全文获取类型
收费全文 | 4401篇 |
免费 | 474篇 |
国内免费 | 496篇 |
专业分类
化学 | 1690篇 |
晶体学 | 149篇 |
力学 | 635篇 |
综合类 | 55篇 |
数学 | 917篇 |
物理学 | 1925篇 |
出版年
2024年 | 6篇 |
2023年 | 33篇 |
2022年 | 51篇 |
2021年 | 75篇 |
2020年 | 88篇 |
2019年 | 75篇 |
2018年 | 71篇 |
2017年 | 96篇 |
2016年 | 127篇 |
2015年 | 93篇 |
2014年 | 203篇 |
2013年 | 294篇 |
2012年 | 235篇 |
2011年 | 257篇 |
2010年 | 232篇 |
2009年 | 298篇 |
2008年 | 308篇 |
2007年 | 315篇 |
2006年 | 245篇 |
2005年 | 302篇 |
2004年 | 271篇 |
2003年 | 193篇 |
2002年 | 190篇 |
2001年 | 152篇 |
2000年 | 135篇 |
1999年 | 135篇 |
1998年 | 122篇 |
1997年 | 114篇 |
1996年 | 82篇 |
1995年 | 80篇 |
1994年 | 66篇 |
1993年 | 63篇 |
1992年 | 75篇 |
1991年 | 38篇 |
1990年 | 30篇 |
1989年 | 32篇 |
1988年 | 30篇 |
1987年 | 27篇 |
1986年 | 22篇 |
1985年 | 9篇 |
1984年 | 12篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 14篇 |
1980年 | 4篇 |
1979年 | 20篇 |
1978年 | 12篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1973年 | 2篇 |
排序方式: 共有5371条查询结果,搜索用时 15 毫秒
91.
92.
IntroductionMicellarelectrokineticchromatography (MEKC)wasinventedtoextendtheutilityofcapillaryelectrophoresis(CE)andpermittedtheseparationandanalysisofneutralcompounds .ButjustlikeothermodesofCE ,MEKCarehamperedbythelowconcentrationsensitivityoftheultra … 相似文献
93.
Some of the blending interpolation methods (which) stated by a convex combination technique are presented. This includes C1 ,C2 blending triangular interpolanls and C1 -blending quadrilateral inter polanls for surfaces. The mentioned methods can be generalized to the construction of C" blending interpolants. 相似文献
94.
利用Bridgman-Stockbarger方法在氩气气氛下生长出KZnF3:Eu^3+单晶,测定了晶体的激发光谱、荧光发射光谱和ESR谱,讨论了Eu离子的取代格位。 相似文献
95.
96.
97.
一阶导数停流法测定药物和饮用水中的铁 总被引:3,自引:0,他引:3
本文利用Fe^3+离子催化H2O2氧化四甲基对苯二胺的反应,将采用停流技术获得的动力学曲线转换成一阶导数曲线,根据导数峰高值与Fe^3+离子浓度的线性关系测定药物和自来水中的含量,本方法的线性范围为4.0-40.0ngFe^3+/ml,相对标准偏差小于2.5%,标准加入回收率在98.7%-101%之间,检测限为1.92ngFe^3+/ml。对照实验结果表明,导数动力学法比一般非导数动力学法具有线关 相似文献
98.
Krzysztof Maruszewski Marek Jasiorski Witold Wacławek Wiesław Stręk Marek Lisowski 《Journal of Sol-Gel Science and Technology》1998,13(1-3):585-586
A series of silicate xerogels with entrapped chiral amino acids have been obtained via sol-gel technology. The transparent, glassy samples obtained exhibit chirality in the bulk due to the presence of the entrapped asymmetric molecules. Measurements of the optical activity of the doped xerogel samples revealed that the entrapment did not significantly influence the optical activity observed for liquid solutions of the amino acids. Thus, the sol-gel method enables the preparation of amorphous optical materials exhibiting properties of strictly spatially defined molecular systems. Apart from the obvious optical applications, such porous materials with asymmetric centers might find interesting applications in chiral chemical syntheses and separations. 相似文献
99.
Underpotential deposition studies of copper on glassy carbon 总被引:1,自引:0,他引:1
Studies on the deposition and dissolution of copper from 0·5 M sulphuric acid solutions onto glassy carbon (GC) using potential
sweep techniques indicated that an additional peak occurs at higher positive potentials than the bulk stripping peak. This
peak is identified as due to the stripping of underpotential deposited (UPD) copper. Results of investigations on the effect
of sweep rate, deposition potential and time of deposition on the peak characteristics of UPD and bulk deposited copper are
also reported. 相似文献
100.
Four new stationary phases for HPLC were prepared by modifying silica gel with a trifrnctional aminoalkyl silane. A conjugated π-electron system was linked to the amino group either directly or with a carboxylic anhydride as a spacer in between. Characterization and dynamic measurements of the new stationary phases were performed by solid state NMR spectroscopy. The results of the 29si and 13C CP/MAS techniques were compared with the recently developed 1H MAS-only technique. Despite strong homonuclear dipole-dipole interactions it was possible to obtain well resolved 1H MAS spectra of those stationaru phases with a high degree of crosslinking. Limited mobility of the aromatic ligand fragments is common for all examined stationaryu phases. The chromatographic properties of the new phases were tested by their ability tio sepatate a mixture of eight PAHS. It could be shown that the π-π interaction mechanism is responsible for the separation of the eight PAHs, because the elution order of the PAHs did not changem despite the use of both a nonpolar mobile phase (n-heptane) and a polar mobile phase (methanol/ water mixture). 相似文献