全文获取类型
收费全文 | 163篇 |
免费 | 10篇 |
国内免费 | 39篇 |
专业分类
化学 | 120篇 |
晶体学 | 2篇 |
力学 | 9篇 |
综合类 | 1篇 |
数学 | 36篇 |
物理学 | 44篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 12篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 10篇 |
2014年 | 5篇 |
2013年 | 7篇 |
2012年 | 12篇 |
2011年 | 14篇 |
2010年 | 16篇 |
2009年 | 15篇 |
2008年 | 12篇 |
2007年 | 7篇 |
2006年 | 11篇 |
2005年 | 4篇 |
2004年 | 20篇 |
2003年 | 1篇 |
2002年 | 5篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有212条查询结果,搜索用时 500 毫秒
101.
In this paper, new discrete analogue of high-order Cohen-Grossberg neural networks with varying delay is obtained by analysis and approximation techniques. The existence of periodic solution for discrete high-order Cohen-Grossberg neural networks with varying delay is studied by continuation theorem of coincidence degree theory, and sufficient condition is given to guarantee global exponential stability of periodic solution. Finally, an example is given to show the effectiveness of the results in this paper. 相似文献
102.
在HMBr2-Na2O-Al2O3-SiO2-La2O3-H2O体系中,采用水热法合成了高结晶度的La-Al-EU-1分子筛。通过XRD,FT-IR,XPS,TG-DTG和UV-Vis DRS等手段对合成样品进行分析。结果表明:随着原始溶胶中镧的质量分数增加,La-Al-EU-1分子筛晶胞体积膨胀;FT-IR骨架振动频率向低波数方向移动,在约980 cm-1处出现Si-O-La对称伸缩振动谱带;在λ=245 nm分子筛骨架O原子的成键2p电子向骨架四配位的La原子的空d轨道的p-d跃迁产生的特征峰强度增强;La3d3/2和La3d5/2伴峰电子结合能比La2O3高1.0 eV,氧的O1s电子结合能比La2O3高1.1 eV,La3d和O1s的电子结合能同步向高能方向移动,导致La-O键共价性减少,电子云密度降低,La-O键长增加,证明了La原子已经进入了分子筛骨架,并以La3+离子四配位方式存在;当ωLa0.82%,n(SiO2)/n(Al2O3)=50~80时,晶化时间24~41 h,可以合成高结晶度的La-Al-EU-1分子筛。 相似文献
103.
研究了氧化石墨烯(GO)对聚乙烯醇(PVA)/硼酸(borate)水凝胶线性及非线性流变性能的影响。 通过扫描电子显微镜、硼谱核磁共振波谱以及流变研究了水凝胶的流变性能。 结果表明,GO质量浓度在稀溶液区时,GO片层与PVA链间通过硼酸根离子形成了具有弹性活性的缔合点,有效地提高了水凝胶的平台模量、松弛时间和零切粘度;当GO进一步增加到亚浓溶液区,部分的交联剂被GO的团聚体捕获并处于非弹性活性的缔合状态,处于有效缔合状态的交联剂变少,导致平台模量、松弛时间和零切粘度降低。 稳态剪切测试下,样品在剪切增稠区的粘度增加随着GO添加量的增加明显加强,这与剪切场下取向的氧化石墨烯片层参与网络结构的重排有关。 相似文献
104.
Using urea as fuel, SrMgAl10O17:Eu, Dy phosphor was prepared by a combustion method. Its luminescence properties under ultraviolet (UV) excitation were investigated. Pure SrMgAl10O17 phase was formed by urea-nitrate solution combustion synthesis at 550 °C. The results indicated that the emission spectra of SrMgAl10O17:Eu, Dy has one main peak at 460 nm and one shoulder peak near 516 nm, which are ascribed to two different types of luminescent Eu2+ centers existing in the SrMgAl10O17 matrix crystal. The blue luminescence emission of SrMgAl10O17:Eu phosphors was improved under UV excitation by codoping Dy3+ ions. The SrMgAl10O17:Eu phosphors showed green afterglow (λ=516 nm) when Dy3+ ions were doped. Dy3+ ions not only successfully play the role of sensitizer for energy transfer in the system, but also act as trap levels and capture the free holes in the spinel blocks. 相似文献
105.
