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在超声辐射和哌啶催化反应条件下,1,3-二氢吲哚-2-酮(1)与芳香醛2a~2m发生Knoevenagel缩合反应,合成了一系列3-芳亚甲基吲哚-2-酮衍生物3a~3m。该方法具有产率高、反应时间短、后处理简单和环境友好等优点,产物通过~1H NMR、~(13)C NMR和HRMS手段进行结构表征,并通过核磁2D NOESY确定了所有化合物几何构型。初步抑菌活性测试结果表明,化合物3d对革兰氏阳性菌具有较好的抑制作用,最小抑菌浓度(MIC)为15.6μg/m L,化合物3f、3g、3h和3k对油菜菌核病菌表现出良好的抑制活性,MIC为62.5μg/m L,与阳性对照多菌灵相当。此外,对此类化合物的构效关系进行了讨论。 相似文献
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An elastic-viscoplastic constitutive model was adopted to analyze asymptotically the tip-field of moving crack in linear-hardening materials under plane strain condition. Under the assumption that the artificial viscosity coefficient was in inverse proportion to power law of the rate of effective plastic strain, it is obtained that stress and strain both possess power law singularity and the singularity exponent is uniquely determined by the power law exponent of the rate of effective plastic strain. Variations of zoning structure according to each material parameter were discussed by means of numerical computation for the tip-field of mode Ⅱ dynamic propagating crack, which show that the structure of crack tip field is dominated by hardening coefficient rather than viscosity coefficient. The secondary plastic zone can be ignored for weak hardening materials while the secondary plastic zone and the secondary elastic zone both have important influence on crack tip field for strong hardening materials. The dynamic solution approaches to the corresponding quasi-static solution when the crack moving speed goes to zero, and further approaches to the HR (Hui-Riedel) solution when the hardening coefficient is equal to zero. 相似文献
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功能梯度双材料弱/微间断界面的冲击断裂分析 总被引:1,自引:0,他引:1
提出强间断、弱间断、微间断和全连续界面的概念与分类,建立功能梯度弹性双材料弱间断
界面冲击断裂问题的力学模型,采用积分变换法推导问题的Cauchy奇异积分方程,并用配
点法求得数值解. 分析表明,弱/微间断性对于FGMs界面裂纹应力强度因子有着重要影响,
而且微间断性是优于弱间断性的一种界面力学性能连接关系. 以FGMs界面某一侧
的力学性能函数在界面处的Taylor展开式的低阶项作为界面另一侧的力学性能函数,便可
以使FGMs界面成为``微间断'界面. 界面的一阶微间断对应力强度因子的减小作用较为明
显,而高阶(二阶及以上)微间断对应力强度因子的影响较小. 减小界面的弱间断程度或使
FGMs界面具备``微间断性',都将利于提高功能梯度双材料界面抗冲击断裂能力,在一定
程度上达到界面增韧的目的. 相似文献
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本文重点描述了应用Fe/Mo/Al2O3载体载入式催化剂,以CO为碳源,通过氧炔焰形成热解火焰合成单壁、双壁和三壁碳纳米管的实验过程.研究了合成温度,取样时间以及碳源气体CO流最对最终产物的影响.结果表明,830℃的合成温度可以满足合成单壁、双壁和三壁碳纳米管所需要的高温环境,消除载体催化剂聚合物对碳纳米管的包裹,大幅提高合成产物的产量;10 min的取样时间以及0.4 L/min的CO流量可以良好分散载体催化剂聚合物团簇,进而优化产物形态和进一步提高产量. 相似文献
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In this paper, we present a new car-following model, i.e. comprehensive optimal velocity model (COVM), whose optimal velocity function not only depends on the following distance of the preceding vehicle, but also depends on the velocity difference with preceding vehicle. Simulation results show that COVM is an improvement over the previous ones theoretically. Then, the stability condition of the model is obtained by the linear stability analysis, which has shown that the model could obtain a bigger stable region thanprevious models in the phase diagram. Through the nonlinear analysis, the Burgers, Korteweg-de Vries (KdV) and modified KdV (mKdV) equations are derived for the triangular shock wave, the soliton wave, and the kink-antikink soliton wave. At the same time, numerical simulations are also carried out to show that the model could simulate these density waves. 相似文献
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以CO为碳源,通过氧炔焰形成热解火焰合成了碳纳米管.为了详细研究催化剂与合成环境对合成产物的影响,实验分别应用不同催化剂在不同合成环境中进行取样分析.结果表明:催化剂颗粒尺寸直接决定合成产物的种类,不同产物对合成温度也有不同要求,过高温火焰环境会遏制碳纳米管的合成.最终得出,Fe/Mo/Al2O3载体催化剂适合在热解腔内部830℃无氧的环境下催化合成小直径的单壁、双壁和三壁碳纳米管,而由Fe(CO)5热解-附着-聚合产生的Fe催化剂颗粒适合在600℃的V型体火焰中催化合成大直径多壁碳纳米管. 相似文献