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21.
Four novel antimicrobial maleimido phenyl urea stabilizers 1–4 were synthesized from N-[4-(chlorocarbonyl) phenyl] maleimide with phenyl urea and its derivatives (p-methyl, o-chloro and p-carboxy). The effect of mixing maleimido phenyl urea stabilizer 2 with each of the reference stabilizers, dibasic lead carbonate (DBLC), cadmium-barium-zinc stearate (Cd-Ba-Zn stearate) or n-octyltin mercaptide (n-OTM), on the stabilization efficiency in thermal degradation of rigid PVC at 180 °C in air, has been investigated. Mixing was effected in the range of 0–100 wt% of stabilizer 2 relative to each of the reference stabilizers. The stabilizing efficiency was evaluated by measuring the length of the thermal stability period (Ts), the period during which no detectable amount of hydrogen chloride gas could be observed, and also from the rate of dehydrochlorination as measured by continuous potentiometric determination, and by the extent of discoloration of the degraded polymer samples. The results show a true synergistic effect from the combination of stabilizer 2 with any of the reference stabilizers. Mixing of the stabilizers improves the Ts values, decreases the rate of dehydrochlorination and lowers the extent of discoloration of the polymer. The maximum synergism was attained when stabilizer 2 is mixed with either of the three reference stabilizers in equivalent weight ratio (50%/50%). The observed synergism may be attributed to the different mechanisms by which the investigated and the reference stabilizers work. 相似文献
22.
Zakieh Yousefi Hossein Eshtiagh‐Hosseini Alireza Salimi Janet Soleimannejad 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(5):386-393
In the title compound, [Cu(C7H3N2O4)(C4H5N2)(H2O)], (I), pyridine‐2,6‐dicarboxylate (pydc2−), 2‐aminopyrimidine and aqua ligands coordinate the CuII centre through two N atoms, two carboxylate O atoms and one water O atom, respectively, to give a nominally distorted square‐pyramidal coordination geometry, a common arrangement for copper complexes containing the pydc2− ligand. Because of the presence of Cu...Xbridged contacts (X = N or O) between adjacent molecules in the crystal structures of (I) and three analogous previously reported compounds, and the corresponding uncertainty about the effective coordination number of the CuII centre, density functional theory (DFT) calculations were used to elucidate the degree of covalency in these contacts. The calculated Wiberg and Mayer bond‐order indices reveal that the Cu...O contact can be considered as a coordination bond, whereas the amine group forming a Cu...N contact is not an effective participant in the coordination environment. 相似文献
23.
24.
John Engbers 《Journal of Graph Theory》2017,85(4):780-787
For graphs G and H , an H‐coloring of G is a map from the vertices of G to the vertices of H that preserves edge adjacency. We consider the following extremal enumerative question: for a given H , which connected n‐vertex graph with minimum degree δ maximizes the number of H‐colorings? We show that for nonregular H and sufficiently large n , the complete bipartite graph is the unique maximizer. As a corollary, for nonregular H and sufficiently large n the graph is the unique k‐connected graph that maximizes the number of H‐colorings among all k‐connected graphs. Finally, we show that this conclusion does not hold for all regular H by exhibiting a connected n‐vertex graph with minimum degree δ that has more ‐colorings (for sufficiently large q and n ) than . 相似文献
25.
Jean MAWHIN 《数学年刊B辑(英文版)》2017,38(2):563-578
The existence of a zero for a holomorphic functions on a ball or on a rectangle under some sign conditions on the boundary generalizing Bolzano's ones for real functions on an interval is deduced in a very simple way from Cauchy's theorem for holomorphic functions.A more complicated proof,using Cauchy's argument principle,provides uniqueness of the zero,when the sign conditions on the boundary are strict.Applications are given to corresponding Brouwer fixed point theorems for holomorphic functions.Extensions to holomorphic mappings from Cn to Cn are obtained using Brouwer degree. 相似文献
26.
研究了一类具有收获率的脉冲Lotka-Volterra竞争合作系统的正概周期解.通过利用重合度理论延拓定理、概周期理论和不等式分析技巧,获得了系统至少存在8个正概周期解的充分条件,推广和改进了早期文献的相关结果. 相似文献
27.
矿井通风系统具有随机性、模糊性和不确定性等特征,一般单一的赋权评价法难以对其进行准确的优化评价.采用模糊层次分析法和熵权法的组合赋权法不仅可以提升对目标评价的准确性还能避免单一赋权的偶然性和局限性,结合可拓学的优度评价法,依据优度排序,得到最优方案.事实证明,基于组合赋权的可拓评价模型较其他评价方法更为客观,评价结果更加符合实际,可为解决类似优化方案问题提供一种新思路和方法. 相似文献
28.
以某低渗透油藏为对象,首先在数据挖掘的基础上制定了低渗透油藏注CO_2驱筛选标准.基于模糊综合评价法,建立了适用于低渗透油藏CO_2驱适宜度评价的模糊综合评价模型,并运用该模型对目标油藏注CO_2的适宜度进行了评价.计算结果表明目标油藏注气驱开发适应性较好.评价过程有效地降低了直接进行注气开发的风险,为之后低渗透油藏注气开发提供了技术和经济上的指导. 相似文献
29.
张春芝 《数学的实践与认识》2017,(6):221-225
在直觉I-fuzzy拓扑空间中定义了内部度,并研究了它的一些性质,接着给出了直觉I-fuzzy拓扑空间内部算子的概念,最后得到了从拓扑的直觉I-Fuzzy内部算子I出发,得到一个直觉I-fuzzy拓扑r,再利用r定义的内部算子恰好回到了I等结论. 相似文献
30.
将交通需求级别进行划分后,通过数据包络分析法计算交通需求匹配度和交通运行效率,近乎绝对细化交通运行表现,依据具有时间轴的四维交通状况模拟建立了全新多维度的交通评价体系。此外,利用模糊层次分析法确定道路交通安全评价指标体系中各个指标的权重,同时作出基于差异驱动原理的综合评价。最后,将交通的污染指标提炼为机动车的排放指标和电动车的耗电指标来衡量交通工具对环境的影响。 相似文献