首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5493篇
  免费   816篇
  国内免费   545篇
化学   2059篇
晶体学   107篇
力学   1411篇
综合类   56篇
数学   1224篇
物理学   1997篇
  2024年   5篇
  2023年   45篇
  2022年   124篇
  2021年   146篇
  2020年   178篇
  2019年   166篇
  2018年   163篇
  2017年   177篇
  2016年   240篇
  2015年   190篇
  2014年   283篇
  2013年   405篇
  2012年   331篇
  2011年   351篇
  2010年   302篇
  2009年   363篇
  2008年   342篇
  2007年   378篇
  2006年   319篇
  2005年   257篇
  2004年   263篇
  2003年   222篇
  2002年   179篇
  2001年   181篇
  2000年   155篇
  1999年   132篇
  1998年   134篇
  1997年   115篇
  1996年   122篇
  1995年   73篇
  1994年   57篇
  1993年   71篇
  1992年   57篇
  1991年   50篇
  1990年   44篇
  1989年   42篇
  1988年   31篇
  1987年   32篇
  1986年   27篇
  1985年   19篇
  1984年   16篇
  1983年   9篇
  1982年   13篇
  1981年   13篇
  1980年   11篇
  1979年   9篇
  1978年   4篇
  1973年   2篇
  1971年   2篇
  1957年   2篇
排序方式: 共有6854条查询结果,搜索用时 15 毫秒
991.
This paper is a continuation of previous work and shows the enhancement of the surface plasmon resonance effect in a tapered optical fiber device. The study investigated liquid crystal cells containing a tapered optical fiber covered with a silver nanolayer, surrounded by a low refractive index liquid crystal in terms of the properties of light propagation in the taper structure. Silver films with a thickness of d = 10 nm were deposited on the tapered waist area. Measurements were performed at room temperature; liquid crystal steering voltage U from 0 to 200 V, with and without any amplitude modulation with a frequency of f = 5 Hz, and the wavelength λ ranged from 550 to 1200 nm. A significant influence of the initial arrangement of liquid crystals molecules on light propagation was observed. Three types of liquid crystal cells—orthogonal, parallel, and twist—were considered. During the measurements, resonant peaks were obtained—the position of which can also be controlled by the type of liquid crystal cells and the steering voltage. Based on the obtained results, the best parameters, such as highest peak’s width reduction, and the highest SNR value were received for twisted cells. In addition, the present work was compared with the previous work and showed the possibility of improving properties of the manufactured probes, and consequently, the surface plasmon resonance effect. In the presented paper, the novelty is mainly focused on the used materials as well as suitable changes in applied technological parameters. In contrast to gold, silver is characterized by different optic and dielectric properties, e.g., refractive index, extension coefficient, and permittivity, which results in changes in the light propagation and the SPR wavelengths.  相似文献   
992.
We consider the problem of encoding a deterministic source sequence (i.e., individual sequence) for the degraded wiretap channel by means of an encoder and decoder that can both be implemented as finite-state machines. Our first main result is a necessary condition for both reliable and secure transmission in terms of the given source sequence, the bandwidth expansion factor, the secrecy capacity, the number of states of the encoder and the number of states of the decoder. Equivalently, this necessary condition can be presented as a converse bound (i.e., a lower bound) on the smallest achievable bandwidth expansion factor. The bound is asymptotically achievable by Lempel–Ziv compression followed by good channel coding for the wiretap channel. Given that the lower bound is saturated, we also derive a lower bound on the minimum necessary rate of purely random bits needed for local randomness at the encoder in order to meet the security constraint. This bound too is achieved by the same achievability scheme. Finally, we extend the main results to the case where the legitimate decoder has access to a side information sequence, which is another individual sequence that may be related to the source sequence, and a noisy version of the side information sequence leaks to the wiretapper.  相似文献   
993.
速度和载荷对脂润滑2Cr13钢离子渗氮层摩擦学行为的影响   总被引:1,自引:0,他引:1  
利用销-盘式摩擦磨损试验机对不同速度和载荷条件下 PFPE脂润滑2Cr13钢离子渗氮层进行了系统的真空滑动摩擦磨损试验.采用扫描电子显微镜(SEM)、X射线光电子能谱仪(XPS)和傅里叶变换红外光谱(FTIR)分别对磨损表面的形貌、化学状态及润滑脂的成分进行分析.结果表明:随着载荷和滑动速度的增加,脂润滑渗氮层的磨损机制由轻微磨损向轻微复合磨损机制转变.在真空摩擦磨损过程中2Cr13钢离子渗氮层与PFPE润滑脂发生化学反应,并有FeF3生成,促进PFPE润滑脂发生降解,形成酸性的氟化物.增加载荷和速度会加速渗氮层与润滑脂之间的反应,进一步促进润滑脂的降解.  相似文献   
994.
