Localized flexible integration of high-efficiency surface enhanced Raman scattering (SERS) monitors into microfluidic channels

We report here a facile approach for flexible integration of high efficiency surface enhanced Raman scattering (SERS) monitors in a continuous microfluidic channel. In our work, femtosecond laser direct writing was adopted for highly localizable and controllable fabrication of the SERS monitor through a multi-photon absorption (MPA) induced photoreduction of silver salt solution. The silver substrate could be shaped into designed patterns, and could be precisely located at the desired position of the microchannel bed, giving the feasibility for real-time detection during reactions. SEM and TEM images show that the silver substrates were composed of crystallized silver nanoplates with an average thickness of 50 nm. AFM results reveal that the substrates were about 600 nm in height and the surface was very rough. As representative tests for SERS detection, p-aminothiophenol (p-ATP) and flavin adenine dinucleotide (FAD) were chosen as probing molecules for microfluidic analysis at visible light (514.5 nm) excitation, exhibiting an enhancement factor of ~10(8). In addition, the combination of the SERS substrate with the microfluidic channel allows detection of inactive analytes through in situ microfluidic reactions.     

以乙醇作溶剂电沉积制备CIGS薄膜

利用恒电位电沉积法在以乙醇为溶剂的溶液中制备了铜铟镓硒(CIGS)薄膜.并采用扫描电子显微镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)和紫外-可见-近红外(UV-VIS-NIR)分光光度计分别对薄膜的形貌、成分、晶体结构和吸收特性进行了表征.结果表明在-1.6V(相对于饱和甘汞电极电位)工作电位下沉积的薄膜经450°C退火后能够形成形貌均匀致密、结晶性良好、带隙约为1.17eV的黄铜矿结构CuIn0.7Ga0.3Se2薄膜.实验过程中发现,以乙醇为溶剂可以有效避免在水溶液中出现的析氢现象,减小了沉积电位的限制.     

纳米复合模板水凝胶的制备及其性能

以非离子表面活性剂聚氧乙烯(20)鲸蜡醇醚(Brij58)为模板, 采用自由基聚合制备得到聚(N-异丙基丙烯酰胺)/Brij58/粘土纳米复合模板水凝胶(PLH). 相比于传统纳米复合水凝胶, PLH水凝胶力学性能与亲水性明显改善. 场发射扫描电镜(FESEM)结果表明: Brij58的引入导致传统纳米复合水凝胶的孔洞数量增加, 孔与孔相互贯穿, 大孔结构更加规整, 大孔之间由众多小孔连接. 拉伸应力-应变、储能模量和溶胀动力学研究结果表明, 断裂应力、断裂负载和断裂伸长率随Brij58含量的增加呈先增加后降低的趋势, 然而水凝胶储能模量与最大溶胀度随Brij58含量的增加而增加. 同时, 表面接触角结果表明: 由于Brij58的模板作用和Brij58同粘土之间的吸附作用, 使PLH水凝胶表面接触角先增大后减小.     

一类高聚类系数的加权无标度网络及其同步能力分析

针对真实世界中大规模网络都具有明显聚类效应的特点, 提出一类具有高聚类系数的加权无标度网络演化模型, 该模型同时考虑了优先连接、三角结构、随机连接和社团结构等四种演化机制. 在模型演化规则中, 以概率p增加单个节点, 以概率1–p增加一个社团. 与以往研究的不同在于新边的建立, 以概率φ在旧节点之间进行三角连接, 以概率1–φ进行随机连接. 仿真分析表明, 所提出的网络度、强度和权值分布都是服从幂律分布的形式, 且具有高聚类系数的特性, 聚类系数的提高与社团结构和随机连接机制有直接的关系. 最后通过数值仿真分析了网络演化机制对同步动态特性的影响, 数值仿真结果表明, 网络的平均聚类系数越小, 网络的同步能力越强. 关键词： 无标度网络 加权网络 聚类系数 同步能力     

光敏催化氧化α-蒎烯合成桃金娘烯醛

以α-蒎烯为原料,以卤素灯为光源,在自制光化学反应器中进行反应.研究了α-蒎烯光敏催化氧化制备高附加值桃金娘烯醛的新工艺.考察了光敏催化氧化反应条件对反应转化率和选择性的影响规律.气相色谱分析结果表明:以吡啶-醋酸酐-铜盐为催化剂,在氧流速0.3L/min、原料浓度0.75mol/L、催化剂浓度0.253mol/L、反应温度45℃下反应6h,原料的转化率达97.34％,桃金娘烯醛的选择性可达48.10％.     

The basis of organic spintronics：Fabrication of organic spin valves

Organic spintronics focuses on utilizing the spin degree of freedom in organic materials because of the long spin relaxation time. The vertical organic spin valve (OSV) is a typical sample structure used to study the spin transport phenomena. However, the fabrication of high quality OSVs is difficult, which results in controversial experiment results and hence hinders the development of organic spintronics. In this work, we describe our recent study on the fabrication of typical vertical organic spin valves, La_0.67Sr_0.33MnO₃ (LSMO)/Alq₃/Co. The LSMO bottom electrodes are annealed to obtain an atomically smooth surface and improved magnetic properties. The top Co electrodes are deposited by an indirect deposition method to reduce the interfusion between Co and Alq3. The controlled fabrication process provides much better performance and sample yield of OSVs.     

Analysis of Optical Readout Sensitivity for Uncooled Infrared Detector

An optical readout uncooled infrared detector, employing a substrate-free focal plane array with pitch size 60μm, is established. The reflector deformation induced by the stress mismatching of the bi-layer structure is discussed and, in turn, a universal solution to determine both the optical readout sensitivity and the optimal filter position is found. By applying this solution, the optical readout sensitivity for the ideal plane reflector could theoretically increase by 80% as compared with the conventional operation, and the sensitivity loss caused by the reflector deformation can also be reduced to a reasonable level.     

一维Klein-Gordon/Fermi-Pasta-Ulam混合原子链中非线性参数作用的研究

采用推广的旋转平面波近似对一维非线性Klein-Gordon/Fermi-Pasta-Ulam混合原子链的运动方程进行简化,数值求解得到该系统中存在的离散呼吸子解.研究了系统中各非线性参数对该振动模的直流、一阶简谐项和二阶简谐项三个分量的对称性的影响以及对系统中局域模的影响. 关键词： Klein-Gordon/Fermi-Pasta-Ulam混合原子链 推广的旋转平面波近似 离散呼吸子 对称性     

Ultrasensitive determination of Cu2+ by synchronous fluorescence spectroscopy with functional nanoparticles

Microchimica Acta - A new synchronous fluorescence method was developed for the rapid determination of Cu2+ with functional CdS nanoparticles as a probe, based on the fluorescence quenching of...