光纤过程检测硫酸亚铁缓释片释放度

建立光纤药物溶出度实时测定仪（FODT）在线监测硫酸亚铁溶出度测定的新方法.研究发现通过络合反应检测Fe2＋是可行的,FODT测定硫酸亚铁缓释片释放度与AAS测定结果无统计学意义.利用FODT过程检测硫酸亚铁缓释片释放度,全面直观地反映了药品的释放过程和内在质量,较经典方法能提供更多信息,测定过程简便自动,测定结果准确可靠.     

A reduced dimensionality model of torsional vibrations in star molecules

The torsional vibrations of star molecules are studied with a reduced dimensionality model. In this model, the molecule is described by two equivalent sets of lumped inertial cylinders and vibrational frequencies are predicted by solution of the coupled equations of motion. Force constants are determined by including them as free parameters in the model and fitting the computed frequencies to their analogs as determined using full normal coordinate analysis at the HFSCF level of theory. Best agreement between the methods occurs when torsional force constants are included for the first two layers of the molecule. This reveals that non-bonded torsional interactions are important in the vibrational dynamics of these systems. Further insight is afforded by an analysis of why simple harmonic oscillator models are sufficient for modeling some related systems but fail to reproduce the trend in global mode frequencies for saturated aliphatic star molecules. The analysis reveals that the origin of this failure lies in backbone flexibility in these branched polymeric systems.     

自动化质谱图解卷积和鉴定系统用于鉴定含痕量杂原子的石油馏分（英文）

Here we present a simple yet effective gas chromatography-mass spectrometry (GC-MS) identification approach for the detection of heteroatom-containing compounds (HACCs) in petroleum fractions. The MS/AMDIS (Automated Mass Spectral Deconvolution and Identification System) program was used to identify parts per million (ppm) HACC concentrations in petroleum fractions in place of traditional techniques (extraction and standard injection). Polycyclic aromatic sulfur heterocycles (S-PAHs) were used as model compounds to confirm the validity of the AMDIS identifiers, which were compared with extracted results using the off-line X-calibur software. AMDIS was able to identify ppm concentrations of S-PAHs in oil condensate. There was good agreement between experimental and AMDIS identification results for S-PAHs in oil condensate. AMDIS was also used to detect nitrogen-containing compounds (NCCs) and alkylphenols in oil condensate. Our results confirmed the presence of 2-methylbenzothiazole, carbazole, and 2,4-ditertbutyl phenol. In a crude oil sample, AMDIS identification of m/z=191 biomarkers was consistent with empirical results. Therefore, AMDIS can help to reduce the number of experimental steps in identification protocols.     

Correlated electron current and temperature dependence of the conductance of a quantum point contact

We investigate finite temperature corrections to the Landauer formula due to electron–electron interaction within the quantum point contact. When the Fermi level is close to the barrier height, the conducting wavefunctions become peaked on the barrier, enhancing the electron–electron interaction. At the same time, away from the contact the interaction is strongly suppressed by screening. To describe electron transport we formulate and solve a kinetic equation for the density matrix of electrons. The correction to the conductance G is negative and strongly enhanced in the region 0.5 × 2e²/h ≤ G ≤ 1.0 × 2e²/h. Our results for conductance agree with the so-called “0.7 structure” observed in experiments.     

Thermal conductance of nanofluids: is the controversy over?

Over the last decade nanofluids (colloidal suspensions of solid nanoparticles) sparked excitement as well as controversy. In particular, a number of researches reported dramatic increases of thermal conductivity with small nanoparticle loading, while others showed moderate increases consistent with the effective medium theories on well-dispersed conductive spheres. Accordingly, the mechanism of thermal conductivity enhancement is a hotly debated topic. We present a critical analysis of the experimental data in terms of the potential mechanisms and show that, by accounting for linear particle aggregation, the well established effective medium theories for composite materials are capable of explaining the vast majority of the reported data without resorting to novel mechanisms such as Brownian motion induced nanoconvection, liquid layering at the interface, or near-field radiation. However, particle aggregation required to significantly enhance thermal conductivity, also increases fluid viscosity rendering the benefit of nanofluids to flow based cooling applications questionable.     

闪光照相中源尺寸和散射对成像的影响

 利用Monte Carlo(MC)模拟技术解释实验中心线灰度曲线的各部分波形。结果发现，系统中的散射照射量、光源的尺寸和H-D特征曲线的形状对实验灰度曲线的各部分波形均有影响：散射量越大，中心信号幅度越低;H-D曲线趾部的非线性越严重，中心信号幅度也越低;光源尺寸造成图像越模糊。指出了用实验波形可以半定量确定系统散射程度和光源尺寸。在测量照射量时，应该尽可能避免散射的干扰,用台阶法测量H-D曲线时，应使台阶远离剂量片而前移。     

一类非线性代数方程组的并行迭代算法

１．引言考虑非线性代数方程组这里,　　　　　　　　　　　　　　　　　　　　　　　　　　　　为连续的对角映射,二者的导函数均存在,但并不一定连续．这类非线性代数方程组具有丰富的实际背景．譬如,Ｓｔｅｆａｎ问题和许多弱非线性椭圆型偏微分方程,就可归结为（１．１）的数值求解问题．根据方程组（１．１）的特殊结构,并利用矩阵多重分裂思想,文ｔＺ］讨论了一类并行非线性Ｇａｕｓｓ－Ｓｅｉｄｅｌ型迭代算法．这类算法具有很好的数值性质和较高的并行效率·在此基础上,运用松弛加速技术,文［８］进一步研究了一类并行多分…     

Théorie de Kasparov équivariante et groupo?des I

Let be a locally compact topological groupoid, A and B two C*-algebras endowed with a continuous action of . We define an operator K-theory group K K (A,B). We describe two basic properties of this theory: the existence of a Kasparov product and functoriality with respect to groupoid cocycles.     

一类描述混沌映射的符号动力系统

本文定义了符号空间上的拟移位映射,并用该类映射描述了Ｃａｎｔｏｒ集及平面Ｃａｎｔｏｒ集上的混沌映射,本文结果可看作Ｓｍａｌｅ马蹄模型的简化。     

Existence and Uniqueness of Solutions for a Class of Reaction-diffusion Systems

61.Intr0ducti0nInthispaper,wediscussareactionnetinacombusti0nmodel:V={R,,R2},whereR,andR2aredistinctreacti0nprocesses:Rl:A1+A,-A,,R2:A2+A3-P,A,(j=1,2,3)denotesthereactant,andPdenotestheinertproduct.Thesereactionsareexothermicreactions-LetQ,,Q2standforheatenergiesandU=(U,,U,,U,,U,)forstatevariablesdescribingreactions,whereUoisreactiontemporature,andU,(j=1,2,3)isthemolarityofthej-threactant.AssumethatV,(i=1,2)isthereactantvariablefortheithreactionpr0cess:V,=(Q,,1,-l,l)",V2=(Q,,O,-l,-…