沙墙吸能作用对爆炸冲击波影响的实验研究

在爆炸冲击波作用下沙墙快速飞散,爆炸能量转换为沙粒动能和细化沙粒的摩擦做功,因此由沙袋堆积起来组成的沙墙对强冲击波具有消波吸能作用,对爆炸实验结构起到防护作用.本文利用366gTNT当量的球形药球中心起爆,进行了沙墙消波吸能作用下密闭柱形容器承受栽荷的实验.实验结果表明:沙墙使冲击波峰值超压降低最高可达6倍,到时也明显...     

高效液相色谱-串联质谱法测定动物源性食品中矮壮素残留

建立了高效液相色谱-串联质谱测定动物源性食品中矮壮素残留的分析方法。样品经含1%（v/v）乙酸的乙腈溶液提取、正己烷脱脂、阳离子固相萃取柱（PCX）净化,采用Venusil MP C18（2）色谱柱（150 mm×2.1 mm,3 μm）分离,以乙腈和0.1%（v/v）甲酸水溶液为流动相进行梯度洗脱,采用电喷雾电离、正离子模式扫描,多反应监测模式（MRM）检测,基质匹配标准曲线内标法定量。结果表明：矮壮素在0.200~500 μg/L范围内呈良好线性,相关系数（r²）均不低于0.9993,方法的定量限为0.500 μg/kg;以猪肉、牛肉、羊肉、鸡肉、鸡蛋、猪肾、牛肝、羊肾、鸡肝、牛奶为基质,矮壮素的平均加标回收率为93.4%~101%,相对标准偏差为2.3%~8.0%。该方法基质干扰小,灵敏度高,准确可靠,适用于动物源性食品中矮壮素残留的定量检测。     

Cross Sections of Elastic Electron and Positron Scattering from Proton-Rich Nuclei

We investigate the cross sections of the elastic electron or positron scat tering from 208 Pb, ^12C ^12,16O and ^28,32S by the relativistic partial-wave expansion method using the static charge density distribution from the self-consistent relativistic mean fiel model and also calculate the charge form factor for ^12＇16O and ^28,32S. The numerical results are compared with the available data. Calculations indicate that the extended charge density distributions of ^12O and ^28S have observable effects on the cross sections of the electron or positron scattering as well as the charge form factors.     

海水重金属电化学传感器检测系统

研制了一种新型的海水重金属电化学传感器流动分析系统.通过在线过滤、紫外线消解、电化学富集以及离子选择性电极电位测定等过程,实现对海水重金属的高灵敏、高选择性的快速检测.在海水基体条件下,对于镉、铅和铜的测定线性范围分别为1.0×10-9～1.0×10-7 mol/L,3.0×10-9～1.0×10-7 mol/L和1.0×10-9～1.0× 10-7 mol/L,相应检出限为2.8×10-10,6.6×10-10和5.1×10-10 mol/L,连续6次测定的RSD均小于5％,全程分析在25 min内完成.应用于实际海水样品分析,其测定结果与溶出伏安法一致.此传感器性能可靠、成本低廉,在海水重金属现场快速监测方面具有良好的应用前景.     

Scaling of anisotropic flows and nuclear equation of state in intermediate energy heavy ion collisions

Elliptic flow ($v_2$) and hexadecupole flow ($v_4$) of light clusters have been studied in detail for 25 MeV/nucleon $^{86}$Kr + $^{124}$Sn at large impact parameters by using a quantum molecular dynamics model with different potential parameters. Four sets of parameters including soft or hard equation of state (EOS) with or without symmetry energy term are used. Both number-of-nucleon ($A$) scaling of the elliptic flow versus transverse momentum ($p_{\rm t}$) and the scaling of $v_4/A^{2}$ versus $(p_{\rm t}/A)^2$ have been demonstrated for the light clusters in all above calculation conditions. It is also found that the ratio of $v_4/{v_2}^2$ maintains a constant of 1/2 which is independent of $p_{\rm t}$ for all the light fragments. Comparisons among different combinations of the EOS and the symmetry potential term show that the above scaling behaviours are sound and independent of the details of potential, while the strengths of flows are sensitive to the EOS and the symmetry potential term.     

