一种新颖一维铅碘聚合物[(Pb_2I_5)(L-H~ )·2DMF]_n(L=Piperazine)的自组装合成和晶体结构(英文)

0IntroductionIncreasinginterestisfocusedonthestudyofmagnetic,electronicandoptoelectronicpropertiesoflow鄄dimensionalorganic鄄inorganichybridcompoun鄄ds[1~3].Studiesshowthatcomplexconsistingoforganicandinorganiccomponentshavegreatpotentialforthecreationoff…     

纳米核壳式铜-锡双金属粉的制备及性能研究

A kind of novel core-shell Cu-Sn bimetallic nanoparticles has been prepared by a new method (displacement method), in which Sn was made to cover on the surface of Cu nano-core. The preparation method and reaction mechanism have been discussed. This reaction happened under the existence of coordinate agent-(NH₂)₂CS and protective agent PVP. The nanoparticles prepared were with a core-shell structure, granule diameter between 50～100 nm and good dispersing capability. The Cu-Sn nanoparticles proposed has better oxidation-resistant ability than Cu nanoparticles with corresponding granule diameter and can be applied as lubricant additives as well as antibacterial agent. When the additive amount is very low (0.1wt‰～0.5wt‰), it can improve the P_B of the lubricant by 92%～106%, and also enhance its antiwear characteristics and friction-reducing properties. At the concentration of 1 000 ppm, it can reach an antibacterial ratio of 99.99%.     

验证感生电场存在的实验

针对磁场变化时激发产生的感生电场很难演示的问题,设计了演示感生电场存在的实验. 该实验将不同功能的仪器组合起来使用,通过亥姆霍兹线圈的交变磁场对带电粒子的作用效果,直观说明感生电场的存在.     

Characteristic improvements of thin film AlGaInP red light emitting diodes on a metallic substrate

We report a type of thin film Al Ga In P red light emitting diode(RLED) on a metallic substrate by electroplating copper(Cu) to eliminate the absorption of Ga As grown substrate.The fabrication of the thin film RLED is presented in detail.Almost no degradations of epilayers properties are observed after this substrate transferred process.Photoluminescence and electroluminescence are measured to investigate the luminous characteristics.The thin film RLED shows a significant enhancement of light output power(LOP) by improving the injection efficiency and light extraction efficiency compared with the reference RLED on the Ga As parent substrate.The LOPs are specifically enhanced by 73.5% and 142% at typical injections of 2 A/cm~2 and 35 A/cm~2 respectively from electroluminescence.Moreover,reduced forward voltages,stable peak wavelengths and full widths at half maximum are obtained with the injected current increasing.These characteristic improvements are due to the Cu substrate with great current spreading and the back reflection by bottom electrodes.The substrate transferred technology based on electroplating provides an optional way to prepare high-performance optoelectronic devices,especially for thin film types.     

参数可控长距无衍射光束的生成方法研究

为了消除光学器件几何参数对无衍射光束传播特性调整的限制,实现长距空间中无衍射光束传播时特性参数的可控性,首先,通过研究axicon折射阴影区的电场分布特征,发现axicon无衍射区外过临界面后的近轴区域虽处于几何折射阴影近轴区域内,但仍存在光强服从第一类零阶贝赛尔函数分布的球面波;以此为基础,提出了一种不受传播空间距离限制的无衍射光束的生成方式;最后,在近12 m的尺度范围内进行无衍射光传播特性参数测试,发现其实验参数与理论计算值的差值不超过0.1μm。该无衍射光通过对第一类零阶贝塞尔函数分布的球面衍射光斑准直生成,本质上区别于传统的干涉无衍射光束生成方式,易于生成大尺度空间无衍射光束。该无衍射光生成方式适合用于非能量使用情况下大尺度空间的直线基准、光束空间通讯等领域,具有较大的价值与意义。     

