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51.
QIN Guo-Yi 《理论物理通讯》2003,40(12)
An improved valence force field model (VFFM) is suggested to calculate the phonon modes in both bulk specimens and quantum dots (QDs) of AlAs taking account of the effect of transverse effective charges (TCs) correctly.The resultant dispersions of AlAs bulk phonons are in accord better with the results carefully fitted to the experimental data by using 11-parameters rigid-ion model, than those got by ordinary VFFM, especially in the region of near F point. For AlAs QDs, TCs are evaluated bond by bond for each phonon mode of QD and its effect on the change of the force on atoms is taken into account to modify further the phonon spectrum. The frequency spectra and densities of phonon states of different irreducible representations calculated by using improved VFFM are compared with the results of ordinary VFFM. The correct evaluation of the TCs is not only important in calculating the phonon spectrum of both bulk and QD specimens accurately, but is also in the further discussion of the electron-phonon (e-ph) interaction, which can be directly related to TCs of ions in QD. 相似文献
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53.
Memory switching of germanium tellurium amorphous semiconductor 总被引:1,自引:0,他引:1
M.M. Abdel-Aziz 《Applied Surface Science》2006,253(4):2059-2065
The dc conductivity and switching properties of amorphous GeTe thin film of thickness 262 nm are investigated in the temperature range 303-373 K. The activation energy ΔEσ, the room temperature electrical conductivity σRT and the pre-exponential factor σ0 were measured and validated for the tested sample. The conduction activation energy ΔEσ is calculated. The I-V characteristic curves of the thin film samples showing a memory switching at the turnover point (TOP) from high resistance state (OFF state) to the negative differential resistance state (NDRS) (ON state). It is found that the mean values of the threshold electrical field Eth decreased exponentially with increasing temperatures in the investigated range. The switching activation energy ΔEth is calculated. Measurements of the dissipated threshold power Pth and the threshold resistance Rth were carried out at TOP point at different temperatures of the samples. The activation energies ΔER and ΔEP caused by resistance and power respectively are deduced. The results obtained support thermal model for initiating switching process in this system. 相似文献
54.
光纤环形外腔半导体激光器频偏特性研究 总被引:1,自引:1,他引:0
本文给出了在环形光纤外腔光反馈之下半导体激光器频偏特性的小信号分析理论.分析表明,尤其在千兆赫以下的调制频段中,耦合腔相移、内外腔光耦合强度及内外腔光场相位失谐对频偏功率比均有显著影响.可望用作强度调制直接检测高速率、长距离光纤通信系统中的光源. 相似文献
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Shvalagin V. V. Stroyuk A. L. Kuchmii S. Ya. 《Theoretical and Experimental Chemistry》2004,40(3):149-153
The photoreduction of Cu2+ at the surface of ZnO nanoparticles and ZnO/Ag nanostructures was investigated. The spectral characteristics of the obtained ZnO/Cu and ZnO/Ag/Cu composites were studied in relation to the reaction conditions. It was shown that the ZnO/Ag nanoparticles have higher photocatalytic activity in the reduction of Cu2+ ions than the individual ZnO particles. 相似文献
58.
Based upon a thermodynamical approach, the generalized Onsager type of relaxation of van der Waals networks is presented. By linearly and identically coupling the set hidden variables to the network, the memory function of the system can be related to the equilibrium strain-energy function. The relaxation behavior of real networks on stretching can quantitatively be described by means of a distribution of relaxation times known from small strain experiments. Some new and interesting conclusions are discussed as to how the macroscopically non-linear visco-elastic response might be interpreted. 相似文献
59.
The effects of radiofrequency (RF) (1–4) and magnetic fields (5–9) on the behavior of aqueous solutions and suspensions have been a popular subject in recent years. The mechanism of the magnetic “water memory” effect, though, is still largely unknown (5). In this work, we present evidence that the primary “receptor” of the electromagnetic radiation is a gas/liquid interface. Gas can be either already present in water or produced by the effects of electromagnetic fields. Perturbed gas/liquid interfaces require hours to equilibrate. Certain RF and magnetic signals also produce reactive oxygen and hydrogen species (superoxide, hydrogen peroxide, hydrogen, atomic hydrogen). The perturbed gas/liquid interface modifies the hydrogen bonding networks in water and also the hydration of ions and interfaces. Careful outgassing removes all of the effects of the electromagnetic fields, including the magnetic memory effect. The amplitude of the applied field influences the observed effects. Different amplitudes of RF radiation perturb the interfacial water in different ways and consequently affect the behavior of colloids and ions in specific manners. For instance, the bulk and template precipitation of calcium carbonate, zeta potentials of suspended colloids, rate of dissolution of colloidal silica, and attachment of colloidal silica to metal surfaces are modified in specific ways with the low amplitude or high amplitude RF treatments described in this paper. The solubility/diffusivity of gas species is also modified in a different manner, and it is probably at the core of the specificity of the RF amplitude effects. 相似文献
60.
本文综述了半导体氧化物光催化裂解水制氢的反应机理,以及近年来半导体光催化裂解水制氢的研究进展。讨论了各种因素对材料光催化性能的影响以及改性方法,并对今后的研究方向提出了一些建议。 相似文献