YbSi2 and the derivatives YbTxSi2–x (T = Cr, Fe, Co) crystallizing in the α‐ThSi2 structure type were obtained as single crystals from reactions run in liquid indium. All silicides were investigated by single‐crystal X‐ray diffraction, I41/amd space group and the lattice constants are: a = 3.9868(6) Å and c = 13.541(3) Å for YbSi2, a = 4.0123(6) Å and c = 13.542(3) Å for YbCr0.27Si1.73, a = 4.0142(6) Å and c = 13.830(3) Å for YbCr0.71Si1.29, a = 4.0080(6) Å and c = 13.751(3) Å for YbFe0.34Si1.66, and a = 4.0036(6) Å, c = 13.707(3) Å for YbCo0.21Si1.79. YbSi2 and YbTxSi2–x compounds are polar intermetallics with three‐dimensional Si and M (T+Si) polyanion sub‐networks, respectively, filled with ytterbium atoms. The degree of substitution of transition metal at the silicon site is signficant and leads to changes in the average bond lengths and bond angles substantially. 相似文献
Reflections from geometric discontinuities can be used with ultrasonic energy to predict the temperature of an interface where classical temperature measurement techniques are impractical because of physical access limitations or harsh environmental conditions. Additionally, these same ultrasonic measurements can be used with inversion methods commonly applied to ill-posed heat transfer problems to increase the accuracy of the measurement of surface temperature or heat flux at the surface of interest. Both methods for determining surface temperature are presented, along with a comparison of results both from a verification example and using data gathered in a field test of the methods. The results obtained with these two methods are shown to be in good agreement with an empirical relationship used in the design of large caliber guns. 相似文献
A solid state metathesis (SSM) reaction was investigated with respect to the formation of rare‐earth carbodiimides, the role of the co‐produced salt (LiCl), and the eutectic flux medium (LiCl/KCl). A SSM reaction is characterized by an exothermic reaction in which a salt (often LiCl) is coproduced. When the salt melts, it can serve as a useful medium for the crystallization of a desired product. An improved crystal growth can be observed by using an eutectic flux. However, the composition of an eutectic LiCl/KCl flux is altered when LiCl is produced during the reaction. The thermal effects concerning the endothermic melting of the flux and the exothermic ingnition of the SSM reaction may compensate each other, which is not necessarily a drawback for the reaction to proceed. 相似文献
The purpose of this investigation is to theoretically shed some light on the effect of the unsteady electroosmotic flow (EOF) of an incompressible fractional second-grade fluid with low-dense mixtures of two spherical nanoparticles, copper, and titanium. The flow of the hybrid nanofluid takes place through a vertical micro-channel. A fractional Cattaneo model with heat conduction is considered. For the DC-operated micropump, the Lorentz force is responsible for the pressure difference through the microchannel. The Debye-Hükel approximation is utilized to linearize the charge density. The semi-analytical solutions for the velocity and heat equations are obtained with the Laplace and finite Fourier sine transforms and their numerical inverses. In addition to the analytical procedures, a numerical algorithm based on the finite difference method is introduced for the given domain. A comparison between the two solutions is presented. The variations of the velocity heat transfer against the enhancements in the pertinent parameters are thoroughly investigated graphically. It is noticed that the fractional-order parameter provides a crucial memory effect on the fluid and temperature fields. The present work has theoretical implications for biofluid-based microfluidic transport systems.
When simulating two-phase flow in porous media, one has to consider the case where there is a discontinuity in the medium. There relative permeabilities and capillary pressure functions may change and we address the problem of calculating the convective part of the numerical flux at the interface between the two rock types. Several solutions are compared. 相似文献