Memory effects in gas chromatographic detection with a microwave-induced plasma

Capillary gas chromatography coupled to microwave-inducedplasma detection furnishes sensitivity adequate for trace analysis when the signal is monitored at a carbon emission line. Work performed with one of these systems at high electronic gain for the carbon signal has revealed solvent band widths in excess of four minutes; these impeded quantification of peaks eluting after the solvent. This report discusses two phenomena which could be related to the unexpected intensity of this solvent response: photomultiplier tube saturation and carbon deposits in the quartz plasma discharge tube.     

High-Throughput Screening of Ten Microcystins and Nodularins, Cyanobacterial Peptide Hepatotoxins, by Reversed-Phase Liquid Chromatography-Electrospray Ionisation Mass Spectrometry

Liquid chromatography-electrospray ionisation mass spectrometry was evaluated in the high-throughput analysis of microcystins and nodularins, cyanobacterial peptide hepatotoxins. Extracts originating from cyanobacterial strains and field material were separated on a 30 mm × 4 mm I.D. Merck Purospher STAR RP-18e column using a rapid gradient of aqueous formic acid and acetonitrile, ionised by electrospray technique and analysed on a Micromass Quattro II triple-quadrupole mass spectrometer operated in the selected ion recording (SIR) mode. The total analysis time per sample was 2.8 min corresponding to 514 samples a day. The system showed good robustness during a series of 320 repetitive injections of a field sample containing three major microcystins.     

Comparison of detection efficiencies of negatively charged gold-alkanethiolate-, gold-sulfur- and gold-clusters in ToF-SIMS

In order to improve quantification of high mass ions, the influence of cluster composition on detection efficiencies has been studied using a TOF-SIMS IV with the extended capability of postaccelerating ions up to 20 keV. In this experimental study, we focus on the comparison of detection efficiencies for three types of negatively charged secondary cluster ions: gold-alkanethiolate-clusters (Au_xM_y), gold-sulfur-clusters (Au_xS_y) and gold-clusters (Au_x). The clusters were sputtered from self-assembled monolayers of hexadecanethiols on gold substrates using 10 keV Ar⁺ primary ions. The detection efficiencies were derived on the basis of a function for the secondary electron yield and a fourth-order approximated Poisson probability distribution for electron propagation and amplification within the microchannel plate.In addition to the well-known dependence of detection efficiencies on ion mass and energy, which has already been studied for positively charged ions, we were able to show a similar behaviour for the investigated negatively charged secondary ions. We have observed major variations among the three types of clusters at similar mass and energy as predicted in a theoretical approach. The observed differences are due to the different composition of the investigated clusters which has a major influence on the kinetic ion induced electron emission within the microchannel plate. For the first time it was possible to experimentally verify these predictions for detection efficiencies.     

激光磁共振用于对NO_2分子的定量测量

本文叙述了采用CO激光磁共振方法对NO_2分子作定量测量,给出了激光磁共振信号幅度的数学表达式以及信号与分子浓度、激光功率等实验参数之间的依赖关系,实验结果与理论分析一致。     

波长检测技术在温度测量中的应用

提出一种波长检测技术实现温度测量的方法,利用FBG传感器对温度等物理量实施监测,具有测试精度高,应用场合不受限制等特点,当环境参数发生变化时,光纤光栅的有效折射率和光栅周期会受到影响,将引起光纤光栅峰值波长的偏移,依据反射光谱结构的变化,可知道其温度的变化趋势。实验测试结果表明,在温度变化0.1°,波长变化1pm,温度和波长具有良好的线性关系。     

单分子光子源光子统计的非平衡探测

研究了在Hanbury Brown Twiss探测方式下，非平衡探测系统对光子统计测量的影响。通过记录2个单光子计数器响应的单分子光子源输出的每一个事件，分析具有泊松统计背景的实际单分子光子源的光子统计特性，讨论并给出了非平衡探测系统的单分子光子源Mandel参数。研究表明：非理想的50／50分束器、非理想的线性传输效率和非理想的探测器都会使单分子光子源Mandel参数的实际测量结果小于平衡系统的Mandel参数，最后给出了单分子光子源Mandel参数的非理想探测的校正表达式。     

一类非线性方程解的存在和唯一性及在图像中的应用

本文我们给出一个修正的非线性扩散方程模型，与Cotte Lions和Morel的模型相比该模型有许多实质上的优点。主要的想法是把原来去噪声部分：卷积Gauss过程替代为解一个有界区域上的线性抛物方程问题，因此避开了对初始数值如何全平面延拓的问题。我们从数学上的证明该问题解的存在性和适定性，同时给出对矩形域情况的解的级数形式。最后我们给基于本模型的数值计算差分模型，并且给出几个具体图像在该模型下处理结果。     

离轴球形粒子对高斯波束的散射光通量的计算

利用矢量球谐函数展开的方法,研究了离轴球形粒子对椭圆高斯波束的散射。根据其远区散射场的形式,得出了归一化散射场的斯托克斯参量(散射强度)与颗粒直径、折射率以及散射角的关系。建立了计算离轴球形粒子对高斯波束散射通量的解析模型,计算了散射光在任意散射方向上的光通量,得到了前向任意立体角内散射通量的计算公式,为激光散射探测提供了理论依据。     

位相物体激光全息二次曝光法无损检测

为借助激光全息进行无损检测，获得位相物体的信息，对位相物体激光全息二次曝光法无损检测进行了研究，指出一般的二次曝光法测位相物体典型光路的缺点，提出了物光波2次通过样品的改进方案。利用此方案对一些位相物体(如普通玻璃和有机玻璃)作了无损检测实验，得到了较满意的实验结果。与普通检测方法相比，该方法具有精度高、结果直接可靠、不损伤物体等诸多优点。对改进方案稍作改动，即可用于塑料制品和玻璃制品生产线对加工产品进行在线产品质量监控。