:中文标题;作者姓名;作者单位;中文摘要(要有目的、方法、结果、结论 4要素内容,200字左右);中文关键词(3~5个,用分号隔开);中图分类号(按《中国图书馆分类法》(第4版)标引);正文;附录(非必有);参考文 相似文献