全文获取类型
收费全文 | 1651篇 |
免费 | 250篇 |
国内免费 | 155篇 |
专业分类
化学 | 890篇 |
晶体学 | 21篇 |
力学 | 256篇 |
综合类 | 37篇 |
数学 | 79篇 |
物理学 | 773篇 |
出版年
2024年 | 5篇 |
2023年 | 23篇 |
2022年 | 41篇 |
2021年 | 67篇 |
2020年 | 68篇 |
2019年 | 47篇 |
2018年 | 37篇 |
2017年 | 69篇 |
2016年 | 74篇 |
2015年 | 68篇 |
2014年 | 57篇 |
2013年 | 182篇 |
2012年 | 103篇 |
2011年 | 89篇 |
2010年 | 83篇 |
2009年 | 84篇 |
2008年 | 67篇 |
2007年 | 100篇 |
2006年 | 96篇 |
2005年 | 67篇 |
2004年 | 55篇 |
2003年 | 64篇 |
2002年 | 55篇 |
2001年 | 61篇 |
2000年 | 49篇 |
1999年 | 40篇 |
1998年 | 50篇 |
1997年 | 35篇 |
1996年 | 29篇 |
1995年 | 37篇 |
1994年 | 38篇 |
1993年 | 24篇 |
1992年 | 13篇 |
1991年 | 12篇 |
1990年 | 18篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1959年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有2056条查询结果,搜索用时 718 毫秒
31.
32.
33.
Anna Worobiec Lucyna Samek Zoya Spolnik Velichka Kontozova Elzbieta Stefaniak René Van Grieken 《Mikrochimica acta》2006,156(3-4):253-261
The St. Michael Archangel’s Church in Szalowa, Poland, was selected for closer investigation with respect to the indoor/outdoor
air exchange and its influence on the air quality and work arts preservation. Chemical composition, size and abundance of
particulate matter and concentration of gases NO2, SO2, O3 inside and outside the church were determined. To study seasonal variation of the weather condition (temperature, inversion
level, wind direction) and the influence of seasonal sources of the air pollution (like heating of the nearby houses), samples
were collected in winter and summer time. It was stated that suspended particulate matter inside the wooden church has in
general an outdoor source. Several groups of particles were distinguished such as the organic ones, soil dust, nitrates and
sulphates. In case of organic and soil dust particles, the concentration inside was higher than outside. From the results,
in comparison to literature data, one can conclude that accumulation of particulate suspended matter in the church is more
intense than in other types of buildings. Gaseous pollutants were detected but their concentration was negligible. 相似文献
34.
35.
Interfacial layers have been widely applied to study the formation and stability of emulsion-based systems. However, the application of isolated interfaces to address digestibility of emulsions is often limited because of the complexity of experimental methods and results. This review summarizes the latest developments in analytical methods and literature data on effects of digestion on interfacial layers. Particular emphasis is given to understand the changes on interfacial magnitudes during oral, gastric, and duodenal digestion, either applied separately or sequentially. Limitations of interfacial aspects and key factors that influence emulsion microstructure in bulk and lipid digestion are identified. Understanding the behavior of interfacial layers upon gastrointestinal digestion promotes an accurate tracking of the physiological fate of emulsions. 相似文献
36.
M. Paluch 《Colloid and polymer science》1998,276(7):648-652
The results of experimental studies of the adsorption at the solution/air interface from an aqueous mixture: 2,4,6-trimethylphenol–2,4,6-trichlorophenol
are presented. The surface properties of the above-mentioned mixture were studied by surface potential and surface tension
measurements. These measurements were carried out as a function of the concentration of 2,4,6-trimethylphenol aqueous solution
at a constant concentration of 2,4,6-trichlorophenol.
Using the results obtained and based on the Gibbs equation, Helmholtz formula and Motomura’s method the relative surface excesses
of adsorbed substances, effective dipole moments, surface molar fractions of solutes and miscibility of adsorbed films were
determined.
Received: 7 November 1997 Accepted: 26 February 1998 相似文献
37.
Suset Rodríguez-Alemn Ernesto M. Hernndez-Cooper Rolando Prez-lvarez Jos A. Otero 《Molecules (Basel, Switzerland)》2021,26(2)
Front tracking and enthalpy methods used to study phase change processes are based on a local thermal energy balance at the liquid–solid interface where mass accommodation methods are also used to account for the density change during the phase transition. Recently, it has been shown that a local thermal balance at the interface does not reproduce the thermodynamic equilibrium in adiabatic systems. Total thermal balance through the entire liquid–solid system can predict the correct thermodynamic equilibrium values of melted (solidified) mass, system size, and interface position. In this work, total thermal balance is applied to systems with isothermal–adiabatic boundary conditions to estimate the sensible and latent heat stored (released) by and salts which are used as high-temperature phase change materials. Relative percent differences between the solutions obtained with a local thermal balance at the interface and a total thermal balance for the thermal energy absorbed or released by high-temperature phase change materials are obtained. According to the total thermal balance proposed, a correction to the liquid–solid interface dynamics is introduced, which accounts for an extra amount of energy absorbed or released during the phase transition. It is shown that melting or solidification rates are modified by using a total thermal balance through the entire system. Finally, the numerical and semi-analytical methods illustrate that volume changes and the fraction of melted (solidified) solid (liquid) estimated through a local thermal balance at the interface are not invariant in adiabatic systems. The invariance of numerical and semi-analytical solutions in adiabatic systems is significantly improved through the proposed model. 相似文献
38.
39.
As an alternative to acid pretreated UCON and FFAP capillaries for the analysis of wide-boiling free fatty acid mixtures, OV-1 : FFAP phase mixtures were used on high-temperature silylated inert glass capillary columns. The HETP-carrier gas velocity curves, peak asymmetry factors, coating efficiency, gas phase and stationary phase contributions to the mass transfer resistance were determined for various OV-1 : FFAP ratios. Mixed-phase capillaries showed optimum performance at a 2 : 1 OV-1 : FFAP ratio. The thermal and long-term stability of OV-1-stabilized FFAP columns surpassed those of the UCON and pure FFAP reference column used. 相似文献
40.
用环形扩散管和滤纸联用采样技术采集空气中氨和铵盐 总被引:1,自引:0,他引:1
建立了环形扩散管和滤纸采样夹联用,分形态同时采集空气中所态氨和颗粒态铵盐的方法。在同一气流中,采用涂渍1.5%草酸乙醇水溶液的环形扩散管采集气态氨,用浸渍上述试剂的玻璃纤维纸和慢速定量滤纸分别采集颗粒安和第一层滤纸上的铵盐挥发产生的氨气。用靛酚蓝比色法分别测定氨和铵盐。当采气流速为1.0L/min时,采样效率高于98.2%。将本法测得的氨气和铵盐的总量与标准采样方法的测定结果比较。无显著性差异(P 相似文献