Spectroscopic properties of thulium ions in bismuth silicate glass

A new type of bismuth silicate glass (Bi2O3-SiO2-ZnO-Al2O3-La2O3) doped with Tm2O3 is prepared by melt-quenching method. The thermal stability of the glass is examined by differential scanning calorimetry. No crystallization peak is found. Using the absorption and emission spectra, the absorption and emission cross-sections are calculated. Their maximum data are 2.9×10-21cm2 at 1663 nm and 4.7×10-21cm2 at 1826 nm, respectively. Using the Judd-Ofelt theory, the radiation transition probabilities and radiative lifetimes are obtained. The extended overlap integral method is applied to analyze energy transfer process among the Tm3+ ions. The transfer constants of cross-relaxation and energy migration among the Tm3+ ions at the 3H4 level are 7.60×10-40 and 14.98×10-40 cm6 /s, respectively. The critical transfer radius for cross-relaxation is 0.99 nm. The cross relaxation process is easy to realize and is favorable for obtaining ～2-μm laser.     

磁控溅射制备ZnO薄膜的结构及发光特性研究

采用射频反应磁控溅射法在玻璃衬底上制备出具有c轴高择优取向的ZnO薄膜,利用X射线衍射、扫描探针显微镜及荧光分光光度法研究了生长温度对ZnO薄膜微观结构及光致发光特性的影响。结果表明,合适的衬底温度有利于提高ZnO薄膜的结晶质量;在室温下测量样品的光致发光谱(PL),观察到波长位于400 nm左右的紫光、446 nm左右的蓝色发光峰及502 nm左右微弱的绿光峰,随衬底温度升高,样品的PL谱中紫光及蓝光强度逐渐增大,同时,绿光峰的强度也表现出一定程度的增强。经分析得出紫光应是激子发光所致,而锌填隙则是引起蓝光发射的主要原因,502 nm左右的绿光峰应该是氧的深能级缺陷造成的。此外,还测量了样品的吸收谱,并结合样品吸收谱的拟合结果对光致发光机理的分析作了进一步的验证。     

Tripartite states Bell-nonlocality sudden death in a quantum-critical environment

We demonstrate that multipartite Bell-inequalities violations can be fully destroyed in finite time in three-qubit states under a quantum-critical environment, which is an Ising model in a transverse field. We use the Mermin--Ardehali--Belinksii--Klyshko (MABK) inequality to detect the degree of nonlocality as measured by the extent of their violations. The effects of system-environment couplings, the size of degrees of freedom of environment and the strength of transverse field on the Bell-inequality violations are given for two different initial states, namely, the W class and GHZ class states. The results indicate that the Bell-inequality violations of the tripartite states will be completely destroyed by the decoherence under certain conditions.     

甲醇水蒸气重整制氢Cu-Zn-Al尖晶石催化剂的研究

以硝酸铜、硝酸锌、拟薄水铝石和柠檬酸为原料,采用湿式球磨法合成了Cu-Zn-Al三元尖晶石催化剂.通过TG-DTA、XRD、N2物理吸附-脱附、H2-TPR、XPS等表征手段,研究不同Cu/Zn/Al物质的量比对催化剂晶相组成、比表面积、还原性能、表面性质的影响,并通过甲醇水蒸气重整制氢反应(MSR)考察催化剂的缓释催...     

聚合物基板表面状态对异相接枝的影响研究

研究了对于羟丙基纤维素（HPC）基板进行表面修饰时,基板表面状态的调控 对基板表面化学接枝的影响。用双官能团化合物2,4-甲苯二异氰酸酯（TDI）作为 接枝桥梁,其对位的异氰酸酯基先和基板上的羟基反应,保留的邻位异氰酸酯基进 一步再与丙烯酸的羟基反应,让接枝在基板上的活性丙烯酸分子继续和丙烯酸溶液 聚合,通过这种途径在基板表面修饰聚丙烯酸。基板制备时,由于不同介质对HPC 基板表面的不同诱导作用,导致表面组成各异,大大影响了接枝反应的效果。红外 光谱和二次离子飞行时间质谱均证明了可以用2,4-甲苯-二异氰酸酯（TDI）分子 做接枝桥梁在基板表面异相接枝上羟基并进一步接枝聚丙烯酸,从而达到修饰基板 的目的。     

