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121.
122.
泡沫铝是一种新型航天器防护材料,拥有良好的抵御空间碎片超高速撞击的特性。模仿泡沫金属的生产原理,建立了泡沫金属微结构几何模型,结合自编的光滑质点流体动力学程序进行了超高速撞击数值仿真,通过与实验结果的对比,验证了模型的有效性。提出了两种含泡沫铝的空间碎片防护结构,即填充泡沫铝结构和夹层泡沫铝结构。对这两种结构分别进行了仿真计算,获得了其撞击极限曲线。分析结果表明,在空间碎片防护领域涉及的大部分撞击速度区间内,填充泡沫铝结构的防护性能优于夹层泡沫铝结构。 相似文献
123.
在15 mL的不锈钢反应釜中,利用无水三氯化铝与叠氮化钠在无溶剂的条件下直接反应,合成出了六方结构氮化铝泡沫材料,反应温度650 ℃,反应时间3 h.扫描电子显微镜测试结果显示,该试样呈现泡沫状外貌特征.X射线衍射结果表明该试样为六方结构.不同温度条件下的吸收谱表明在202 nm附近存在尖锐的吸收峰.红外吸收谱中存在1381 cm-1和730 cm-1两个吸收峰.同时,提出了六方结构氮化铝泡沫材料的合成机理.
关键词:
六方氮化铝泡沫材料
合成机理
X射线衍射 相似文献
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Firas Awaja Benedicta Arhatari Elisabeth Leiss 《Polymer Degradation and Stability》2009,94(10):1814-1824
Epoxy resin composites reinforced with hollow glass microspheres, microlight microspheres, 3D parabeam glass, and E-Glass individually were subjected to accelerated thermal degradation conditions. X-ray microcomputed tomography (XμCT) was used to evaluate density changes, reinforcement filler damage, homogeneity, cracks and microcracks in the bulk of the different epoxy resin composites. XμCT 3D images, 2D reconstructed images and voids calculations revealed microspheres damage, filler distributions and showed cracks in all composites with different shapes and volume in response to the thermal degradation conditions. In addition, expansion of air bubbles/voids was observed and recorded in the microsphere and microlight epoxy composite samples. In a complementary way, optical coherence tomography (OCT) was used as a novel optical characterisation technique to study structural changes of the surface and near-surface regions of the composites, uncovering signs of surface shrinkage caused by the thermal treatment. Thus, combining XμCT and OCT proved useful in examining epoxy resin composites' structure, filler-resin interface and surface characteristics. 相似文献
127.
Paecilomyces marquandii, a phosphate-solubilizing, starch-utilizing filamentous fungus, was immobilized on polyurethane foam (PUF). The immobilized
fungus was applied in a repeated batch (six batches) fermentation process to solubilize Hirapur rock phosphate. The fungus
was immobilized on PUF cubes and was used for phosphate solubilization in shake flask repeated batch cultivations. The fungus
was also immobilized on PUF sheet and utilized in an airlift bioreactor in a repeated batch process. Maximum soluble phosphate
(370 μg/ml) was recorded after third batch with 8 g rock phosphate/l. After 12 days of fermentation, a total production of
1,643 μg phosphate/ml was achieved. 相似文献
128.
Preparation of novel ion exchange polyurethane foam and its application for separation and determination of palladium in environmental samples 总被引:1,自引:0,他引:1
Moawed EA 《Analytica chimica acta》2006,580(2):263-270
The new strong anion exchanger (PUFIX) from polyurethane foam was prepared by coupling of the primary amine of the foam matrix with ethyl iodide. PUFIX was characterized using different tools (IR spectra, elemental analysis, density and thermal analysis). The sorption properties of the new anion exchanger (PUFIX) and chromatographic behaviour for separation and determination of palladium(II) ions at low concentrations from aqueous iodide or thiocyanate media were investigated by a batch and dynamic processes. The maximum sorption of Pd(II) was in the pH range of 0.3–2. The kinetics of sorption of the Pd(II) by the PUFIX was found to be fast with average values of half-life of sorption (t1/2) of 3.32 min. The variation of the sorption of Pd(II) with temperature gives average values of ΔH, ΔS, ΔG and ΔE to be −38.3 kJ mol−1, −100.7 J K−1 mol−1, −8.3 and 11.8 kJ mol−1, respectively. The sorption capacity of PUFIX was 1.69 mmol g−1 for Pd(II), preconcentration factors of values ≈250 and the recovery 99–100% were achieved (R.S.D. ≈ 1.24%). The lower detection limit, 1.28 ng mL−1 was evaluated using spectrophotometric method (R.S.D. ≈ 2.46%). 相似文献
129.
A stable chelating sorbent was synthesized by covalently linking 4-hydroxytoluene or 4-hydroxyacetophenone with the polyurethane foam (PUF) through -NN- group. The synthesized chelating sorbents were characterized by IR and UV/vis measurements. The modified foams show excellent stability towards various solvents. Factors influencing the extraction process of Zn(II), Pb(II), Cd(II) and Hg(II) were studied and evaluated as a function of pH of metal ion solution and equilibration shaking time. The values of sorption capacity of metal ions (μg g−1) were determined with the two types of bonded foams. The two phenolic bonded foams were studied comparatively. The potential applications of the two newly synthesized foams for the removal and separation of the examined metal ions from two natural water samples (drinking tap water and Qaroun lake water at Fayoum City, Egypt) were investigated. Precision (assessed as a relative standard deviation, R.S.D.) was also evaluated and found to be ≤7.3% (N = 5) with a detection limit under 0.46 μg L−1. 相似文献
130.
Buratti M Pellegrino O Valla C Rubino FM Verduci C Colombi A 《Biomedical chromatography : BMC》2006,20(9):971-978
A method suitable for the determination of unmetabolized polycyclic aromatic hydrocarbons (PAHs) excreted at trace levels (ng/L) in human urine for the monitoring of exposure of the general population to PAH contamination was developed. PAHs were determined, after enrichment by solid-phase extraction on polyurethane foam (PUF) chips, by HPLC with fluorescence detection. Different parameters affecting analyte extraction to the PUF, including urine salting-out and organic additives, and optimization of conditions for clean-up and desorption have been investigated. Optimized conditions were 40 mL acidified urine sample, added with magnesium sulfate, tetrahydrofuran and a 2 cm3 PUF chip, and extracted by shaking at 30 rpm for 1 h at ambient temperature. Desorption was performed, after a clean-up step with diluted sodium hydroxide, using a small amount of diethyl ether. The recovery of PAH congeners from spiked urines was >90% in the 2-100 ng/L range; the detection limit was 0.1-0.5 ng/L, depending on the considered PAH congener; day-to-day precision, at 50 ng/L native PAH content, was CV = 10-20%. The proposed technique provides a simple, economical and effective procedure for the determination of trace amounts of unmetabolized PAHs excreted in human urine spot samples. 相似文献