超临界CO2溶胀聚合法制备聚丙烯酸/尼龙1313及聚苯乙烯/尼龙1313共混物

超临界CO2溶胀聚合法制备聚丙烯酸/尼龙1313及聚苯乙烯/尼龙1313共混物;超临界CO2;聚丙烯酸;聚苯乙烯;尼龙1313;共混     

Angular distribution coefficients of Z(W) boson produced in e~+e~- collisions at s~(1/2) = 240 GeV

At the designed circular electron-positron collider(CEPC), similar to the hadron collider, the angular distribution coefficients of the decay lepton pair from the produced Z(W) boson in e~+e~- collisions are predicted. Their dependence on cosθZ(cosθW) are presented in four different polarization frames. Furthermore, the value of the angular distribution coefficients in different bins of cosθZ are presented in the C-S frame. In comparison with the case at the hadron collider, better accurate measurement for Z(W) is expected because there is less background, and W could be reconstructed from its leptonic decay channel. This works provides a method to precisely test the electroweak production mechanism or some effect induced from new physics in the future measurements at the CEPC.     

A single-event transient induced by a pulsed laser in a silicon-germanium heterojunction bipolar transistor

A study on the single event transient (SET) induced by a pulsed laser in a silicon-germanium (SiGe) heterojunction bipolar transistor (HBT) is presented in this work. The impacts of laser energy and collector load resistance on the SET are investigated in detail. The waveform, amplitude, and width of the SET pulse as well as collected charge are used to characterize the SET response. The experimental results are discussed in detail and it is demonstrated that the laser energy and load resistance significantly affect the SET in the SiGe HBT. Furthermore, the underlying physical mechanisms are analyzed and investigated, and a near-ideal exponential model is proposed for the first time to describe the discharge of laser-induced electrons via collector resistance to collector supply when both base-collector and collector-substrate junctions are reverse biased or weakly forward biased. Besides, it is found that an additional multi-path discharge would play an important role in the SET once the base-collector and collector-substrate junctions get strongly forward biased due to a strong transient step charge by the laser pulse.     

新型粘胶短纤维滤嘴的研制

为改善滤嘴对卷烟焦油的过滤效果,提高吸食品质,降低卷烟成本,本文选用粘胶短纤维作为卷烟过滤材料,开发了粘胶短纤维卷烟滤棒的成型工艺路线,制备了符合国家标准的新型卷烟滤棒。对不同规格纤维和成型工艺条件对滤棒性能的影响进行了较系统的研究。     

尼龙-66与衣康酸的接枝共聚反应

以过硫酸钾／硫酸为引发剂,使尼龙-66纤维与衣康酸进行接枝共聚。研究了尼龙-66纤维接枝率与硫酸浓度、过硫酸钾浓度、衣康酸浓度、反应温度、时间和预处理时间之间的关系。实验结果表明,硫酸浓度为0．5mol／L,反应温度50℃,反应时间40h时,接枝率较高,预处理时间对接枝率也有较大影响。     

聚十二烷二元酸丁二酯及其共聚酯的结晶行为研究

聚十二烷二元酸丁二酯是长碳链脂肪族聚酯中的一种新的聚合物材料．近年来，随着对环境问题的日益重视，利用脂肪族聚酯容易水解的特性，开发生物降解脂肪族聚酯材料的研究得到广泛开展．目前脂肪族二元酸酯的研究大多是围绕聚丁二酸酯、聚乙二酸酯及其共聚酯这一类降解速度较快的材料进行的．虽然这些聚酯已有部分商品化，但远远不能满足对特定降解速率材料的需求．长碳链脂肪族聚酯由于其具有类似PE的结构特征，又兼具聚酯的结构特征，有望在可降解包装材料、书籍装订、服装用热熔胶等方面获得广泛的应用．     

PA13N的合成和非等温结晶动力学研究

采用DSC方法研究了PA13N在不同降温速率下的结晶过程,并利用Avrami方程研究了其非等温结晶动力学。在非等温结晶过程中,随着降温速率的增大,结晶温度向低温偏移。综合利用Avrami方程得到Avrami指数为1.35~1.88和结晶速率常数Zc≈1;并求得其结晶活化能为-58.42kJ/mol。结果表明,PA13N的结晶能力小于其他脂肪族尼龙。     

星型共聚物PEO_3-b-PDMAEMA_3的pH敏感和温敏性研究

本课题组结合阴离子开环聚合技术和原子转移自由基聚合技术,以环氧乙烷(EO)和甲基丙烯酸[2-(二甲基氨基)乙基]酯(DMAEMA)为单体,合成了分子量可控、分子量分布窄的星型嵌段共聚物PEO3-b-PDMAEMA3。基于PEO的亲水性和PDMAEMA的温敏和pH敏感性,我们用荧光光谱仪、动态激光散射仪等比较研究了该系列星型嵌段共聚物在水溶液中的温敏及pH敏行为,证明其具有温敏和pH敏感性,而且其临界胶束化pH值要小于相应的线型嵌段共聚物的临界胶束化pH值。     

PF尼龙Ⅰ号和尼龙1010的结晶度与抗磨性能关系的研究

作者利用X-射线衍射法测定了PF尼龙Ⅰ号和尼龙1010在五种热历程下的结晶度,并且定量地研究了结晶度与抗磨性的关系,为控制工艺条件以提高尼龙的结晶度、增强其抗磨性提供了科学依据。试验结果表明,在五种热历程下,PF尼龙Ⅰ号的结晶性能与抗磨性均比尼龙1010的好。两种尼龙的抗磨性均随结晶度的提高而提高。     

Perturbative QCD for J/ψ inclusive production via initial state radiation in e~+e~- collisions

The process e+e-→J/ψ+X with the center-of-mass(CM)energy in the range from 3.7 to 10.6 GeV is calculated up to the next-to-leading order(NLO)in quantum chromodynamics(QCD).At 10.6 GeV,the result is consistent with the experimental result from Belle.However,the predictions are much smaller than the background in the measurements at BESIII in the low CM energy range from 3.7 to 4.6 GeV.This indicates that the convergence of the QCD perturbative expansion becomes worse as the CM energy is closer to the inclusive J/ψ production threshold.For a further study of the QCD mechanism of J/ψ production in e~+e~-collisions with different CM energies,the initial state radiation effect of e~+e~-→J/ψ +gg and e~+e~-→J/ψ+cc are calculated in QCD NLO.The results are plotted and the number of events for different CM energy bins are provided for SuperKEKB.This provides a method to precisely test the validity of perturbative predictions for J/ψ production in future measurements.