黄芩及其制剂中黄芩素和黄芩甙的

用毛细管区带电泳 -电化学检测法测定了黄芩及其制剂中黄芩素和黄芩甙的含量。研究了电极电位、电解液酸度和浓度、电泳电压及进样时间等对电泳的影响 ,得到了较为优化的测定条件。以直径为300μm的碳圆盘电极为检测电极 ,电极电位为0.90V(vsSCE) ,在100mmol/L硼酸盐缓冲液(pH9.0)中 ,上述两组分在8min内完全分离。黄芩素和黄芩甙浓度与电泳峰电流分别在5.0×10 -7～1.0×10 -3mol/L和1.0×10 -6～1.0×10 -3mol/L范围内呈良好线性 ,检出限分别为2.24×10 -7mol/L和5.48×10 -7mol/L。7次测定分别含5.0×10 -4mol/L黄芩素和黄芩甙试样溶液 ,峰高的相对标准偏差分别为3.53%和4.03%。     

聚硅氧烷/液晶复合膜的制备及其血液相容性研究

以含氢硅油和乙烯基硅油为基质,在氯铂酸催化下与胆甾醇油烯基碳酸酯液晶共混交联成一定强度的聚硅氧烷／液晶复合膜。借助偏光显微撞观察了不同液日含量在材料表面的状态,通过动态凝血实验、血小板粘附与变形实验、溶血实验等研究材料表面形态与血液相容性的关系。结果表明,含液晶２０％、３０％的液晶膜具有优良的抗凝血性能。     

Realization of Toffoli gate operation using four-level atoms in cavity QED system

This paper proposes a scheme for realization of a three-qubit Toffoli gate operation using three four-level atoms by a selective atom--field interaction in a cavity quantum electrodynamics system. In the proposed protocol, the quantum information is encoded on the stable ground states of atoms, and atomic spontaneous emission is negligible as the large atom--cavity detuning effectively suppresses the spontaneous decay of the atoms. The influence of the dissipation on fidelity and success probability of the three-qubit Toffoli gate is also discussed. The scheme can also be applied to realize an N-qubit Toffoli gate and the interaction time required does not rise with increasing the number of qubits.     

Thermal entanglement and teleportation in a three-qubit Heisenberg XXZ model with Dzyaloshinski--Moriya anisotropic antisymmetric interaction

This paper investigates the thermal pairwise entanglement of a three-qubit Heisenberg XXZ chain in the presence of the Dzyaloshinski--Moriya (DM) anisotropic antisymmetric interaction and quantum teleportation when using the Heisenberg chain as a channel. The entanglement dependences on the DM interaction and temperature are given in detail. It obtains the relation between the concurrence and average fidelity, and shows that the same concurrence can lead different average fidelities. Moreover, it finds the thermally entangled states which do not violate the Bell inequalities, and can still be used for quantum teleportation.     

Di-Ab-An、Q-Lc体系非平衡结晶及枝晶结晶学方向测试研究

本文对两个典型的硅酸盐体系:Di(透辉石)-Ab(钠长石)-An(钙长石)体系和Q(石英)-Lc(白榴石)体中结晶物相系进行了枝状形貌、枝体结晶学方向测试及结晶能力方面的研究.通过偏光显微镜(PL)、扫描电镜(SEM)观察发现:透辉石、低鳞石英、α-方石英都发育为枝晶,而斜长石发育成放射状球粒晶和针状晶体.通过电子背散射衍射(EBSD)测试确定出透辉石是沿<001>方向发育成枝晶的主干、低鳞石英是沿<100>和<010>方向发育成枝晶主干、α-方石英是沿两个<100>方向发育成枝晶的主干.并发现两个体系在相同降温速度下的结晶能力不同.