水溶性量子点标记狂犬病P蛋白单克隆抗体的研究

利用共价偶联的方式,在水溶性缩合剂1-乙基-(3-二甲基氨基丙基)碳二亚胺盐酸盐(EDC)和N-羟基硫代琥珀酰亚胺(Sulfo-NHS)促进作用下,将400 μL的2 g/L狂犬病P蛋白抗体与适量的聚丙烯酸修饰后的水溶性硫脲修饰ZnO掺Cd量子点进行共价偶联反应,经磷酸盐缓冲液(PBS,0.01 mol/L,pH 7.4)透析纯化得到目标偶联物,采用荧光发射光谱、生物质谱、酶联免疫法等对偶联物进行表征.结果表明:偶联后的量子点荧光最大发射波长红移了10 nm,荧光强度随着狂犬病P蛋白抗原浓度的增加而逐渐增强;量子点标记狂犬病P蛋白抗体后的分子离子峰在m/z 67580处,比狂犬病P蛋白抗体分子离子峰增大了1453.由此证实狂犬病P蛋白抗体成功偶联到水溶性量子点上,且结构未受破坏.     

近失速状态下压气机静子通道内的三维流动

本文综合运用体式激光粒子图像测速技术和油流显示技术研究了近失速状态下压气机静子通道内部的复杂三维流动,建立了静叶通道内部三维流动结构模型,并分析了典型流动结构的产生、发展和演化机制.实验结果表明,在近失速状态,近叶通道出现了两个截然不同的分离区-吸力面近机匣角区分离(7%～50%弦长,闭式分离)和吸力面近轮毂角区分离(50%弦长以后,开式分离),以及一些复杂的流向旋涡流动结构.     

两类广泛递归序列的动力特性

We investigate the dynamics of two extensive classes of recursive sequences:xn+1=c∑ k ∑xn-ioxn-i1…xn-i2j+f(xn-io,xn-i1,…,xn-i2k)j=0(i0,i1,…,i2j)∈A2j/c∑ k ∑xn-ioxn-i1…xn-i2j-1+c+f(xn-io,xn-i1,…,xn-i2k)j=1(i0,i1,…,i2j)∈A2j-1 and xn+1=c∑ k ∑xn-ioxn-i1…xn-i2j-1+c+f(xn-io,xn-i1,…,xn-i2k)j=1(i0,i1,…,i2j)∈A2j-1/c∑ k ∑xn-ioxn-i1…xn-i2j+f(xn-io,xn-i1,…,xn-i2k)j=0(i0,i1,…,i2j)∈A2j We prove that their unique positive equilibrium x = 1 is globally asymptotically stable.And a new access is presented to study the theory of recursive sequences.     

新型P－N－Si无卤阻燃剂的合成及其在棉纤维中的应用

以二氯磷酸苯酯(1)和γ-氨丙基三乙氧基硅烷(2)为原料,合成了一种新型的P－N－Si三元无卤阻燃剂--苯氧基-双-(三乙氧基硅丙基)磷酰胺(3),其结构经¹H NMR, ³¹P NMR和FT-IR表征。研究了溶剂,反应温度,反应时间,投料比r［n(2) : n(1)］和缚酸剂对3产率的影响。结果表明:在最佳合成条件［THF为溶剂,三乙胺为缚酸剂,1 8 mmol, r=2.4,于40 ℃反应6 h］下, 3的产率为88.2%。利用TGA测试了3的阻燃性能。结果表明：3的初始分解温度为150 ℃, 600 ℃残炭为14.6%。3在棉纤维(c)中的添加量为15%(质量百分数,即c-3¹⁵)时,600 ℃残炭为33.4%,高于c(7.6%)。     

Carrier transport in III–V quantum-dot structures for solar cells or photodetectors

According to the well-established light-to-electricity conversion theory,resonant excited carriers in the quantum dots will relax to the ground states and cannot escape from the quantum dots to form photocurrent,which have been observed in quantum dots without a p–n junction at an external bias.Here,we experimentally observed more than 88% of the resonantly excited photo carriers escaping from In As quantum dots embedded in a short-circuited p–n junction to form photocurrent.The phenomenon cannot be explained by thermionic emission,tunneling process,and intermediate-band theories.A new mechanism is suggested that the photo carriers escape directly from the quantum dots to form photocurrent rather than relax to the ground state of quantum dots induced by a p–n junction.The finding is important for understanding the low-dimensional semiconductor physics and applications in solar cells and photodiode detectors.