Yb(OTf)3催化苯乙酮、芳香醛和芳香胺的Mannich反应: 三组分“一锅法”合成β-氨基酮衍生物

报道了稀土化合物Yb(OTf)₃催化的苯乙酮、芳香醛和芳香胺Mannich反应, 三组分“一锅法”合成了一系列的β-氨基酮衍生物. 该方法操作简单、条件温和、产率较高、催化剂可重复使用, 且对环境友好.     

Lanthanide-daunomycin interactions. Predominance of ML2 at low metal to ligand ratios

Spectroscopic investigations have been undertaken on the effects of lanthanide ions on the spectrum of the anticancer agent, daunomycin. The visible spectral perturbations due to the metal ions resulted in hypochromic effects in the 480 nm region and in shifts towards longer wavelength. The different metal ions investigated did not give any significant difference in the, spectral character. Data analysis according to the methods of molar ratio, continuous variation and graphical approaches based on simplex matrix theory indicated the presence of predominantly a ML₂ species at metal to ligand ratios, less than one. Data also suggested the presence of ML and ML₃ as well.     

Broadband infrared luminescence in Yb-doped Bi2O3–GeO2 glasses

The Yb-doped Bi₂O₃–GeO₂ glasses were prepared by the conventional melt quenching technique. Near-infrared (NIR) broadband emission was found at about 1024 nm, and 1330 nm (under 785 nm excitation), and the measured fluorescent lifetime was about several hundred microseconds. The emission intensity of Yb-doped Bi₂O₃–GeO₂ glasses increased with increasing of Yb dopant in our experiments. The NIR emission should be related to Yb³⁺ and lower valence Bi ions.     

Spectroscopic Properties of Yb3+-doped Borate Glasses

The spectroscopic properties of Yb3+-doped some borate glasses have been determined from absorption and emission measurements at room temperature. The emission cross sections range from approximately 1.0 to 1.7 pm2. Systematic variations of the spectroscopic properties with glass composition and activator concentration can be used to optimize emission cross-sections and fluorescence lifetimes.     

2-(2-Pyridyl)Indole Derivatives Preparation Via Fischer Reaction on Montmorillnite K10/Zinc Chloride Under Microwave Irradiation

Fischer condensation was performed in 50-60% yield in lower temperatures and shorter times if conducted in solvent-free acid medium under microwave irradiation.     

A New Crystal Phase Molybdate Yb2Mo4O15: The Synthesis and Upconversion Properties

A new upconversion nanocrystal phase Yb₂Mo₄O₁₅:Er is developed by using a facile aqueous‐precipitation procedure combined with thermal annealing. Nanocrystals of Yb₂Mo₄O₁₅ are exclusively synthesized, with particle sizes ranging from 1 to 20 nm. The optical properties are characterized and a high upconversion quantum yield is determined to be ≈1.3% at room temperature, under excitation of ≈500 mW cm^?2 IR (975 nm). To the best of our knowledge, this is the first work concerning the synthesis of nanocrystalline Yb₂Mo₄O₁₅ and the characterization of its upconversion properties, which possesses the potential to be utilized in bio‐probing and thin‐film optoelectronic device applications.     

NaYF_4∶Yb~(3+),Tm~(3+)/CdSe纳米异质结构的近红外上转换发光性能

采用两步高温热分解法合成了纳米异质结构的Na YF4∶Yb3+,Tm3+/Cd Se。X射线衍射测试结果表明样品由纯六角相的Na YF4(β-Na YF4)和纤锌矿型Cd Se组成。980 nm激发的上转换光谱表明Na YF4∶Yb3+,Tm3+和Cd Se之间存在能量传递,Tm3+将Yb3+传递给它的能量部分地传递给Cd Se,被激发的Cd Se又将能量回传给Tm3+的相应能级,最终使得Na YF4∶Yb3+,Tm3+的紫外和蓝光发射完全消失,而797 nm的近红外发射大幅增强。Na YF4∶Yb3+,Tm3+/Cd Se纳米异质结构的激发光和发射光均处于生物组织的光学透过窗口(700~1 100 nm),对生物组织的光损伤小,在生物医学领域有很大的应用潜力。     

双包层掺镱光纤激光器连续和调Q运转的实验研究

采用布拉格光纤光栅作为谐振腔,实现了980 nm半导体激光器端面泵浦下的双包层掺镱光纤激光器的连续和调Q运转.连续激光实验结果表明,在泵浦功率固定时,增益光纤存在激光输出功率最大情况下的最佳长度,当泵浦功率增大时,最佳增益光纤长度也随之增加.采用石墨烯分散液作为可饱和吸收体,插入增益光纤与布拉格光纤光栅之间,实现了光纤激光器的稳定被动调Q运转.当泵浦功率为2.87W时,得到了最小脉冲宽度33 ns、重复率38.5 kHz的脉冲序列;随着泵浦功率进一步增大,出现不稳定的调Q锁模现象.     

1.12-W Q-switched Yb:KGW laser based on transmission-type Bi2Se3 saturable absorber

We present a passively Q-switched Yb:KGW laser based on a transmission-type saturable absorber of topological insulator:Bi_2Se_3.The saturable absorber is prepared on a 0.17-mm glass substrate and can translate intra-cavity for best performance nearly without influence on the laser mode.At a maximum pump power of 13.7 W,the central wavelength,pulse duration,repetition rate,and pulse energy of Q-switched pulse are 1043 nm,1.5 μs,175.4 kHz,6.39 μJ,respectively.The maximum output power is 1.12 W.To our knowledge,this is the highest average output power from passively Qswitched lasers with topological insulator saturable absorbers.     

Ba5SiO4Cl6: Yb3+, Er3+, Li+荧光粉的制备及上转换发光性质研究

本文采用高温固相反应法制备了Ba₅SiO₄Cl₆: Yb³⁺, Er³⁺, Li⁺ 荧光粉, 并对其上转换发光性质及其发光机理进行了研究. 在980 nm 激光的激发下, Ba₅SiO₄Cl₆: Yb³⁺, Er³⁺ 荧光粉呈现较强的红色(662 nm) 和较弱的绿色(550 nm) 的上转换发光, 红色和绿色的上转换发光分别对应于Er³⁺ 离子的⁴S_3/2/²H_11/2→⁴I_15/2 和⁴F_9/2→⁴I_15/2 跃迁, 且随着掺杂的Er³⁺ 和Yb³⁺ 离子浓度增加, 样品的上转换发光强度增加, 这是因为Yb³⁺ 离子和Er³⁺ 离子之间的能量传递效率增加引起的. 在0.5—0.8 W 功率激发下,样品属于双光子发射, 而在0.9—1.2 W 功率激发下样品具有新的上转换发光机理——光子雪崩效应. 探讨了Li⁺ 掺杂对Ba₅SiO₄Cl₆: Yb³⁺, Er³⁺ 样品的上转换发光性质的影响, Li⁺ 离子的掺杂引起Ba₅SiO₄Cl₆:Yb³⁺, Er³⁺ 上转换发光强度增加, 这是由于Li⁺ 离子的掺入降低了晶体场的对称性引起的.