表面增强电输运:研究C60-金属相互作用的一个新尝试

通过在超薄金属层上蒸镀C_(68)时的电阻原位测量,发现在平均厚度约一个C_(68)单层范围内样品电阻有明显可观测的变化,主要表现为电导增强,电阻变化的程度与金属层厚度有关,最多近一个数量级。这一新的现象揭示出有可能利用宏观物理性质测量来间接研究C_(68)-金属界面相互作用,从而对常规喇曼谱和各种电子谱测量的结果给出旁证和补充。 关键词：     

中能重离子碰撞中的涨落和中间质量碎片发射的机制

在QMD模型的基础上,系统研究了⁴⁰Ca+⁴⁰Ca中心碰撞系统的中间质量碎片随能量和时间的演化以及它们的动力学起源.集中讨论了反应机制的跃迁,动力学过程中密度涨落和平均中间质量碎片的关系以及碎裂的时间尺度.发现中间质量碎片随能量的上升和下降伴随着涨落的上升和下降.并预言对所研究的反应,当入射能量为65MeV/u时,彻底解体可能发生.碎裂的时间尺度大约为140fm/c,且随能量的增大,此时间尺度不再减小,达到饱和.     

关于HADAMARD不等式的注记

本文主要研究一类Ｆ－矩阵的性质，这类矩阵包含对称半正定矩阵，完全非负矩阵，τ矩阵和Ｍ－矩阵为其子类。我们不仅对Ｆ－矩阵改进了Ｈｄａｍａｒｄ不等式，而且证明对此类矩阵Ｈａｄａｍａｒｄ不等式成立等式的充要条件是它的每条对角线，除主对角线外，都含有零元。     

CRYSTALLOGRAPHIC STRUCTURE AND MAGNETIC PROPERTIES OF R_(2)Fe_(17)N_(2.4)

By a proper thermal treatment, the nitrogen atoms can enter the R2Fe17 structure. The crystallographic and intrinsic magnetic properties as well as their relationship have been studied by magnetic measurements, X-ray and neutron diffraction techniques. The neutron data indicate that the nitrogen atoms occupy the interstitial sites in the Th2Zn17-type rhom-bohedral structure. The inserting nitrogen atoms are found to dilate the cell volume, increase the Curie temperature and enhance the saturation moment by raising the difference in the electron number between the spin-up and spin-down 3d subbands of the Fe atoms. Furthermore, the nitrogen atoms have an important effect on the magnetocrystallic anisotropy, which results in an easy axis with Sm2Fe17N2.4. All these make Sm2Fe17N2.4 favorable for permanent magnet applications.     

Structural and electrical properties of SrTiO3 thin films as insulator of metal-ferroelectric-insulator-semiconductor （MFIS） structures

SrTiO₃ (STO) thin films were deposited on p-Si(100) substrates at various substrate temperatures from 300℃ to 700℃ by radio frequency (RF) magnetron sputtering technique. Their structure and electrical properties were investigated. It was found that the transition from amorphous phase to polycrystalline phase occurred at the substrate temperatures 300--400℃. Their crystallinity became better when the substrate temperatures further increased. The dielectric and leakage current measurements were carried out by using the Si/STO/Pt metal--insulator--semiconductor (MIS) structures at room temperature. It was found that the fixed charge density decreased and both the interface trap density and the dielectric constant increased when the substrate temperatures were increased. The leakage current mechanisms for STO MIS structures with STO films prepared at 700℃ followed the space charge limited current (SCLC) under the low applied electric field and the Poole--Frenkel emission under the high one. In addition, the resistivity for films prepared at 700℃ was higher than 10¹¹\Omega \cdot cm under the voltage lower than 10V (corresponding to the electric field of 1.54\times 10³kV\cdotcm^-1). It suggested that the STO films prepared at 700℃ were suitable for acting as the insulator of metal--ferroelectric--insulator--semiconductor (MFIS) structures.     

蚕丝蛋白的NMR研究Ⅱ.桑、柞蚕丝及其丝素的13C CP-MAS NMR研究

本文在Bruker AC-250和MSL-400谱仪上,首次测试了河南桑蚕茧、丝素及柞蚕黄茧、人工白茧和丝素的固态¹³C CP MAS NMR谱,归属了¹³C NMR谱线,并揭示了白茧和黄茧二级结构的差异。     

基于谱分析的数值内插快速算法

给出一个基于频谱分析的数据插值快速算法 ,应用该算法实现了对一维的硅烷射频辉光放电等离子体中质谱信号的数据和对二维的托卡马克小截面磁面网格数据的快速内插。     

维生素B12模型分子侧链钴-氮键稳定性研究

维生素B12(VB12)模型分子[单腈六甲基-N-(3-咪唑基)丙酰胺钴啉酯高氯酸盐4b-4f],在甲醇溶液中用酸性缓冲溶液处理生成5b-5f.通过测定不同pH的缓冲溶液中的UV-Vis谱,计算了Co-N键的平衡常数,侧链氮原子与中心钴离子配位键的强弱次序为4d＞4f＞4c＞4e＞4b.