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31.
We consider two tests of the null hypothesis that the k-th derivative of a regression function is uniformly bounded by a specified constant. These tests can be used to study the shape of the regression function. For instance, we can test for convexity of the regression function by setting k=2 and the constant equal to zero. Our tests are based on k-th order divided difference of the observations. The asymptotic distribution and efficacies of these tests are computed and simulation results presented.Research supported by Natural Sciences and Engineering Research Council of Canada Grant OGP0007969.Research supported by National Science Foundation Grant DMS-9306738. 相似文献
32.
Giampaolo?Liuzzi Stefano?LucidiEmail author Veronica?Piccialli Antonello?Sotgiu 《Mathematical Programming》2004,101(2):339-364
In this paper we are concerned with the design of a small low-cost, low-field multipolar magnet for Magnetic Resonance Imaging with a high field uniformity. By introducing appropriate variables, the considered design problem is converted into a global optimization one. This latter problem is solved by means of a new derivative free global optimization method which is a distributed multi-start type algorithm controlled by means of a simulated annealing criterion. In particular, the proposed method employs, as local search engine, a derivative free procedure. Under reasonable assumptions, we prove that this local algorithm is attracted by global minimum points. Additionally, we show that the simulated annealing strategy is able to produce a suitable starting point in a finite number of steps with probability one.This work was supported by CNR/MIUR Research Program Metodi e sistemi di supporto alle decisioni, Rome, Italy.Mathematics Subject Classification (1991):65K05, 62K05, 90C56 相似文献
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In this paper, we propose a high order Fourier spectral-discontinuous Galerkin method for time-dependent Schrödinger–Poisson equations in 3-D spaces. The Fourier spectral Galerkin method is used for the two periodic transverse directions and a high order discontinuous Galerkin method for the longitudinal propagation direction. Such a combination results in a diagonal form for the differential operators along the transverse directions and a flexible method to handle the discontinuous potentials present in quantum heterojunction and supperlattice structures. As the derivative matrices are required for various time integration schemes such as the exponential time differencing and Crank Nicholson methods, explicit derivative matrices of the discontinuous Galerkin method of various orders are derived. Numerical results, using the proposed method with various time integration schemes, are provided to validate the method. 相似文献
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The combined derivative spectrophotometry developed in this paper is a new method, which can be used to determine multicomporent mixture simultaneously and may improve the sensitivity and accuracy of the measurement remarkably. Two practical tests were carried out to verify the correctness of the theory, and the results are satisfactory. 相似文献
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A multiplier rule is proved for constrained minimization problems defined on a metric spaces. The proof requires a generalization of the values of a derivative in the classical case that the metric space is a normed space. 相似文献
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建立了柱前衍生-气相色谱-电子捕获(GC-ECD)法同时测定水中PFBA、PFPeA、PFHxA、PFHpA,PFOA,PFNA,PFDA,PFUnA及PFDoA等(全称见正文)9种全氟羧酸(Perfluorinated carboxylic acids,PFCAs).使用2,4-二氟苯胺(2,4-Difluoroaniline,2,4-DFA)为衍生剂,N,N'-二环己基碳二亚胺(N,N'-Dicy-clohexylcarbodiimide,DCC)为脱水剂,与PFCAs形成酰胺衍生产物,衍生产物通过TR-5毛细管色谱柱分离,并以ECD检测器进行检测.对全氟羧酸衍生化过程中2,4-DFA和DCC用量、衍生反应溶剂、反应温度、反应时间等条件进行了优化,得出最佳衍生化条件.结果表明,在最优实验条件下,9种PFCAs衍生产物的线性相关系数>0.99,检出限为0.62~ 1.38 μg/L,相对标准偏差RSD为1.3%~7.5%.应用本方法对城市污水中全氟类羧酸进行了分析,城市污水中存在以PFPeA、PFHpA和PFOA为主的痕量PFCAs化合物,实际样品的加标回收率在84.4% ~ 120.9%之间.本方法稳定、可靠、成本低,能够满足水样中多种全氟羧酸的同时检测的要求,可为水体中全氟化合物的污染评价提供技术支持. 相似文献
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