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51.
Orhan Destanoğlu 《液相色谱法及相关技术杂志》2016,39(9):465-474
The first aim of this study was to develop a selective, sensitive, and reliable method for direct simultaneous determination of cyanate, thiocyanate, and hexavalent chromium by ion chromatography (IC) with conductivity detection. The other target was to successfully determine cyanides by utilizing same chromatographic system. Yet, since cyanides can not be detected by the direct method, free cyanide ions were converted into cyanate with chloramine-T at alkaline pH. In addition, strongly complexed metal cyanides were converted into cyanate by using photo-oxidation following chloramine-T. Total cyanate ion obtained from developed methods were analyzed with IC. The chromatographic separations on anion exchange column were accomplished by optimized multistep gradient eluent program using NaOH as the eluent. Proposed method was applied for the simultaneous determination of cyanide and hexavalent chromium in electroplating bath solutions and in industrial wastewater. Cyanide and hexavalent chromium could be measured in the linear dynamic ranges of 0.6–961.5 and 0.9–118.5 µmol L?1, respectively. The limit of detection and limit of quantification of cyanide were 0.18 and 0.61 µmol L?1, and these values for chromium(VI) were 0.26 and 0.86 µmol L?1, respectively. 相似文献
52.
TaiBao Wei Hui Li QingQing Wang GuoTao Yan YuanRong Zhu TaoTao Lu 《Supramolecular chemistry》2016,28(3-4):314-320
A simple Schiff base sensor (L1) derived from N-(1-naphthyl) ethylenediamine dihydrochloride was designed and synthesised by simple chemistry procedures. The sensor exhibited a visible colour change observed by both colorimetric and fluorimetric responses for cyanide ion in aqueous solution. The detection of cyanide was performed via the nucleophilic attack of cyanide anion on the imine group of the sensor with a 1?:?1 binding stoichiometry. Moreover, test strips based on the sensor were fabricated, which served as convenient and efficient CN? test kits and the sensor L1 is a good way to detect hydrogen cyanide in aqueous extracts of sprouting potatoes. 相似文献
53.
Either to sustain autotrophy, or as a prelude to heterotrophy, organic synthesis from an environmentally available C1 feedstock molecule is crucial to the origin of life. Recent findings augment key literature results and suggest that hydrogen cyanide—“Blausäure”—was that feedstock. 相似文献
54.
Dr. Jonathan Rittle Prof. Jonas C. Peters 《Angewandte Chemie (International ed. in English)》2016,55(40):12262-12265
Nitrogenase enzymes mediate the six‐electron reductive cleavage of cyanide to CH4 and NH3. Herein we demonstrate for the first time the liberation of CH4 and NH3 from a well‐defined iron cyanide coordination complex, [SiPiPr3]Fe(CN) (where [SiPiPr3] represents a tris(phosphine)silyl ligand), on exposure to proton and electron equivalents. [SiPiPr3]Fe(CN) additionally serves as a useful entry point to rare examples of terminally‐bound Fe(CNH) and Fe(CNH2) species that, in accord with preliminary mechanistic studies, are plausible intermediates of the cyanide reductive protonation to generate CH4 and NH3. Comparative studies with a related [SiPiPr3]Fe(CNMe2) complex suggests the possibility of multiple, competing mechanisms for cyanide activation and reduction. 相似文献
55.
Dr. Kuirun Zhang Dr. Soonchul Kang Dr. Zi‐shuo Yao Kazusa Nakamura Dr. Takashi Yamamoto Prof. Dr. Yasuaki Einaga Nobuaki Azuma Dr. Yuji Miyazaki Prof. Dr. Motohiro Nakano Dr. Shinji Kanegawa Prof. Dr. Osamu Sato 《Angewandte Chemie (International ed. in English)》2016,55(20):6047-6050
Heterometallic Prussian blue analogues are known to exhibit thermally induced charge transfer, resulting in switching of optical and magnetic properties. However, charge‐transfer phase transitions have not been reported for the simplest FeFe cyanide‐bridged systems. A mixed‐valence FeII/FeIII cyanide‐bridged coordination polymer, {[Fe(Tp)(CN)3]2Fe(bpe)?5 H2O}n, which demonstrates a thermally induced charge‐transfer phase transition, is described. As a result of the charge transfer during this phase transition, the high‐spin state of the whole system does not change to a low‐spin state. This result is in contrast to FeCo cyanide‐bridged systems that exhibit charge‐transfer‐induced spin transitions. 相似文献
56.
57.
Herewith are the two processes developed by Nitto, which produce N-containing compounds such as hydrogen cyanide and methylamines. These processes are characterized by unique selective catalysts: an Fe–Sb–O based fluid-bed catalyst for ammoxidation of methanol and a shape-selective zeolite catalyst for ammonolysis of methanol. 相似文献
58.
Jan Philipp Hofmann 《Journal of Molecular Spectroscopy》2010,262(2):75-81
The emission spectrum of H13CN at 1370 K has been recorded with a hot gas high resolution FT-IR emission apparatus [1] in the wavenumber region of with a resolution of . This work reports the analysis of 50 subbands for the H13CN isotopologue of hydrogen cyanide in the 2ν1 wavenumber region. 23 rovibronic states of H13CN including the rovibronic states at have been characterized for the first time and for seven other states it was possible to improve the existing spectroscopic constants substantially. The dense emission spectrum was analyzed with the spectrum analysis software SyMath™ implemented in the Mathematica™ computer algebra system [1]. 相似文献
59.
《Analytical letters》2012,45(14):2797-2803
Abstract A rapid, simple and sensitive fluorimetric method has been developed for the determination of cyanide with fluorescein as fluorogenic reagent (λex = 494 nm, λem = 514 nm) at pH 6.0–7.0. A linear calibration curve was obtained in the range 0.004–2.0 μg CN?/25 ml. The detection limit is 0.004 μg CN-/25 ml. The method was successfully applied to the determination of cyanide in waste water. 相似文献
60.
《Analytical letters》2012,45(9):2075-2082
Abstract A spectrophotometric method for nickel has been developed based on the formation of a ternary complex in the system Ni(II)/3-(4′,5′-dimethyl-2′-thiazolylazo)-2,6-dihydroxybenzoic acid/cyanide at pH 9.2 (borate buffer), which allows the determination of 0.05–0.47ppm of nickel (ε = 3.53×104 1.mol?1. cm?1) at 538nm. Interferences have been studied and the method applied to the determination of nickel in low alloy steels. 相似文献