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Ni—W alloy was electrodeposited from the electrolyte solution containing sodium tungstate, nickel sulfate and ammonium citrate. The electrodeposition, heat treatment, structure, surface morphology and corrosion resistance in w=0.03 NaCl solution, of Ni-W alloys were studied by means of DSC, XRD, SEM and electrochemical techniques. The results showed that the obtained Ni-W alloy electrodeposit with W weight content (Ww=0.471) was presented in more typical nanocrystaUine, After heat treatment at 400 ℃ for 1 h, the phase structure of the deposits was not obviously changed whereas the agglomerate for the reunion of tiny grains on deposit surface caused the granule in a more smooth morphology, the microhardness was slightly increased and the corrosion resistance was enhanced. 相似文献
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采用控电位电解、循环伏安法和交流阻抗法研究了FeCl_2-K_2MoS_4体系对乙炔在石墨电极上还原为乙烯的电催化活性及反应机理。实验结果表明,当石墨阴极的电位控制在-1.50V(vs.SCE)时,FeCl_2+K_2MoS_4的DMF溶液对C_2H_2还原为C_2H_4表现出明显的电催化活性和高的选择性。在-0.5~-1.0V时Mo(Ⅵ)还原为Mo(Ⅴ);在按连串的电子传递机理进行的Mo(Ⅴ)→Mo(Ⅲ)反应的电位区间(-1.0~-1.50V)溶液中所形成的络合品种传递电子的能力更强。Mo(Ⅲ)可能是络合物的电活性成分。 相似文献
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Ni—Mo—PTFE复合电极的制备及其对甲醇电氧化的催化性能 总被引:4,自引:0,他引:4
在0.22mol/L硫酸镍,0.06mol/L钼酸钠,0.3mol/L柠檬酸钠,30g/LPTFE乳液,0.1g/LFC-400表面活性剂的电解液(pH=9)中,于温度45℃,通以10mA/cm2的电流,在纯Cu片上沉积出Ni-Mo-PTFE复合沉积层,XRD、XPS表征结果表明,该复合沉积层属立方晶系,其点阵型式为面心点阵F,晶胞参数a为0.3573nm,镍钼合金为固溶体结构,其(111)织构度TC(111)为68%,表明该沉积层呈(111)择优取向.沉积层表面的氟以(CF2)n的形式存在,SEM观察结果表明沉积层含有PTFE时表面的粗糙度增大.镍-钼-PTFE复合电沉积过程经历吸附态物种氢氧化镍和钼的氧化物,它们继续捕获电子被还原为镍钼合金,PTFE粒子以包埋的形式沉积于镀层中.循环伏安结果表明该复合电极在NaOH溶液中对甲醇的电氧化具有催化活性. 相似文献
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To strengthen the properties of Ni-W alloy, dimethylamine borane (DMAB) was added to an alloy Ni-W electrolyte solution and a ternary Ni-W-B alloy was electrodeposited. The electrodeposition, crystallographic structure, surface morphology, heat treatment and corrosion resistance, of the alloy were studied by DSC, XRD, SEM and electrochemical techniques. The results showed that the structure of the alloy was greatly affected by the cooperation of boron compound. DSC experiment combined with X-ray diffractometry indicated that the obtained Ni-W-B alloy was still in amorphous structure although W content in the alloy was decreased by the addition of DMAB. After heat treatment at 400 ℃ for 1 h, the microhardness was increased from 612 to 947 kg.mm^-2 that was com- parative to Cr coating. The appearance of the as-plated coating was in f'me and slice grains and kept almost no change after heat treatment. In w=0.03 NaC1 solution the as-plated coating presented very good corrosion resistance. After the coating was heat-treated its corrosion resistance was enhanced. 相似文献
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电沉积非晶态Ni-W-B/ZrO2复合镀层及其结构与性能 总被引:1,自引:0,他引:1
在含有二氧化锆的Ni-W-B电解液中,电沉积获得Ni-W-B/ZrO2复合镀层.用差示扫描量热分析(DSC)、X射线衍射(XRD)、扫描电子显微镜(SEM)和电化学技术较系统地研究了Ni-W-B/ZrO2复合镀层的电沉积、热处理过程,以及镀层的结构、表面形貌、显微硬度和耐腐蚀性能.结果表明, 复合镀层的质量组成为Ni 47.5%、W 40.9%、B 0.9%和ZrO2 10.7%. DSC和XRD结果清楚说明, 二氧化锆对基质Ni-W-B镀层的结构有明显影响, 使得复合镀层的非晶态结构特征更加明显 .复合镀层比Ni-W-B合金有更高的显微硬度, 呈现团粒状结构, 晶块之间不存在裂纹但晶界清晰可辨; 二氧化锆粒子分散于Ni-W-B基质镀层中. 400 ℃、1 h热处理后, Ni-W-B基质镀层中W向镀层表面偏析, 镀层呈现固溶体晶态结构特征, 表面形貌特征基本不变, 复合镀层的显微硬度进一步提高, 抗腐蚀性能增强, 但镀层表层中的二氧化锆粒子大量脱落. 相似文献
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