首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   96389篇
  免费   8345篇
  国内免费   14443篇
化学   72166篇
晶体学   2744篇
力学   1966篇
综合类   650篇
数学   14287篇
物理学   27364篇
  2024年   152篇
  2023年   1212篇
  2022年   1682篇
  2021年   2503篇
  2020年   2750篇
  2019年   3199篇
  2018年   2403篇
  2017年   3202篇
  2016年   2984篇
  2015年   2665篇
  2014年   3501篇
  2013年   7494篇
  2012年   5155篇
  2011年   5918篇
  2010年   4663篇
  2009年   5718篇
  2008年   5900篇
  2007年   5876篇
  2006年   5605篇
  2005年   4820篇
  2004年   5032篇
  2003年   4439篇
  2002年   4576篇
  2001年   4066篇
  2000年   3815篇
  1999年   3518篇
  1998年   3013篇
  1997年   2237篇
  1996年   1569篇
  1995年   1350篇
  1994年   1192篇
  1993年   888篇
  1992年   804篇
  1991年   596篇
  1990年   524篇
  1989年   467篇
  1988年   376篇
  1987年   277篇
  1986年   280篇
  1985年   349篇
  1984年   305篇
  1983年   126篇
  1982年   236篇
  1981年   357篇
  1980年   323篇
  1979年   203篇
  1978年   230篇
  1977年   168篇
  1976年   116篇
  1974年   94篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
1. INTRODUCTION In the process of coking plant, about 30%~35% sulfur is transformed to H2S and some other sulfide, which form impurity in coal gas together with NH3 and HCN. Only 0.1% H2S containing in air can lead to die, so it is very important to carry on desulphurization and decyanation with coal gas [1~3]. Currently desulphurization and decyanation craft technique have Dry Oxidation Technology, Wet Oxidation Technology and Liquid Absorption Technology [2] three main kinds. The…  相似文献   
92.
DK Choudhury  PK Sahariah 《Pramana》2002,58(4):599-610
We obtain a solution of the DGLAP equation for the gluon at low x first by expanding the gluon in a Taylor series and then using the method of characteristics. We test its validity by comparing it with that of Glück, Reya and Vogt. The convergence criteria of the approximation used are also discussed. We also calculate εF 2(x,Q)2/ε In Q 2 using its approximate relations with the gluon distribution at low x. The predictions are then compared with the HERA data.  相似文献   
93.
 研究了超临界流体CO2在石墨-金刚石转变中的触媒作用。实验中,采用Ag2O作为流体触媒的先驱材料,在7.7 GPa压力下,Ag2O在1 200 ℃分解成Ag和O2,O2与石墨套管在高温高压下反应形成CO2超临界流体。研究结果表明,在7.7 GPa和1 500 ℃以上温度条件下,石墨在CO2流体触媒的作用下可转变为金刚石晶体,在1 500~1 700 ℃温度范围内合成出的金刚石具有完好的八面体形貌,与天然金刚石的生长特征非常相似。  相似文献   
94.
In this work we investigate the diffusion and precipitation of supersaturated substitutional carbon in 200-nm-thick SiGeC layers buried under a silicon cap layer of 40 nm. The samples were annealed in either inert (N2) or oxidizing (O2) ambient at 850 °C for times ranging from 2 to 10 h. The silicon self-interstitial (I) flux coming from the surface under oxidation enhances the C diffusion with respect to the N2-annealed samples. In the early stages of the oxidation process, the loss of C from the SiGeC layer by diffusion across the layer/cap interface dominates. This phenomenon saturates after an initial period (2–4 h), which depends on the C concentration. This saturation is due to the formation and growth of C-containing precipitates that are promoted by the I injection and act as a sink for mobile C atoms. The influence of carbon concentration on the competition between precipitation and diffusion is discussed. Received: 19 October 2001 / Accepted: 19 December 2001 / Published online: 20 March 2002 / Published online: 20 March 2002  相似文献   
95.
We have studied ultra-fast carrier dynamics of photo-excited carriers in hydrogenated microcrystalline silicon prepared by a very high frequency glow-discharge technique. We report on direct observation of two types of dynamics using selective photo-excitation in picosecond pump and probe measurements. One type of the observed dynamics has been found to be independent of the sample preparation, while the other reflects the relative weights of crystalline and amorphous fractions. We propose a simple rate-equation model that describes the carrier dynamics in microcrystalline silicon in terms of the composition of those in Si microcrystallites and in the a-Si:H tissue which surrounds the microcrystallites. The model without any fitting parameters reproduces the experimental data very well when the dynamics are scaled with relative volume fractions as obtained from Raman spectra. Received: 23 November 2000 / Accepted: 17 March 2001 / Published online: 23 May 2001  相似文献   
96.
Free-standing and supported hydrogenated amorphous carbon films (a:C–H) were prepared upon pyrolysis of the polymer formed by ethanolamine (EA) and citric acid (CA), under an ambient atmosphere at 300 °C. EA facilitates the formation of the macroscopic films, while CA is essential for obtaining the a:C–H microstructure, which comprises a mixture of sp2 and sp3 carbon. Received: 29 May 2001 / Accepted: 17 August 2001 / Published online: 20 December 2001  相似文献   
97.
直流磁控溅射一步法原位制备MgB2超导薄膜   总被引:6,自引:1,他引:5       下载免费PDF全文
用MgB2靶,控制直流磁控溅射工作在异常辉光放电或弧光放电状态,在SrTiO3衬底上原位一次性得到了MgB2超导薄膜,其起始转变温度为32K,零电阻温度为15K. 关键词: 高温超导体 超导薄膜 磁控溅射 二硼化镁  相似文献   
98.
新生MnO2对酸性媒介黑T的吸附   总被引:4,自引:0,他引:4  
蒋兰宏 《光谱实验室》2002,19(4):550-553
以化学法合成的新生MnO2为吸附剂,对水中酸性媒介黑T(染料之一)进行了吸附脱色研究,并探讨了影响吸附的因素。结果表明,酸性媒介黑T的脱色率达95%。且PH是影响染料脱色的主要因素。  相似文献   
99.
We report results of the atomic and electronic structures of Al7C cluster using ab initio molecular dynamics with ultrasoft pseudopotentials and generalized gradient approximation. The lowest energy structure is found to be the one in which carbon atom occupies an interstitial position in Al7 cluster. The electronic structure shows that the recent observation [Chem. Phys. Lett. 316, 31 (2000)] of magic behavior of Al7C- cluster is due to a large highest occupied and lowest unoccupied molecular orbital (HOMO-LUMO) gap which makes Al7C- chemically inert. These results have further led us to the finding of a new neutral magic cluster Al7N which has the same number of valence electrons as in Al7C- and a large HOMO-LUMO gap of 1.99 eV. Further, calculations have been carried out on (Al7N)2 to study interaction between magic clusters. Received 28 July 2001  相似文献   
100.
A new technique is presented for generating myocardial tagging using the signal intensity minima of the transition zones between the bands of 0° and 360° rotations, induced by a tandem of two adiabatic delays alternating with nutations for tailored excitation (DANTE) inversion sequences. With this approach, the underlying matrix corresponds to magnetization that has experienced 0° or 360° rotations. The DANTE sequences were implemented from adiabatic parent pulses for insensitivity of the underlying matrix to B1 inhomogeneity. The performance of the proposed tagging technique is demonstrated theoretically with computer simulations and experimentally on phantom and on the canine heart, using a surface coil for both RF transmission and signal reception. The simulations and the experimental data demonstrated uniform grid contrast and sharp tagging profiles over a twofold variation of the B1 field magnitude.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号