264～280 nm波段萘的共振增强多光子电离研究

在我们自己研制的具有恒温加热进样系统的激光质谱仪上实验获得了气相萘分子的共振增强多光子电离/飞行时间质谱(REMPI-TOFMS),以及萘母体离子C10H+8和一些主要碎片离子C8H+6、C6H+6、C5H+3、C4H+3、C3H+3在264～280 nm的分质量光谱.结合在266 nm激发波长下实验得到的这些离子的光强指数及不同激光能量下的分支比,对母体离子及主要碎片离子的生成机理进行了探讨:在该波段范围内,萘母体分子首先吸收一个光子从基态跃迁至激发态,激发态分子再吸收一个光子而电离产生母体离子C10H+8;碎片离子C8H+6、C6H+6、C5H+3、C4H+3、C3H+3则是由母体离子进一步吸收光子解离形成的,并给出了可能的解离通道.     

Lu2Si2O7：Ce晶体的闪烁性能

用提拉法生长了Lu2Si2O7：Ce晶体，对该晶体的闪烁性能进行了研究。透射光谱表明，Lu2Si2O7：Ce晶体的吸收边比Lu2SiO5：Ce晶体向短波方向移动了25nm，使透光范围进一步拓宽。X射线发射光谱和UV激发发射光谱均具有典型的双峰特征，主峰在378nm。UV激发发射谱具有温度效应，即375K以上时，发光效率迅速降低；425K以上时，发光主峰位明显红移。衰减曲线符合单指数式衰减规律，常温下经UV激发后的衰减时间约为34ns。从曲线形态看，375K以下的衰减谱与室温下的几乎完全相同，拟合的结果在32．8～34ns之间；衰减时间的温度效应从375K开始显现，即随温度的升高，衰减时间有加速变短的趋势，到500K时缩短为6．72ns。热释光谱在488，553K处有两个热释光峰，但室温附近几乎观察不到热释光峰。     

贝塞尔-高斯脉冲光束在色散介质中的时间和光谱特性

 对等衍射长度贝塞尔-高斯脉冲光束在色散介质中的时间和光谱特性作了研究，结果表明，通过选择适当的空间参数，贝塞尔-高斯脉冲光束沿轴上传输时，脉冲宽度不变。传输距离小于无衍射长度时，随衍射角增加，功率谱形状未变，脉冲波形保持不变；传输距离大于无衍射长度时，随衍射角增加，光谱由蓝移变为红移，脉冲展宽。     

时变线性系统特征根判稳的推广

本文研究了二维时变线性系统零解的稳定性，给出了一些允许系数矩阵主对角元变号，系数矩阵特征根变号的判定稳定性的充分条件。     

CdSe和ZnO量子点的拉曼光谱研究

本文介绍了用拉曼光谱研究CdSe和ZnO两种Ⅱ Ⅳ族量子点材料的结果,对拉曼峰进行了指认。观察到的光学声子峰位的移动被认为是由量子限制效应引起。     

《毛细管电色谱理论基础》

毛细管电色谱作为一种新型微分离分析技术,其分离过程具有多种机理协同作用的特征。对于毛细管电色谱的理论研究不仅要考虑系统的电属性,还要兼顾溶质的两相分配特征。该书系统地阐述了毛细管电色谱的基本理论,讨论了分离过程中影响峰展宽的因素及其规律。基于作者发展的弛豫理     

Singlet-Triplet Transition in Quantum Dots Confined by Triangular and Bowl-Like Potentials： the Effect of Electric Fields

We theoretically investigate the energy spectra of two-electron two-dimensional （2e 2D） quantum dots （QDs） confined by triangular potentials and bowl-like potentials in a magnetic field by exact diagonalization in the framework of effective mass theory. An in-plane electric field is found to contribute to the singlet-triplet transition of the ground state of the 2e 2D QDs confined by triangular or bowl-like potentials in a perpendicular magnetic field. The stronger the in-plane electric field, the smaller the magnetic field for the total spin of the ground states in the dot systems to change from S = 0 to S = 1. However, the influence of an in-plane electric field on the singlettriplet transition of the ground state of two electrons in a triangular QD modulated by a perpendicular magnetic field is quite small because the triangular potential just deviates from the harmonic potential well slightly. We find that the strength of the perpendicular magnetic field needed for the spin singlet-triplet transition of the ground state of the QD confined by a bowl-like potential is reduced drastically by applying an in-plane electric field.     

Structural and Electrical Characteristics of Pb（Zr0.53,Ti0.47）O3 Thin Films Deposited on Si （100） Substrates

Pb(Zr0.53, Ti0.47)O3 (PZT) films were directly deposited on Si substrates without a buffer layer by pulsed laser deposition. Only(110)-oriented PZT peaks (other than Si substrate peaks) were observed from the XRD data. The electrical properties of the PZT/Si capacitor were characterized in terms of both the capacitance versus voltage (C-V) and current versus voltage (I-V) measurements. The clockwise trace of the C-V curve shows ferroelectric polarization switching, as is expected. From the I-V curves, the Schottky emission and spacecharge-limited-current behaviour are found to be the mainly leakage current mechanism in a certain electric field range in the negative and positive bias, respectively.     

高纯度烟草过氧化物酶(TOPⅠ)光谱特性研究

采用交换吸附脱色及柱层析新技术,成功地从烟叶中分离和纯化了一种烟草过氧化物酶同工酶(TOPⅠ),并对其进行了一系列光谱特性研究.基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)测得TOPⅠ分子量为21 888.5,等电点pI为3.5;氨基酸组成分析表明TOPⅠ为一含血红素的酸性蛋白酶.光谱学分析揭示,在402 nm处有一典型的Soret带,在498和636 nm处有特征吸收峰(α,β带),酸度和变性剂对TOPI在紫外可见区的特征吸收峰均产生一定的影响,TOP Ⅰ的荧光光谱测定结果说明TOPⅠ分子中含有Trp残基和Tyr残基以及其自身的独特的光谱学特性.