2,6-吡啶二亚胺基锰(Ⅲ)配合物的合成、晶体结构及催化性能

由三齿含氮配体2,6-二[1-(2,6-二甲基苯基亚胺)乙基]吡啶(L1)、2,6-二[1-(2,6-二乙基苯基亚胺)乙基]吡啶(L2)和2,6-二[1-(2,4,6-三甲基苯基亚胺)乙基]吡啶(L3)分别与MnCl2·4H2O在乙腈中反应,合成了3个新的具有较大空间位阻的2,6-吡啶二亚胺基氯化锰配合物L1Mn(Ⅱ)...     

基于第一性原理方法研究ReOx在ReOx-Rh/ZrO2和ReOx-Ir/ZrO2催化的甘油氢解反应中的作用机制

采用密度泛函理论研究了ZrO₂负载的Ru基、Rh基以及Re改性的Rh基、Ir基催化剂上甘油氢解生成1,2-丙二醇和1,3-丙二醇的热力学过程, 重点考察了ReO_x调变催化剂活性和选择性的作用机制. 结果表明, Ru/ZrO₂和Rh/ZrO₂催化剂上甘油分解经由脱水-加氢反应途径, 1,2-丙二醇的生成是热力学有利过程, 其中Ru基催化剂活性更高. 在Re修饰的Rh基和Ir基催化剂上, 反应遵循直接氢解机理, 其中金属表面解离的氢原子进攻ReO_x团簇上与醇盐紧邻的C-O键是催化甘油转化为丙二醇最核心的步骤. ReO_x-Rh/ZrO₂催化剂上1,2-丙二醇为主要产物, 并伴随1,3-丙二醇的生成, ReO_x的修饰则显著提高了Ir/ZrO₂催化剂上1,3-丙二醇选择性. 与单金属催化剂上发生的间接氢解机理相比, 修饰催化剂上1,3-丙二醇选择性的提高可主要归因于Rh(Ir)-Re协同催化的直接氢解反应过程, 其中羟基化铼官能团有利于末端醇盐中间体的生成. ReO_x-Ir/ZrO₂催化剂上较大的Ir-Re团簇使得末端金属醇盐的立体优选性比次级醇盐更为突出, 从而具有最高的1,3-丙二醇选择性.     

用PAR作显色剂光度法研究铼（Ⅶ）在双水相萃取体系（聚乙二醇2000-硫酸铵）中的分配行为

以4-（2-吡啶偶氮）-间苯二酚（PAR）为显色剂,用光度法研究了铼（Ⅶ）在聚乙二醇2000（PEG）-硫酸铵双水相萃取体系中的分配行为。萃取系在有一定量铼标准溶液存在,且含有300g·L~（-1）聚乙二醇2000溶液及300g·L~（-1）硫酸铵溶液各3mL及1g·L~（-1）PAR溶液1mL,并用磷酸盐缓冲溶液控制...     

基于散射矩阵方法的金属光子晶体薄膜异常光学透射研究

散射矩阵方法是一种基于频域的研究方法.将散射矩阵方法用于亚波长周期性金属小孔结构的透射特性研究.以金属铜薄板为研究对象,薄板刻蚀方格子光子晶体空气圆孔;用洛伦兹-德鲁德(Lorentz-Drude)模型来表征铜的介电常数ε;对不同的薄板厚度、周期大小和空气孔孔径的结构进行透射谱分析.并与时域有限差分方法计算所得结果相对...     

微腔中两原子缀饰态的二光子衰变

研究了微腔中原子衰变问题。考虑微腔中存在两个原子，两原子与腔场强耦合形成的缀饰原子与腔壁相互作用在特定初始条件下的衰变问题，指出在腔场中该衰变方式下，腔场光子数越多、衰变则越强     

Mode decoupling in solid state ring laser based on stimulated Raman effect in polar crystals

In this paper we study the gain saturation induced mode-coupling control in solid state ring laser devices based on the stimulated Raman effect of the polar crystals in order to realize solid state ring laser gyroscopes.We theoretically investigate the mode coupling induced by gain saturation between clockwise (CW) and counterclockwise (CCW) propagating laser modes.Because the CW and CCW running waves are pumped with counter-propagating lasers respectively,the independent coexistence can be ensured.     

4-二苯胺基苯甲醇功能化石墨烯的制备、电子传递及光催化性能

在碱性条件下由氧化石墨(GO)还原获得还原石墨烯(RGO). RGO与4-二苯胺基苯甲醇(TPACH₂OH)混合后发生相互作用, 得到功能化石墨烯复合物(TPACH₂OH-RGO). 采用密度泛函理论(DFT)对TPACH₂OH-RGO模拟计算结果表明, TPACH₂OH和RGO之间主要通过氢键作用形成复合物. 利用紫外-可见光谱(UV-vis)、拉曼光谱(Raman)、荧光光谱(Fluorescence)、原子力显微镜(AFM)、透射电子显微镜(TEM)和电化学等方法研究了TPACH₂OH-RGO结构和光电性质, 并研究了以TPACH₂OH-RGO为催化剂在光照射下光催化分解水制氢性能. 实验结果表明: 光照下复合物中激发态TPACH₂OH向RGO转移电子. 在TPACH₂OH和RGO的质量比为4/3, 体系pH＝6条件下, 光照6 h, TPACH₂OH-RGO的产氢总量达到35.0 μmol, 比RGO的产氢总量(20.4 mmol)有明显的提高.     

A new approach to detecting weak signal in strong noise based on chaos system control

In this paper, a chaos system and proportional differential control are both used to detect the frequency of an unknown signal. In traditional methods the useful signal is obtained through the Duffing equation or other chaotic oscillators. But these methods are too complex because of using a lot of chaos oscillators. In this paper a new method is presented that uses the R?ssler equation and proportional differential control to detect a weak signal frequency. Substituting the detected signal frequency into the R?ssler equation leads the R?ssler phase state to be considerably changed. The chaos state can be controlled through the proportional differential method. Through its phase diagram and spectrum analysis, the unknown frequency is obtained. The simulation results verify that the presented method is feasible and that the detection accuracy is higher than those of other methods.     

Relationship between group velocity and symmetry of photonic crystals

Group velocity (GV) of eigenmode is a crucial parameter to explain the extraordinary phenomena about light propagation in photonic crystals (PhCs). To study relationships between group velocity and symmetry of PhCs, a new general expression of GV in PhCs made up of non-dispersive material is introduced. Based on this, the GVs of eigenmodes of PhCs, especially those of degenerate eigenmodes at highly symmetric points in the first Brillouin zone, are discussed. Some interesting results are obtained. For example, the summation of degenerate eigenmodes' GVs is invariant under the operations of wave vector ${{\bm K}}$-group $M_{{\bm K}} $. In addition, some numerical results are presented to verify them.     

高功率脉冲非平衡磁控溅射放电特性和参数研究

用线圈电流控制非平衡磁场,用汤森放电击穿形成深度自触发放电,用磁阱捕获放电形成的二次电子和导致漂移电流,形成了高功率非平衡磁控溅射放电。采用偏压为-100V相对磁控靶放置的圆形平面电极收集饱和离子电流;在距离磁控靶14cm的位置由Langmuir探针测量浮置电位;示波器测量磁控靶的脉冲电压、电流、浮置电位和饱和离子电流信号。装置的放电脉冲功率达到0.9MW,脉冲频率最大值为40Hz左右,空间电荷限制条件是控制电子电流和离子电流的主要机制。