Syntheses, Crystal Structures and Properties of Two Supramolecules Assembled from Weak Interactions

Two complexes, [Cu2(Htdb)4(H2O)2] (1) and [Cd(bipy)2(Hmcmbc)2] (2) (H2tdb = 2,2-thiodibenzoic acid, H2mcmbc = m-(carboxyl-methyloxy)-benzenecarboxylic acid, bipy = 4,4'-bipyridine), have been prepared, and were characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. Structures indicate that complex 1 is a single molecule, and 2 is a one-dimensional chain. Their two-and three-dimensional frameworks are constructed through hydrogen bonding, π…π or C–H…π stacking, and such other weak interactions. The cyclic voltametric behavior of complex 1 and luminescence property of complex 2 were investigated. 1 belongs to the triclinic system, space group P with a = 7.8607(6), b = 11.7619(9), c = 15.3481(12) , α = 109.3670(10), β = 92.4420(10), γ = 92.0450(10)°, V = 1335.65(18) 3, Mr = 1256.26, Dc = 1.5619(2) g/cm3, F(000) = 642, μ = 1.029 mm–1, Z = 1, the final R = 0.0289 and wR = 0.0763 for 5199 observed reflections with I > 2σ(I). Complex 2 crystallizes in triclinic, space group P with a = 9.6378(10), b = 9.7508(10), c = 19.055(2) , α = 88.7020(10), β = 80.5260(10), γ = 69.2000(10)o, V = 1649.9(3) 3, Mr = 815.07, Dc = 1.641 g/cm3, μ = 0.732 mm-1, F(000) = 828, Z = 2, the final R = 0.0511 and wR = 0.1149 for 4729 observed reflections (I > 2σ(I)).     

一种考虑剪切变形的平行四边形厚/薄板通用单元

根据Timoshenko二广义位移梁理论，构造了深梁位移场的插值函数。利用斜坐标系与直角坐标系的变换关系、有限条带思想和深梁位移插值函数，构造了一种考虑剪切变形的平行四边形厚／薄板弯曲通用单元的位移(曲率、剪应变、转角、横向位移)插值函数，导出了刚度矩阵和非结点荷载等效力。并对简支阍支方板、Razzaque斜板、四边简支斜交板弯曲进行了数值计算。算例表明此单元有较好的精度，对于薄板不出现剪切闭锁，可适应于目前桥梁建设中大量采用的斜交板桥结构分析。     

压不弯杆件的室内模拟试验及其应用前景

本文根据对压杆的理论分析，提出一种改变加压方式的压不弯细长杆件，其结论已通过室内模拟试验得到证实．这一思路可成为压不弯钻铤结构设计的基础．     

聚四氟乙烯对齿轮润滑成膜膏润滑性能的影响

作者以聚四氟乙烯(PTFE)为固体润滑剂填料对GM型齿轮润滑成膜膏进行了改进,并且研制出了两种新的成膜膏系列产品。经四球试验机、动静摩擦系数精密测定仪和SRV试验机评价的结果表明,添加PTFE的GM-2型成膜膏的承载能力和减磨性能都明显地比未添加的好;以PTFE为主要固体润滑剂填料的GM-3和MFC-1型两种润滑成膜膏也都具有良好的润滑性能,其中后者的性能与含PTFE的GM-2型成膜膏的接近。通过对摩擦轨迹的电子探针检测发现,PTFE在摩擦过程中于摩擦表面形成了转移膜,因而改善了润滑成膜膏的摩擦学性能。     

Piecewise analysis of oblique vibro-impacting systems

A great number of studies have shown the complex nonlinear dynamics of mechanical systems with repeated normal impacts. An oblique frictional impact introduces even more complicated dynamics such as stick-slip motions to those systems. Hence, the dynamics of oblique vibro-impacting systems with possible sliding motion is an open problem. Based on a hybrid analysis of vibro-impact dynamics, kinematics and complementary conditions, a piecewise analysis method is developed in the paper to describe the sliding motion during an oblique impact. Thereby, a parametrically excited planar pendulum between two parallel rigid walls is studied as an illustrative example. The example, together with the corresponding numerical results, shows that the sliding impacts occur in such a system with a set of properly selected parameters. The project supported by the National Natural Science Foundation of China (59905010) and by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education, China     

