An optical fiber methane gas sensing film sensor based on core diameter mismatch

<正>An optical fiber evanescent wave methane gas sensor based on core diameter mismatch is reported.The sensor consists of a multimode fiber in which a short section of standard single-mode fiber,coated with the inclusion of cryptophane molecules E in a transparent polysiloxane film,is inserted.The sensing principle is analyzed by optical waveguide theory.For different sensing film thicknesses and interaction lengths,the sensor signal is investigated within the methane concentration range of 0-14.5%(v/v).It is shown that the sensor signal with the thickness of 5μm and the interaction length of 3 mm strengthens linearly with the increasing concentration of methane,with a slope of 0.0186.The best detection limit of the sensor for methane is 2.2%(v/v) with a response time of 90 s.This sensor is suitable for the detection of methane concentration below the critical value of 5%.     

偏二甲肼渗透管标准物质的制备及其均匀性稳定性研究

以精馏和光解纯化工艺获得的高纯偏二甲肼为原料,制备了渗透率范围为0.5-30μg/min的偏二甲肼渗透管标准物质.经过均匀性、稳定性检验,结果表明:该标准物质均匀性、稳定性良好,为航天作业环境中各类快速检测仪的监控准确性提供了判定依据.     

实际气体分子间吸引相互作用对Cp,m-CV,m的影响

在考虑温度对分子间吸引相互作用影响的前提下,对Cp,m-CV,m的值做了理论分析,并与实验值和引力项中没有考虑温度因子时的范德瓦耳斯方程的修正值做了比较.     

流气式气体探测器气密性的测量

流气式气体探测器的气密性常用U形管压力计测量.本文给出了该方法测量探测器气体泄漏率的计算公式,讨论了气压、温度测量精度对泄漏率误差的影响.     

气体分子方均根速率的求解

本文给出了气体分子方均根速率求解的三种方法，论述了查表法和Γ函数法的根据，特别是用分部积分法和物理条件求得了解答，与目前采用的方法相比，这样求解，不仅方法简单，适合学生的数学基础，而且突出了物理意义．