全氟并五苯在半金属Ga表面的分子二聚化及自组装单层

利用超高真空扫描隧道显微镜(UHV-STM)和有机分子束沉积(OMBD)方法研究了全氟并五苯(perfluoropentancene,PFP)分子在半金属Ga表面的吸附和两维自组装. 在低覆盖度下单个PFP分子在Ga表面上表现出很高的迁移性. 在1分子单层(monolayer, ML)时PFP分子发生二聚化并在 Ga 表面上无序排列. 轻度热退火可导致PFP两维自组装: 二聚体排列为高度有序的一维分子带阵列, 带中 PFP二聚体排列为砖墙(brick wall)结构. 在高分辨 STM图中, PFP分子两端出现亮暗相反的圆形突起, 并且相邻分子的亮暗极性相反, 表明PFP分子带有电偶极矩, PFP二聚体带有电四极矩. 因此, PFP分子二聚体的形成机制可唯像解释为反向电偶极矩之间的静电吸引作用; 二聚体的砖墙排列结构可归结为同向电四极矩之间的静电排斥作用.     

Emittance measurement & optimization for the photocathode RF gun with laser profile shaping

The Laser Undulator Compact X-ray source(LUCX) is a test bench for a compact high brightness X-ray generator,based on inverse Compton Scattering at KEK,which requires high intensity multi-bunch trains with low transverse emittance.A photocathode RF gun with emittance compensation solenoid is used as an electron source.Much endeavor has been made to increase the beam intensity in the multi-bunch trains.The cavity of the RF gun is tuned into an unbalanced field in order to reduce space charge effects,so that ...     

二乙烯苯交联大孔聚甲基丙烯酸缩水甘油酯的合成及其结构性能的研究

选用反应性单体甲基丙烯酸缩水甘油酯（ＧＭＡ），以二乙烯苯（ＤＶＢ）作为交联剂。在致孔剂甲苯和正庚烷存在下，用悬浮聚合的方法制得了一系列大孔ＧＤ共聚物。通过测定树脂的孔结构性能及化学组成，讨论了不同交联剂用量和配比对共聚物结构的影响。     

Properties of the ν7/2-[503]（f7/2） band in 185Pt

High-spin states in ¹⁸⁵Pt have been reinvestigated via the reaction ¹⁷³Yb(¹⁶O, 4n) at a beam energy of 90 MeV. The previously known band based on the ν7/2^-[503](f_7/2) Nilsson orbital has been extended to higher spin states. Properties of the ν7/2^-[503](f_7/2) band have been discussed with an emphasis on the evolution of configuration while increasing the spin.     

A short history of nuclear magnetic moments and GT transitions

We summarize the history and our present understanding of nuclear magnetic moments and Gamow-Teller transitions.The roles of configuration mixing,meson exchange currents and relativistic effects are examined.Experimental evidence for the importance of tensor correlations is also discussed.     

Electronic structure of GaAs/A1GaAs quantum double rings in lateral electric field

A three-dimensional model of GaAs/A1GaAs quantum double rings in the lateral static electric field is investigated theoretically. The eigenvalue problem with the effective-mass approximation is solved by means of the finite-element method. The energy levels and wave functions of quantum-confined electrons and heavy holes are obtained and show an agreement with our previous theoretical and experimental studies. It is shown in the approximation of neglecting the Coulomb attraction between the electron and heavy hole that a relatively large Stark shift of exciton emission of 4 meV is attainable with an applied electric field of 0.7 kV/cm.     

An improved synthesis of (-)-7-isopropyl-cis-l-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization

(-)-7-Isopropyl-cis-1-amino-2-indanol,a key chiral auxiliary and ligand in the highly stereo-selective asymmetric 6π-azaelectrocyclization, has been prepared previously by two methods.Each however involved using of one extreme condition, i.e.high temperature or high pressure,for the respective reaction.A modified reaction route employed mild condition for synthesis was presented in this report.     

Template preparation of twisted nanoparticles of mesoporous silica

Optical isomers of N-lauroyl-l-(or-d-) alanine sodium salt {C 12 -l-(or-d-)AlaS} surfactants were used for the preparation of mesoporous silica nanoparticles with a twisted hexagonal rod-like morphology. Ther- mogravimetric analysis (TGA) was used to determine the temperature for template removal. Circular dichroism (CD) spectra of the surfactant solution with various compositions illustrated the formation and supramolecular assembly of protein-like molecular architecture leading to formation of twisted nan...     

Facile synthesis and characterization of a novel thiophene-fused polycyclic aromatics based on pyrene

A novel large thiophene-fused polycyclic aromatics 1 based on pyrene 5 has been synthesized,and its structure was confirmed by ¹H NMR,¹³C NMR,MS,UV -vis and elemental analysis.The key steps of the synthesis involved the Stille cross-coupling reaction and followed by selectiveβ-βoxidative cyclization of pendant thienyl rings by FeCl₃ under mild conditions.     

17C反应截面和去中子截面

利用日本理化学研究所的放射性束流线RIPS, 测量了能量为79A MeV的¹⁷C在¹²C反应靶上的反应截面, 并同时得到了¹⁷C的移去1个、2个及3个中子的截面; 分别利用有限力程Glauber模型和少体Glauber模型结合壳模型的谱因子分析了反应截面和移去1个中子截面, 研究了¹⁷C的密度分布、结构和价中子布居. 反应截面和中子移去截面是两个相互独立的量, 通过对两者的分析, 都可以得出¹⁷C由芯核¹⁶C和价中子组成, 并且价中子主要处于d_5/2轨道的结论. 总结了现有的碳同位素的反应截面和相互作用截面的工作.