Isoscaling of projectile-like fragments

In this paper, the isotopic and isotonic distributions of projectile fragmentation products have been simulated by a modified statistical abrasion--ablation model and the isoscaling behaviour of projectile-like fragments has been discussed. The isoscaling parameters α and β have been extracted respectively, for hot fragments before evaporation and cold fragments after evaporation. It looks that the evaporation has stronger effect on α than β. For cold fragments, a monotonic increase of α and β with the increase of Z and N is observed. The relation between isoscaling parameter and the change of isospin content is discussed.     

Disappearance of isospin effect in projectile fragmentation at intermediate energy

The 140~MeV/u ^40,48Ca+^9Be and ^58,64Ni+^9Be reactions are simulated by the statistical abrasion ablation model, and the simulation results are compared to the National Superconducting Cyclotron Laboratory (NSCL) experimental data. By comparing the fragment isotopic distributions of ^40,48Ca and ^58,64Ni, we study the isospin effect in the projectile fragmentation induced by the neutron-rich nuclei at intermediate energy experimentally and theoretically. It is found that the isospin effect in projectile fragmentation decreases and even disappears as the violence of the collision increases.     

Predictions for cross sections of light proton-rich isotopes in the ~(40)Ca + ~9Be reaction

The cross sections for Z=10–19 with isotopes T_z=-3/2 to-5 in the 140A Me V~(40)Ca+~9Be projectile fragmentation reaction have been predicted.An empirical formula based on the correlation between the cross section and average binding energy of an isotope has been adopted to predict the cross section.The binding energies in the AME16,WS4,and the theoretical prediction by the spherical relativistic continuum Hartree-Bogoliubov theory have been used.Meanwhile,the fracs parametrization and the modified statistical abrasion-ablation model are also used to predict the cross sections for the proton-rich isotopes.The predicted cross sections for the T_z=-3 isotopes are close to 10~(-10)mb,which hopefully can be studied experimentally.In addition,based on the predicted cross sections,Z=14 is suggested to be a new magic number in the light proton-rich nuclei with T_z-3/2,for which the phenomenon is much more evident than it is from the average binding energy per nucleon.     

Studies on the exotic structure of 23Al

The longitudinal momentum distribution (P_//) of fragments after one-proton removal from ²³Al and reaction cross sections (σ_R) for ^23,24Al on carbon target at 74A MeV have been measured simultaneously. An enhancement in σ_R is observed for ²³Al compared with ²⁴Al. The full width at half maximum of the P_// distribution for ²²Mg fragments has been determined to be 232±28 MeV/c. Analysis of P_// using the Few-Body Glauber Model indicates a dominant d-wave configuration for the valence proton in the ground state of ²³Al. The exotic structure in ²³Al is discussed.     

芳基汞化合物的性质研究(Ⅴ)——某些氯化芳基汞的质谱

本文研究了23种氯化芳基汞XC₆H₄HgCl的质谱。结果证明大多数氯化芳基汞的分子离子峰均较强,且各种氯化芳基汞生成碎片离子D([XC₆H₄]⁺)均较汞-氯键断裂生成碎片离子E([XC₆H₄Hg]⁺)容易,此结果可以看作是汞有机化合物开裂的普遍性规律。取代基的电性对于碎片离子的稳定性和丰度有明显的影响。就多数间、对位取代基而言,代表取代基对生成离子D速度的影响参数log(Z/Z_H)与HammettBrown常数σ⁺之间有良好的线性关系。邻乙酯基苯基氯化汞与间、对位取代物比较,难于发生McLafferty重排,此与分子内配位有关。