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91.
92.
粉煤灰与复合添加剂的固相反应过程分析 总被引:6,自引:3,他引:6
煤灰分中主要矿物质之间的反应对灰分特性有着重要影响。本文在具有温控的小型高温反应器中对粉煤灰和复合添加剂所组成的混合灰样进行了静态煅烧试验,并对煅烧后的灰样进行了X射线衍射分析(XRD),着重讨论了温度和时间以及复合添加剂量对灰分矿相组成特性的影响。试验结果表明:当温度低于1200℃时,灰色中主要是游离态的氧化物和部分新生成的矿物如钙黄长石,硅酸二钙;当温度在1200℃-1300℃时,灰分中的主要矿物是钙黄长石,当温度在1320℃-1350℃时,灰分主要矿物是硅酸二钙,同时存在一定量的硅酸三钙、铝酸三钙、铁铝酸四钙以及硫铝酸钙。随着灰分中氧化钙的含量增加,高碱性矿物含量逐渐增大,同时高温下加热持续时间过长,部分新生成的矿物将发生分解。 相似文献
93.
94.
Runru Liu Dapeng Xu Shuang Li Zhe Lü Yanfeng Xue Deyong Wang Wenhui Su 《Frontiers of Chemistry in China》2006,1(4):398-401
In this paper, perovskite oxide SmCoO3 was prepared by the solid-state reaction method using Co2O3 and Sm2O3 as raw materials. The structure and properties of the samples were investigated by XRD, Raman spectral techniques, and DC
measurements and so on. The results of XRD and Raman spectra showed that the mixtures of Co2O3 and Sm2O3 can react to produce a single phase perovskite oxide SmCoO3 around 1353 K. The single-phase SmCoO3 changes from an insulator to a semi-conductor and transition occurs around 470 K. The thermal expansion coefficient (2.17
× 10−5 K−1) of the single-phase SmCoO3 is approximately equal to that of doped LaGaO3, but much bigger than that of SDC(Ce0.85Sm0.15O2) above 873 K. 相似文献
95.
Qiong Yu Lai Ji Zheng LuXiao Bo Su Xiao Yang Ji 《Journal of solid state chemistry》2002,165(2):312-316
Spinel compound LiNi1−xMnxVO4 (0≤x≤0.4) had been prepared by using the moist chemical method. X-ray diffraction spectra showed that the lattice constant increased with x in the LiNi1−xMnxVO4, XPS spectra indicating that Li1s had a chemical shift towards lesser binding energy, and manganese in LiNi1−xMnxVO4 existing as the mixed valence of Mn2+ and Mn3+. The electrochemical charge and discharge testing at a current density of 0.1 mA/cm2 between the potentials of 4.0 and 3.0 V vs Li/Li+ in 1 mol/dm3 LiPF6/EC+DEC (1:1 by volume) at 25°C showed that LiNi1−xMnxVO4 cell has a better rechargeability, but a lower cell voltage of 4.0 V vs Li/Li+ than that without the doping sample, and the capacity and the cycle efficiency of the Li/LiNi1−xMnxVO4 cells increased with x in the LiNi1−xMnxVO4. 相似文献
96.
Małgorzata Olejnik Teresa Szprengier-Juszkiewicz Piotr Jedziniak Jan Żmudzki 《Accreditation and quality assurance》2007,12(12):637-641
In this paper, the case of FAPAS PT 0270 “Doramectin and Oxfendazole in Sheep Liver” is discussed. During evaluation of the
data received from participants (determination of total, oxidised oxfendazole residue and calculation of the sum of oxfendazole
and oxfendazole sulfone residues), significant differences were observed between the results obtained by use of two analytical
approaches. This phenomenon can be explained by the route of oxfendazole metabolism, which results in the presence of fenbendazole
in the sample. This was not predicted by the provider; consequently, not all the necessary tests on the material were conducted.
Due to the high uncertainty of the z-scores in this test, the results of the PT cannot be used for purposes of evaluation, and the benefits of participation in
PT 0270 are questionable. 相似文献
97.
介绍废弃线路板中有回收价值元素和有害物质分析的采样、制样及检测技术。样品经过分类采样、剪切破碎和高温灰化制样,采用样品全分析或副批混合样分析。通过提高称样量、多次测定求平均值的办法,火试金富集-重量法测定贵金属金、银。湿法王水溶解样品,碘量法测定主体元素铜。电感耦合等离子体发射光谱(ICP-AES)法测定其它杂质元素,被测元素质量浓度在0~10μg/mL范围内与光谱强度呈良好线性关系,相关系数均大于0.9998。测定结果的相对标准偏差小于10%(n=5),加标回收率为97.0%~102.5%。该方法简单、快速,有效地解决了线路板样品不均匀而难采样,以及硬度、韧性强制样难,金属易包裹难分解的技术瓶颈,测定结果准确,具有代表性。该方法适用于废弃线路板化学成分分析,其它废弃电子产品检测可参考此方法。 相似文献
98.
With a set of equations for the self-consistent large-signal interaction derived in this paper, the bandwidth characteristics of a non-reflection-type gyrotron-TWA using a tapered waveguide and tapered magnetic field system have been analysed. Numerical calculations indicate that under defined conditions an instantaneous bandwidth of nearly 10 % at a center frequency of 35 GHz with a length of the order of only8 cm of the rf interaction region could be achieved. 相似文献
99.
100.
Arthur Cohen 《Journal of multivariate analysis》1977,7(3):454-460
Let Ui = (Xi, Yi), i = 1, 2,…, n, be a random sample from a bivariate normal distribution with mean μ = (μx, μy) and covariance matrix . Let Xi, i = n + 1,…, N represent additional independent observations on the X population. Consider the hypothesis testing problem H0 : μ = 0 vs. H1 : μ ≠ 0. We prove that Hotelling's T2 test, which uses (Xi, Yi), i = 1, 2,…, n (and discards Xi, i = n + 1,…, N) is an admissible test. In addition, and from a practical point of view, the proof will enable us to identify the region of the parameter space where the T2-test cannot be beaten. A similar result is also proved for the problem of testing μx ? μy = 0. A Bayes test and other competitors which are similar tests are discussed. 相似文献