改性磺化聚醚醚酮用作直接甲醇燃料电池聚合物电解质膜

1引言 聚合物电解质膜燃料电池(Polymer electrolyte membranefuel cell,PEMFC)是一种能直接将燃料和氧化剂中的11化学能转化为电能的电化学装置,具有能量转换效率高、环境友好、比能量高(相对于电池)、操作温度低、启动快的特点,可广泛应用于汽车、电站、移动电源等领域[1-4].     

La-Fe基NaZn13型化合物的磁场诱导熵变研究

围绕具有一级磁性相变的La-Fe基NaZn13型化合物的磁场诱导熵变研究,从室温磁制冷目的出发讨论了材料研究和熵变机制。La-Fe-Si在190K附近5T磁场下的熵变值可达29J.kg-1.K-1。用少量Co替代Fe,可以获得室温附近5T磁场下熵变为15J.kg-1.K-1的大熵变材料。这类材料中的熵变主要由磁有序熵变和晶格熵变组成。分析了一级磁性相变体系中磁有序熵变和晶格熵变对总熵变的贡献,并发现大的熵变来源于被晶格贡献抵消后的磁有序熵变。     

一类巴西列维奇函数的Fekete—Szegoe问题

本我们引入了一类巴西列维奇函数,讨论了该类函数上的Ｆｅｋｅｔｅ－Ｓｚｅｇｏｅ问题,所获得的结论是准确的。一些已知的结论是本的特例。     

快淬Nd3.6Pr5.4Fe83Co3B5薄带的反磁化行为和磁黏滞性

用电弧熔炼法制备了Nd_3.6Pr_5.4Fe₈₃Co₃B₅合金铸锭,然后利用熔旋快淬法在铜辊转速V=20m/s下制备了Nd_3.6Pr_5.4Fe₈₃Co₃B₅薄带.快淬带主要由软磁相α-Fe和Nd₂Fe₁₄B型的硬磁相组成.采用直流退磁剩磁曲线方法分析了样品在反磁化过程中的可逆与不可逆磁化部分,并研究了软磁相和硬磁相的反磁化行为,得到样品的不可逆磁化形核场H_no约为440kA/m.同时研究了样品的磁黏滞性,结果表明由于软磁相的存在使得热激活体积较大. 关键词：     

光滑流形的迹上的W^m,p（Ω）嵌入定理

本文讨论了将嵌入定理推广到光滑流形的迹上去,并证有了强局部Lipschitz性质下的嵌入定理.     

Magnetic entropy change and magnetic phase transition of LaFe11.4Al1.6Cx （x=0-0.8） compounds

The unit cell volume and phase transition temperature of LaFe11.4Al1.6Cx compounds have been studied. The magnetic entropy change, refrigerant capacity and the type of magnetic phase transition are investigated in detail for LaFe11.4Al1.6Cx with x=0.1, All the LaFe11.4Al1.6Cx （x=0-0.8） compounds have the cubic NaZn13-type structure. The addition of carbon atoms brings about a considerable increase in the lattice parameter. The bulk expansion results in the change of phase transition temperature （Tc）, Tc increases from 187K to 269 K with x varying from 0.1 to 0.8, Meanwhile an increase in the lattice parameter can also cause a change of the magnetic ground state from antiferromagnetic to ferromagnetic. Large magnetic entropy change IASI is found over a large temperature range around Tc and the refrigerant capacity is about 322J/kg for LaFe11.4Al1.6C0.1. The magnetic phase transition belongs in weakly first-order one for x=0.1.     

一类优化控制问题的有限元解的误差估计和超收敛

对积分微分方程的优化控制问题进行了介绍.讨论了积分微分方程的优化控制问题的混合有限元逼近,给出了优化控制问题的有限元逼近解的误差估计和超收敛性质.     

具动力边界条件的半线性Kirchhoff方程整体解的不存在性

利用凸性方法得到了具动力边界条件的半线性Kirchhoff方程整体解的不存在性.     

大型稀疏无约束优化的分划组修正算法

1 引言我们考虑求解无约束优化问题 (1) 其中f:Rn→R二次连续可微．f(x)的Hesse阵H(x)稀疏．为了求解问题(1),我们考虑下列Newton型方法     

Effect of composition on texture and magnetic the crystallographic properties of the Sm（Co,Fe,Cu,Zr）z ribbons prepared by simple processing

Sm(Co_balFe_yCu_xZr_w)_z ribbons have been prepared by melt spinning at a low wheel velocity followed by short-time aging and slow cooling the as-spun ribbons from 850 to 400℃. It is found that the composition can significantly influence the degree of crystallographic texture of the ribbons. The 1:7 phase of the as-spun ribbons is segregated into 1:5 and 2:17 phases by the simple processing procedure. However, the crystallographic texture is still preserved in the ribbons after precipitation hardening. (BH)_{\rm max} about 86kJ/m^{3} can be obtained in the Sm(Co, Fe, Cu, Zr)_{z} ribbons by the adjustment of composition.