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以不同沉淀剂的反向共沉淀法制备了SrZrO_3∶Ce纳米粒子;采用X射线衍射(XRD)、扫描电镜(SEM)、热重-差热分析(TG-DTA)测试方法,对样品物相、形貌、发光强度及烧结致密化进行了分析,讨论了不同前驱体的热分析动力学。结果表明:用单相和复相沉淀剂制备的前驱体在1 000℃煅烧2 h分别获得分散性良好的棱柱形和近球形SrZrO_3∶Ce粒子,粒径约80和60 nm。利用Doyle-Ozawa积分法和Kissinger微分法分别求出用单相和复相沉淀剂制备的前驱体在不同反应阶段的表观活化能平均值为94.18、69.39、255.72 kJ·mol~(-1)和90.46、51.03、232.35 kJ·mol~(-1),晶体生长活化能为E_(单相)=27.97 kJ·mol~(-1)和E_(复相)=22.53 kJ·mol~(-1),后者的表观活化能和晶体生长活化能都小于前者,表明复合沉淀剂的引入降低了合成能量,提高了粒子活性,所制备样品的发光强度明显优于用单相沉淀剂制备的样品,经1 760℃真空烧结保温4 h后用复相沉淀剂制备的样品的晶粒尺寸均一并达到了致密化。 相似文献
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为满足兰州重离子加速器的实验要求,在14.5GHz高电荷态ECR离子源上做了一系列产生金属离子的实验,尝试了多种方法,包括炉子加热及MIVOC(Metallic Ion form Volatile Compounds)两种方法,其中,用炉子做的结果较理想。实验主要研究了铜、锌、镍多种电荷态离子的产生,具有代表性的是39euA的13+,30euA的Zn13+和29euA的Ni10+。分别给出了这三种金属离子产生的多电荷态束流峰谱图,以及实验的一些其它现象及结果,并对其进行了讨论与总结。 相似文献
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采用醇水溶剂热法制备了BaZrO3∶(Ce、Pr)发光粒子。用XRD,SEM等测试技术分析了样品物相变化及形貌特征;用荧光光度计分析了样品的激发光谱和发射光谱。结果表明,当n(Ba)∶n(Zr)=0.7∶1,反应温度200℃,保温时间20h,V(H2O)∶V(C2H5OH)=1∶3,pH=14时,制备出分散性良好、粒径约39.0nm、形貌近似球形的BaZrO3∶(Ce、Pr)纳米粒子。当掺杂Ce3+、Pr3+摩尔浓度比为1∶3时,样品的发光强度最大。 相似文献
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以CoCl2·6H2O和CS(NH2)2为水热前驱物,在不同pH值下制备了CoS2粒子,对CoS2的物相组成、微观形貌、热稳定性和正极材料电化学性能进行表征和测试.结果表明,CoS2粒子在酸性和碱性溶液中形核生长机制不同,当pH =5和pH=10时分别获得黄铁矿结构CoS2粒子其形貌为类球形和不规则块状,对应热分解温度为650℃和610℃.在100 mA/cm2放电时,两种形貌CoS2正极材料的电化学性能基本相近;800 mA/cm2放电时,类球形CoS2放电比容量较块状CoS2高9.65;,并具有优于后者的高初始放电电压及低内阻特性. 相似文献
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Deterministic joint remote preparation of an arbitrary two-qubit state in the presence of noise 下载免费PDF全文
Using two tripartite Greenberger-Horne-Zeilinger (GHZ) states as the shared channels, we investigate the noise effects on the deterministic joint remote preparation of an arbitrary two-qubit state. By unitary matrix decomposition procedure, we first construct the quantum logic circuit of the deterministic joint remote state preparation protocol. Then, we analytically derive the fidelity and the average fidelity for the deterministic joint remote preparation of an arbitrary two- qubit state and of four types of special two-qubit states under the influence of the Pauli noises. It is found that the fidelity depends on the noise types, the qubit-environment coupling strength, and the state to be remotely prepared. Moreover, even if the two GHZ channels are subject to the same environmental noises, the average fidelities for remotely preparing different two-qubit states display different time evolution behaviors. The remote preparation of the identical two-qubit states also shows that the average fidelities affected by different noisy environments exhibit different evolution actions. 相似文献
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简单介绍了采用炉子加热、 挥发性金属化合物和溅射产生ECR离子源的金属离子的3种方法和实验结果, 主要研究了铜、 锌、 镍和铁等多种电荷态离子的产生. 对3种方法分别进行了探讨.To satisfy the requirements of HIRFL (Heavy Ion Research Facility in Lanzhou), series of experiments have been done to produce metallic ion beams. By now, numerous methods have been tested, in which MIVOC (Metallic Ion from Volatile Compounds), heating oven methods and plasma sputter methods are all included. According to the experiments, the results of using MIVOC methods and heating oven methods are very good. In most of our researches, emphasis was put upon the ion production of iron, Nickel, Tantanum, copper of different charge states. Among the ion beams we have obtained, 210 μA Fe11+, 175 μA Fe12+, 142 μA Fe13+, 25 μA Fe16+, 64 μA Ni10+, 57 μA Ni13+, 31 μA Ni15+ and 15 μA Ni16+ are representative results. 相似文献