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排序方式: 共有206条查询结果,搜索用时 15 毫秒
41.
在碘化亚铜、四丁基溴化铵和磷酸钾存在下,9,9-二(4-羟基苯基)呫吨(1)和4-甲基碘苯(2)于N,N-二甲基甲酰胺溶剂中发生Ullmann偶联反应,加热回流反应24 h,以95%的产率合成了中间体--9,9-二[4-(4-甲基苯氧基)苯基]呫吨(3),继而加入催化量的N-溴代丁二酰亚胺并在光照条件下,将中间体3氧化得到一种新型芳香族二羧酸--9,9-二[4-(4-羧基苯氧基)苯基]呫吨(4),其产率为84%,二步反应总收率为79.8%。 目标化合物4经1H NMR、13C NMR、IR和元素分析测试技术确定了其结构。 该法具有原料易得,操作简单,反应条件温和,收率高等优点。 相似文献
42.
Characteristics of ultrafast K line hard x—ray source from femtosecond terawatt laser—produced plasma 下载免费PDF全文
Theoretical studies and analytical scalings were carried out to find the optimized laser parameters and target conditions so that ultrashort hard x-ray pulses and high x-ray power could be achieved.The dependence of laser intensity and wavelength on the yield of K-shell x-ray emission was studied.We propose an optimal design for a foil target for producing high-yield hard x-ray pulses of customizing duration. 相似文献
43.
By developing multiple-scale method combined with
Wentzel--Kramer--Brillouin expansion, this paper analytically
studies the modulating effect of weakly periodic potential on the
dynamical properties of the Bose--Einstein condensates (BEC) trapped
in harmonic magnetic traps. A black--grey soliton transition is
observed in the BEC trapped in harmonic magnetic potential, due to
the weakly periodic potential modulating effect. Meanwhile, it finds
that with the slight increase of the weakly periodic potential
strength, the velocity of the soliton decreases, while its width
firstly decreases then increases, a minimum exists there. These
results show that the amplitude, velocity, and width of matter
solitons can be effectively managed by means of a weakly periodic
potential. 相似文献
44.
This paper studies initial-boundary value problems for a class
of nonlinear thermoelastic plate equations. Under some certain
initial data and boundary conditions, it obtains an existence and
uniqueness theorem of global weak solutions of the nonlinear
thermoelstic plate equations, by means of the Galerkin method.
Moreover, it also proves the existence of strong and
classical solutions. 相似文献
45.
碳黑经过酸处理后再加入醋酸钴经氨气900 ℃热处理后, 以其制备的气体扩散电极在6 mol•L―1 KOH溶液中对氧还原反应(ORR)的电催化性能得到大大提高. XRD物相分析表明: 碳粉中加入醋酸钴经氨气热处理生成了氮化钴(Co5.47N). 通过极化曲线和交流阻抗方法对制备的气体扩散电极在空气中的性能进行了研究. 室温时在-0.2 V (vs. Hg/HgO)电位下, 未经处理的碳电极对氧还原基本没有电流产生; 用酸处理后的碳电极在空气中的电流密度提高到57 mA•cm―2; 而Co-N/C复合电极在同样条件下电流密度可达170 mA•cm―2, 交流阻抗显示氮化物的生成减小了氧还原反应的阻抗, 增强了对氧还原反应的电催化作用. 相似文献
46.
研读新课程标准中的相关要求,分析鲁科版必修新教材的情境素材类型和呈现方式,得出教材中情境素材具有:微项目使实践情境大放异彩、史实情境彰显中华民族自信、情境素材充分体现STSE教育理念等特点。据此提出从静态的教材情境到动态的教学情境转化的3条教学建议:充分重视教材栏目所蕴含的情境教学功能;深挖教材情境素材所承载的学科核心素养;考虑教学的整体设计选取和呈现情境素材。 相似文献
47.
48.
The structure and catalytic properties of SrTi1-xMgxO3-δ perovskite-type catalysts for oxidative coupling of methane (OCM) have been studied by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Temperature-programmed desorption (O2-TPD) methods. It has been shown that doping Mg2+ cations to the B site of SrTi1-xMgxO3-δ perovskite-type catalysts results in the formation of oxygen vacancies in the lattices of oxide cata-lysts. With increasing the amount of Mg2+ doped in the B site of SrTi1-xMgxO3-δ, methane conversion and C2 selectivity first increase and then decrease remarkably. The SrTi1-xMgxO3-δ catalyst with x=0.1 has the highest methane conversion and C2 yield. It is suggested that the oxygen vacancies produced by Mg2+ cations doping are the sites responsible for oxygen activation, and the adsorbed oxygen species on the surface of SrTi1-xMgxO3-δ catalysts are the main active species for OCM reaction. However, the over high content of the adsorbed oxygen species on the surface results in the complete oxidation of methane. Introducing water steam into feedstock can improve the catalytic properties of SrTi1-xMgxO3-δ perovskite-type catalysts for OCM reaction at lower temperature. The SrTi0.9Mg0.1O3-δ catalyst has the methane conversion of 28.0 % with C2 hydrocarbons selectivity of 36.8 % under reaction temperature of 550 ℃. 相似文献
49.
50.
In this paper we present the three dimensional EHMO crystal orbital calculations for crystalline Li2CsC60, Na2CsC60, K2CsC60 and Rb2CsC60. For all these four dopants with a fcc structure, our calculated band structures and density of state unequivocally suggest a metallic conducting phase with each a set of three half-filled band across the Fermi level which is just located close to a peak of density of state. A monotonic relationship is found between our calculated Fermi-level density of state N and experimental transition temperature Tc which is in excellent agreement with some theoretical studies and experimental results. With our other calculation results, such as the overlap populations between A (where A represents an alkali-metal) and C60 molecules, net atomic and orbital charges, crystal orbital vectors and various projected DOS, we could probably shed some light on the mechanism of the superconductivity for this new marvelous kind of materials from a chemical point of view. 相似文献