In this study, poly(3-hydroxybutyrate) (PHB)-based scaffolds containing nanosized hydroxyapatite (nHAP) were manufactured by gas-jet/electrospinning. The morphologies of the scaffolds were characterized. The effect of the scaffolds on attachment, proliferation and differentiation of the bone marrow stroma cells (BMSCs) were accessed by using scanning electron microscopy (SEM), methylthiazol tetrazolium (MTT) assay and alkaline phosphatase (ALP) activity. The results show that the gas-jet/electrospun scaffolds possess an extracellular matrix-like topography. In vitro studies describe that the scaffolds have positive effects on attachment, proliferation and differentiation of BMSCs in vitro. It can be concluded that the scaffolds combing the unique structural features generated by gas-jet/electrospinning with functional factors, have the potential to be used in bone tissue engineering. 相似文献
106.
High-sensitivity proton detected experiments in solid-state NMR have been recently demonstrated in proton diluted proteins as well as fully protonated samples under fast magic-angle spinning. One key element for performing successful proton detection is effective solvent suppression achieved by pulsed field gradients (PFG) and/or saturation pulses. Here we report a high-performance solvent suppression method that attenuates multiple solvent signals simultaneously by more than a factor of 10,000, achieved by an optimized combination of homospoil gradients and supercycled saturation pulses. This method, which we call Multiple Intense Solvent Suppression Intended for Sensitive Spectroscopic Investigation of Protonated Proteins, Instantly (MISSISSIPPI), can be applied without a PFG probe. It opens up new opportunities for two-dimensional heteronuclear correlation spectroscopy of hydrated proteins at natural abundance as well as high-sensitivity and multi-dimensional experimental investigation of protein-solvent interactions. 相似文献
107.
Proton-detected solid-state NMR spectroscopy of fully protonated proteins at 40 kHz magic-angle spinning 总被引:3,自引:0,他引:3
Zhou DH Shah G Cormos M Mullen C Sandoz D Rienstra CM 《Journal of the American Chemical Society》2007,129(38):11791-11801
Remarkable progress in solid-state NMR has enabled complete structure determination of uniformly labeled proteins in the size range of 5-10 kDa. Expanding these applications to larger or mass-limited systems requires further improvements in spectral sensitivity, for which inverse detection of 13C and 15N signals with 1H is one promising approach. Proton detection has previously been demonstrated to offer sensitivity benefits in the limit of sparse protonation or with approximately 30 kHz magic-angle spinning (MAS). Here we focus on experimental schemes for proteins with approximately 100% protonation. Full protonation simplifies sample preparation and permits more complete chemical shift information to be obtained from a single sample. We demonstrate experimental schemes using the fully protonated, uniformly 13C,15N-labeled protein GB1 at 40 kHz MAS rate with 1.6-mm rotors. At 500 MHz proton frequency, 1-ppm proton line widths were observed (500 +/- 150 Hz), and the sensitivity was enhanced by 3 and 4 times, respectively, versus direct 13C and 15N detection. The enhanced sensitivity enabled a family of 3D experiments for spectral assignment to be performed in a time-efficient manner with less than a micromole of protein. CANH, CONH, and NCAH 3D spectra provided sufficient resolution and sensitivity to make full backbone and partial side-chain proton assignments. At 750 MHz proton frequency and 40 kHz MAS rate, proton line widths improve further in an absolute sense (360 +/- 115 Hz). Sensitivity and resolution increase in a better than linear manner with increasing magnetic field, resulting in 14 times greater sensitivity for 1H detection relative to that of 15N detection. 相似文献
108.
Based on the property that carboxymethylcellulose (CMC ) can be de-graded to anhydroglucose residues by cellulase, the rate constant (K) of enzymatic degra-dation of CMC synthesized in the benzene-ethanol medium has been determined. Further-morel experimental equation K = 2.71× 10~(-2)(DS)~(-1.2) reflecting the relationship betweenK and the degree of substitution (DS) is correlated and used to describe chemical mi-crostructure uniformity of the distribution of substituents along chains effectively. Chainstructure parameters of enzymatic degradation products of CMC-the number of chainbreaks and the percentage of glucose released have been also measured. Average length ofsubstituted and unsubstituted chain segments are calculated simultaneously. Through thestudy of static and dynamic procedures of enzymatic degradation, the method to charac-terize the distribution of substituents of CMC along the chain has been improved. 相似文献
109.
110.