The existence of shock–turbulent boundary layer interactions lead to very complicated flow phenomena and pose a challenge for numerical simulation. In this paper, two turbulence models, the Baldwin–Lomax (B–L) model and the Johnson–King (J–K) model, which were originally developed for simple external flow simulation, are modified to model complex high-speed internal separated flows. The full Navier–Stokes solver used in this paper is based on a cell-centered finite volume method and multistepping time marching scheme. Both implicit residual smoothing and local time stepping techniques are incorporated to accelerate the convergence rate. To ensure the numerical stability with the present explicit scheme, a point-implicit treatment to the source term in the ordinary differential equation (ODE) of the J–K model has been developed and has proved to be very effective in modeling such a complex flow. An arc-bump channel flow case has been studied. Comparisons of computed results with experimental data show that the present solver, with the modified turbulence models, predicts the shock and the flow separation very well. The J–K model is found to predict the size of the separation bubble with a higher accuracy. © 1998 John Wiley & Sons, Ltd.  相似文献   
995.
研究了脉冲HF激光与水柱表面相互作用下电信号的产生过程。电信号显示了与激光能量线性相关的峰值间有时间间隔的两峰结构,且第二个尖峰在水柱底部的蒸汽腔塌缩后出现。实验还显示电信号的幅值和激光脉冲照射过程中是否存在膨胀和挤压的薄水层密切相关。如果在电池上边缘和石英平板(石英板紧邻电池,并与水柱上表面相接)之间存在一薄水层,电信号强度会增加10倍。  相似文献   
996.
目前,有机-无机杂化钙钛矿太阳能电池(PSC)的器件效率已经超过25%。电子传输层作为PSC中的重要组成部分在提取和传输光生电子,阻挡空穴,修饰界面,调节界面能级和减少电荷复合等方面起着关键作用。无机n型材料,例如TiO2、ZnO、SnO2和其他金属氧化物材料具有成本低和稳定性好的特点,经常在传统PSC中被用作电子传输层(ETL)。有机n型材料,例如富勒烯及其衍生物、萘二酰亚胺聚合物和小分子,具有良好的成膜性能及强的电子传输性能,经常在反式PSC中被用作ETL。本综述详细介绍了PSC中电子传输层的作用机理和制备方法;重点总结了金属氧化物材料、有机分子材料、复合材料和多层分子材料电子传输层和其改性手段的最新研究进展;最后,展望了电子传输层材料朝着高性能PSC的实际应用和发展前景。  相似文献   
997.
生物分子与纳米材料作用形成的“蛋白冠”影响纳米材料的物理和化学性质, 目前缺少有效的原位实时技术监测蛋白冠的形成过程. 本研究基于二氧化硅胶体晶体薄膜和反射干涉光谱法, 研究了三种代表性血液蛋白质在二氧化硅纳米粒子表面的蛋白冠形成过程, 结果表明这三种蛋白具有不同的蛋白冠形成过程及参数; 研究了人血清白蛋白在三种表面曲率的二氧化硅表面的蛋白冠形成过程, 结果表明曲率越大时, 蛋白冠形成速率越快, 厚度越大. 以血浆和全血样品为生物环境开展蛋白冠形成过程研究, 结果表明本研究的监测方法可以直接用于血浆和全血在纳米粒子表面蛋白冠的形成过程监测, 为纳米材料与生物分子的相互作用研究提供了一种简单可靠的评价技术.  相似文献   
998.
ONTHESTABILITYOFFORCEDDISSIPATIVENONLINEARSYSTEM¥ChenDaduan(陈达段)LiuXiaoming(刘晓明)ShiWeihui(施惟慧)(ShanghaiUniversity.Shanghai200...  相似文献   
999.
The effects of the PbO volatilization, excess Pb content of PbZr0.52Ti0.48 (PZT) precursor, PbTiO3 (PT) seeding layers and annealing condition on the microstructures, surface morphologies, preferred orientation and ferroelectric properties of PbZr0.52Ti0.48 films were systematically investigated. PZT films with a variety of excess Pb (0-20%) were spin-deposited on Si(1 0 0) and Pt(1 1 1)/Ti/SiO2/Si(1 0 0) substrates by sol-gel technique. The films composition, Pb/Zr/Ti/O atom rate and Pb loss were semiquantitative analyzed by X-ray photoelectron spectrometer (XPS). When the excess Pb of PZT precursor was 10%, the Pb/Zr/Ti/O atomic rate of the fabricated films was very close to the designed rate of 1:0.52:0.48:3. The XRD and AFM investigations confirmed that PT seeding layer promoted the PZT films perovskite phase transformation and grains growth with (1 1 0) plane preferred orientation, accordingly lowered perovskite phase crystallization temperature and reduced Pb loss. The PZT films annealed in O2 flow demonstrated better microstructure and ferroelectric properties comparing with films annealed in air by double remnant polarization increase and 8% coercive field increase. The underlying mechanism was also investigated.  相似文献   
1000.
The minimum number of k-subsets out of a v-set such that each t-set is contained in at least one k-set is denoted by C(v, k, t). In this article, a computer search for finding good such covering designs, leading to new upper bounds on C(v, k, t), is considered. The search is facilitated by predetermining automorphisms of desired covering designs. A stochastic heuristic search (embedded in the general framework of tabu search) is then used to find appropriate sets of orbits. A table of upper bounds on C(v, t + 1, t) for v 28 and t 8 is given, and the new covering designs are listed. © 1999 John Wiley & Sons, Inc. J. Combin Designs 7: 217–226, 1999  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号