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131.
A simple and practical procedure for the reduction of acetals to ethers is described. It is based on the use of a 1,1,3,3-tetramethyldisiloxane (TMDS)-Pd/C system in the presence of a Brønsted acid as the co-catalyst. The reaction occurs under mild conditions and ethers are obtained in high yields. 相似文献
132.
Helena LundbergHans Adolfsson 《Tetrahedron letters》2011,52(21):2754-2758
A ruthenium catalyst formed in situ by combining [Ru(p-cymene)Cl2]2 and an amino acid hydroxy-amide was found to catalyze efficiently the asymmetric reduction of aryl alkyl ketones under transfer hydrogenation conditions using ethanol as the hydrogen donor. The secondary alcohol products were obtained in moderate to good yields and with good to excellent enantioselectivity (up to 97% ee). 相似文献
133.
NiO nanoparticles with an average size of 12 nm and a high specific surface area of 88.5 m2/g were easily prepared via the thermal decomposition of the complex Ni(dmgH)2 and were characterized by TGA, XRD, FT-IR, TEM and BET surface area measurement. This nanosized transition metal oxide was used as a new heterogeneous catalyst for the reduction of nitroarenes under microwave irradiation. The efficient and selective reduction of aromatic nitro compounds into their corresponding amines was observed by using ethanol as a hydrogen donor (reducing agent) and KOH as a promoter under microwave irradiation. This highly regio- and chemoselective method is fast, simple, inexpensive, high yielding, clean and compatible with several sensitive functionalities, such as halogens, -OH, -OCH3, -CHO, -COCH3, -COOH, -COOEt, -CONH2, -CN, -CHCH2 and -NHCOCH3. This method is suitable for the large scale preparation of different substituted anilines as well as other arylamines. In addition, the catalytic activity of nanosized NiO is higher than that of the bulk sample. 相似文献
134.
135.
João Paulo dos Santos Benedito Leandro 《Journal of Mathematical Analysis and Applications》2019,469(2):882-896
We consider the static vacuum Einstein spacetime when the spatial factor is conformal to a n-dimensional pseudo-Euclidean space. The most general ansatz that reduces the resulting system of partial differential equations to a system of ordinary differential equations is completely described. We obtain the entire set of solutions of the reduced system, where the classical Schwarzschild solution arises as a particular solution. In addition, we show that the Riemannian spatial factors associated to these solutions are foliated by parallel hypersurfaces of constant mean curvature. 相似文献
136.
The reduction and nitration of 1-keto and 4-keto-1,2,3,4-tetrahydrophenanthrene were investigated. The structures of the products were confirmed by spectroscopic data. 相似文献
137.
138.
Mieczysław Kozłowski Helena Wachowska Jan Yperman 《Central European Journal of Chemistry》2003,1(4):366-386
Products of reductive and non-reductive methylation of two high-sulphur coals (Mequinenza and Illinois No. 6) have been extracted
by dichloromethane. It has been established that the efficiency of the transformation of coal to the products soluble in CH2Cl2 is higher for coals subjected to non-reductive methylation by the Liotta method than for those after reduction in the potassium/liquid
ammonia system. The extracts and the extraction residues were subjected to elemental analysis, IR spectroscopy, and AP-TPR
(Atmospheric Pressure-Temperature Programmed Reduction) measurements. It has been shown that the main species undergoing extraction
by CH2Cl2 are aliphatic compounds or aromatic structures of low degree of condensation. The effect of the extraction on the sulphur
groups in coal has been discussed. 相似文献
139.
140.
Sandrine Calvet-Vitale 《Tetrahedron》2005,61(32):7774-7782
The results of a study dealing with the chemio- and diastereoselective reduction of chiral pyrrolidine and piperidine β-enamino esters 1, 2 and 3, 4 into β-amino esters are reported. This approach was successfully applied to a formal synthesis of (+)-calvine. 相似文献