全文获取类型
收费全文 | 12160篇 |
免费 | 2365篇 |
国内免费 | 1314篇 |
专业分类
化学 | 6618篇 |
晶体学 | 162篇 |
力学 | 624篇 |
综合类 | 149篇 |
数学 | 1586篇 |
物理学 | 6700篇 |
出版年
2024年 | 27篇 |
2023年 | 162篇 |
2022年 | 269篇 |
2021年 | 318篇 |
2020年 | 346篇 |
2019年 | 311篇 |
2018年 | 263篇 |
2017年 | 467篇 |
2016年 | 565篇 |
2015年 | 514篇 |
2014年 | 744篇 |
2013年 | 1421篇 |
2012年 | 848篇 |
2011年 | 1020篇 |
2010年 | 764篇 |
2009年 | 767篇 |
2008年 | 752篇 |
2007年 | 849篇 |
2006年 | 789篇 |
2005年 | 680篇 |
2004年 | 583篇 |
2003年 | 527篇 |
2002年 | 467篇 |
2001年 | 318篇 |
2000年 | 322篇 |
1999年 | 238篇 |
1998年 | 184篇 |
1997年 | 188篇 |
1996年 | 172篇 |
1995年 | 141篇 |
1994年 | 119篇 |
1993年 | 82篇 |
1992年 | 78篇 |
1991年 | 64篇 |
1990年 | 61篇 |
1989年 | 76篇 |
1988年 | 78篇 |
1987年 | 47篇 |
1986年 | 29篇 |
1985年 | 32篇 |
1984年 | 24篇 |
1983年 | 10篇 |
1982年 | 29篇 |
1981年 | 22篇 |
1980年 | 23篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1974年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 328 毫秒
81.
Vandana Singh Ashutosh TiwariDevendra Narayan Tripathi Tulika Malviya 《Tetrahedron letters》2003,44(39):7295-7297
O-Methylation is of outstanding importance in structural polysaccharide chemistry. A novel method for the methylation of polysaccharides using microwave (MW) irradiation is described. Seed gum from Cyamopsis tetragonolobus (Guar) was fully methylated with dimethyl sulphate and sodium hydroxide using 100% microwave power for 4 min in 68% yield. The completely methylated seed gum thus obtained was hydrolyzed by 70% formic acid followed by 0.5N H2SO4 under full microwave power for 1.16 and 1.66 min, respectively. The partially methylated monosaccharides were separated and identified. 相似文献
82.
The rotational spectra of three low-energy conformers of thiodiglycol (TDG) (HOCH2CH2SCH2CH2OH) have been measured in a molecular beam using a pulsed-nozzle Fourier-transform microwave spectrometer. To determine the likely conformational structures with ab initio approach, conformational structures of 2-(ethylthio)ethanol (HOEES) (CH3CH2SCH2CH2OH) were used as starting points together with the consideration of possible intramolecular hydrogen bonding in TDG. Three lower-energy conformers have been found for TDG at the MP2=Full/6311G** level and ab initio results agree nicely with experimentally determined rotational constants. In addition, Stark measurements were performed for two of the three conformers for dipole moment determinations, adding to our confidence of the conformational structure matches between experimental observations and ab initio calculations. Of the three lower-energy conformers, one displays a compact folded-like structure with strong hydrogen bonding between the two hydroxyl groups and the central sulfide atom. Two other conformers have relatively open chain-like structures with hydrogen bonding between each of the hydroxyl groups to the central sulfur atom, of which one has pure b-type dipole moment according to the ab initio results. 相似文献
83.
主要研究在高空核爆的双指数类型电磁脉冲平面波入射时,地面附近的电磁脉冲环境。计算给出了在不同入射波状态,不同地表介质电气特性和距地面不同高度等条件下的电磁脉冲环境参数,归纳了一些规律性认识。结果显示:地面附近的电场会随距地面高度的不同而发生显著的变化,对于水平场分量,其反射场总是试图抵消入射场,而对于垂直场分量,其反射场叠加在入射场上,使得地面附近的垂直场强幅值一般大于入射波场强幅值;当入射波仰角增大时,合成电场波形的脉冲宽度会变宽;地表介质的电气特性参数不同也会对地面附近电场的波形和幅值造成一定的影响。 相似文献
84.
增长曲线模型中回归系数的广义根方估计 总被引:6,自引:0,他引:6
本文对增长曲线模型中的回归系数B提出了一种新的估计形式-广义根方估计的B(K),其中K=diag(k1,k2,…,kp)并证明了通过广义根方偏参数ki(i=1,2,…,p)的适当选取可使得该估计在均方误差矩阵的意义下优于已有的LS估计和根方估计,及广义根方估计是可容许估计,本文还给出了选取广义根方偏参数的两种方法,算法及一个应用实例。 相似文献
85.
86.
Huimin Xie Biao Li Robert Geer Bai Xu James Castracane 《Optics and Lasers in Engineering》2003,40(3):163-177
A focused ion beam (FIB) Moiré method is proposed to measure the in-plane deformation of object in a micrometer scale. The FIB Moiré is generated by the interference between a prepared specimen grating and FIB raster scan lines. The principle of the FIB Moiré is described. The sensitivity and accuracy of deformation measurement are discussed in detail. Several specimen gratings with 0.14 and 0.20 μm spacing are used to generate FIB Moiré patterns. The FIB Moiré method is successfully used to measure the residual deformation in a micro-electro-mechanical system structure after removing the SiO2 sacrificial layer with a 5000 lines/mm grating. The results demonstrate the feasibility of this method. 相似文献
87.
A facile, rapid and regioselective method for the 1-O-deacylation of peracylated glycopyranoses is described which occurs under mild conditions by absorption onto alumina using microwave irradiation. 相似文献
88.
钛酸钾晶须通常是直径和长度在微米量级的无机晶须 ,可用K2 O·nTiO2 表示其组成 ,n =1,2 ,4 ,6 ,8,[1] .六钛酸钾晶须具有耐高温、耐腐蚀、纤维拉伸强度高、导热系数小、红外反射率高 ,硬度低的特点 .在民用及工业方面有很多应用 .如催化剂载体、离子吸附交换材料、高温过滤器、绝热材料、耐摩擦材料等[2~ 5] .钛酸钾纳米线的合成尚未见报道 .我们在用电弧产生的N2 等离子体热解焦油时 ,生成了一种直径 9~ 2 0nm长约几百纳米线 .X射线能谱定量分析表明这种纳米线化学组成为K2 Ti8O15,是一种新的非化学计量化合物 .试验装… 相似文献
89.
Z. J. Yu L. J. Liu R. X. Zhuo 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):13-21
The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by 1H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (Mw) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (Mw/Mn)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with Mw = 12,100 and Mw/Mn = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in Mw of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003 相似文献
90.