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91.
Chandran Karunakaran K.R. Justin Thomas Arunachalam Shunmugasundarama Ramachandran Murugesan 《Journal of chemical crystallography》2000,30(5):351-357
Single crystals of the helical hydrogen-bridged one-dimensional Cu(II) complex, [Cu(stpy)2(CH3COO)2(H2O)2] (1) [Cu(stpy)2(CH3COO)2(H2O)] (2), are prepared and characterized by elemental and thermal analyses, IR, electronic and X-ray crystal structure determination. The crystals are monoclinic, of space group C2/c, with unit cell parameters a = 31.842(7) Å, b = 5.9829(10) Å, c = 30.970(14) Å, = 111.78(3)°, Z = 4. The asymmetric unit contains two different types of Cu(II) polyhedra, namely, octahedron and square pyramid within the same unit cell. 1 has elongated octahedral geometry with two nitrogen atoms from stpy and two oxygen atoms from synmonodentate acetate ligands, transcoordinated to Cu(II) in the basal plane. The oxygen atoms of the two water molecules occupy the axial positions. 2 has Cu(II) coordination polyhedra similar to 1, except that only one of the apical positions is occupied by a water molecule. The structure consists of two independent linear chains, one involving octahedral (1) and the other involving square-pyramidal (2) polyhedra, held by hydrogen bridges. The Cu–Cu intra- and interchain separations in both 1 and 2 are 5.983 and 8.214 Å. The unit cell packing shows weak -stacking between adjacent coordinated stpy ligands in the chain, resulting in ladder-type structure. Further, the extended packing reveals helical arrangement of Cu(II) polyhedra in the lattice. 相似文献
92.
93.
C. Giusti F. D. Pacati M. Schwamb S. Boffi 《The European Physical Journal A - Hadrons and Nuclei》2007,33(1):29-38
Results for the cross-sections of the exclusive 16O(e, e'pn)14N and 16O(γ, pn)14N knockout reactions are presented and discussed in different kinematics. In comparison with earlier work, a complete treatment
of the center-of-mass (CM) effects in the nuclear one-body current is considered in connection with the problem of the lack
of orthogonality between initial bound and final scattering states. The effects due to CM and orthogonalization are investigated
in combination with different treatments of correlations in the two-nucleon overlap function and for different parametrizations
of the two-body currents. The CM effects lead in super-parallel kinematics to a dramatic increase of the 16O(e, e'pn) cross-section to the 12
+ excited state (3.95MeV) of 14N . In all the situations considered the results are very sensitive to the treatment of correlations. A crucial role is played
by tensor correlations, but also the contribution of long-range correlations is important. 相似文献
94.
95.
本文将报告对硅纳米线、多孔硅、Si C纳米棒和碳纳米管等一维纳米体系的本征拉曼光谱及其特征的研究结果 ,并讨论拉曼光谱在上述材料的几何和物理特性研究中的应用。 相似文献
96.
Antoine Bonnefont Franoise Argoul Martin Z. Bazant 《Journal of Electroanalytical Chemistry》2001,500(1-2)
We investigate the subtle effects of the diffuse charged layer on interfacial kinetics by solving the governing equations for ion transport (Nernst–Planck) with realistic boundary conditions representing reaction kinetics (Butler–Volmer) and compact-layer capacitance (Stern) in the asymptotic limit =λD/L→0, where λD is the Debye screening length and L is the distance between the working and counter electrodes. Using the methods of singular perturbation theory, we derive the leading-order steady-state response to a nonzero applied current in the case of the oxidation of a neutral species into cations, without any supporting electrolyte. In certain parameter regimes, the theory predicts a reaction-limited current smaller than the classical diffusion-limited current; this over potential effect is not due to ohmic drop effects in the bulk of the cell but rather to antagonist processes involved in the surface charge transfer and diffuse layer charging respectively. We demonstrate that the charging of diffuse charge, since it is intimately coupled to the surface reaction and cannot be considered independently, plays a fundamental role in nonequilibrium surface reactions when the transport of one of the reacting species is coupled to the total interfacial response of the compact and diffuse layers. 相似文献
97.
A.V. Barashev 《哲学杂志》2013,93(2):204-207
Evans's comments are related only loosely to the main body of our paper, which is devoted to the onset of void ordering: his Monte Carlo simulations of this early stage of ordering are in a qualitative agreement with our results. They question, however, the basic mechanisms of damage accumulation revealed by a number of scientists using various techniques over the years. Here we argue that his views are erroneous due to overlooking some essential features of one-dimensional defect transport. 相似文献
98.
A hyperbolic reaction–diffusion model for the hantavirus infection, generalizing the parabolic set of equations recently derived by Abramson and Kenkre, is proposed within the context of Extended Thermodynamics. The model, as in the parabolic case, captures some of the realistic features of the dynamics of hantavirus in mice population, while it avoids the unphysical features concerning the instantaneous diffusive effects typical of parabolic equations. Traveling wave solutions, related to the spread of the infection in the landscape, are investigated. Both analytical and numerical results obtained herein are discussed and validated from the behavior of the biological system. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
99.
Isabelle Lefebvre 《Set-Valued Analysis》2001,9(3):273-288
In the first place, we present a quasi fixed-point theorem for a correspondence defined on some infinite-dimensional locally convex topological vector space such that some variables have open lower sections and the other ones are upper semicontinuous.In the second place, we propose a direct application of the quasi fixed-point result in an economic model. More precisely, we prove a nonemptiness result of the core of an exchange economy with asymmetric information, a continuum of states and a finite number of commodities. 相似文献
100.
M. M. Lafisheva M. Kh. Shkhanukov-Lafishev 《Computational Mathematics and Mathematical Physics》2008,48(10):1875-1884
Locally-one-dimensional difference schemes for the fractional diffusion equation in multidimensional domains are considered. Stability and convergence of locally one-dimensional schemes for this equation are proved. 相似文献