斜入射激光超声体波声场的实验研究

为研究微烧蚀状态下圆形光斑斜入射时激光超声声场的指向性,使用脉冲激光辐照半圆柱形铝质工件表面,并使用压电探头和电磁超声探头分别接收纵波和横波信号。根据速度参数确定了超声信号的类型,提取了信号的峰-峰值,并绘制出声场指向性曲线。通过分析获得以下结论:激光斜入射角度在0~60°范围内变化时,纵波声场的声束轴线方向保持不变,且与工件内法线平行;另外,横波声场的峰-峰值仍然在±35°的方向上取最大值,但是横波指向图形的主瓣易受激光入射方向的影响,当倾斜角度大于等于45°时,横波主瓣的范围变得较宽。     

导弹发射姿态测量方法研究

针对导弹发射姿态测量问题,提出采用高速摄像机通过斜瞄和平瞄姿态测量方法求解导弹中轴线俯仰角和方位角,仿真典型导弹起飞段近距离姿态测量,分析两种测量方法对导弹飞行姿态测量精度和适用性。仿真结果表明:平瞄和斜瞄姿态测量方法,测量误差在0.2°以内。斜瞄方式使用更便捷,通用性好。平瞄方式测量精度高,数据处理方法、机械结构相对简单,在适合的应用场合优势明显。此分析方法、分析结果为姿态测量方法选取和研究等提供一种可行的途径,也可为其它运动目标的姿态测量提供借鉴。     

细长尖头刚性弹对金属靶板的斜侵彻/穿甲分析

给出细长尖头刚性弹（如尖卵、尖锥形）斜侵彻/穿甲金属靶的一个分析模型。在细长尖头弹对中厚度金属靶的斜穿甲中,韧性孔洞扩张为主要的穿甲机理;着靶初期,发生方向角的改变。研究表明,金属靶的斜穿甲仅由4个量纲一参数控制,即冲击函数I、弹体几何函数N、量纲一靶厚和撞击斜角。分析得到显式的侵彻深度、终点弹道极限、剩余速度和撞击方向改变角表达式。该模型可预期跳飞发生的临界条件。理论预期与实验结果吻合较好。     

锂蓝闪石产出的地质特征及其利用价值

锂蓝闪石是一种罕见矿物；产于花岗伟晶岩脉的外接触带，系二云母石英片岩在伟晶作用的晚期阶段，经锂－钠气水热液沿片锂交代而成，锂蓝闪石呈放射状集合体，沿片理面分布，貌如黑色菊花，形似蝴蝶，“花径”一般２￣５ｃｍ，最大可达１０ｃｍ；“花瓣”突起，边界清晰，基底为灰白色织云母石英片岩，丝绢光泽．花、底相衬，尤如印花丝绸一般，具有较高的陈列，收藏和观赏价值，现行骨灰盒多系木质或热固性塑料制品，色调暗淡，造型     

绳系小球上升最高点速度参数的设置

在高中阶段学生所学习的曲线运动中,竖直面内的圆周运动比较典型、综合的运动,其运动过程存在较多变数和不确定性.绳系小球或者单轨光滑内侧的物体在竖直面内的圆周运动,是学习圆周运动知识过程中一个难点.其中的变数和不确定性是由设置竖直面内最低点的速度大小不同所决定的.不同的速度大小就会有不同的运动过程,比如是一般的摆动、完整的圆周运动还是圆周运动与斜上抛运动结合,求解最大高度时的方法大不相同.下面通过分析例题,总结求最大高度的方法,讨论不同难易度的题目应如何设置最低点的速度大小.