含三正辛胺微胶囊对六价铬的富集

本文将对六价铬有效的萃取剂ＴＯＡ（三正辛胺）微胶囊化，制成填充柱型的酸性体系六价铬的富集分离装置。实验结果表明，微胶囊填充柱中每毫升ＴＯＡ对六价铬的最大萃取容量为１５８．０ｇ／ｍＬ，为纯ＴＯＡ液相萃取的４．９倍。微胶囊经碱／水洗涤后，可再生使用。     

Total Dose Radiation Tolerance of Phase Change Memory Cell with GeSbTe Alloy

Phase change memory （PCM） cell array is fabricated by a standard complementary metal-oxide-semiconductor process and the subsequent special fabrication technique. A chalcogenide Ge2Sb2Te5 film in thickness 50hm deposited by rf magnetron sputtering is used as storage medium for the PCM cell. Large snap-back effect is observed in current-voltage characteristics, indicating the phase transition from an amorphous state （higher resistance state） to the crystalline state （lower resistance state）. The resistance of amorphous state is two orders of magnitude larger than that of the crystalline state from the resistance measurement, and the threshold current needed for phase transition of our fabricated PCM cell array is very low （only several μA）. An x-ray total dose radiation test is carried out on the PCM cell array and the results show that this kind of PCM cell has excellent total dose radiation tolerance with total dose up to 2 ×10^6 rad（Si）, which makes it attractive for space-based applications.     

Equation of State of Dense Liquid Nitrogen in the Region of the Dissociative Phase Transition

We have measured the equation of state for liquid nitrogen compressed dynamically to a pressure of 10-60 GPa by employing a two-stage light-gas gun.The data show a continuous phase transition above the shock pressure of 33GPa,as indicated previously by shock wave experiments.A theoretical model has been derived to examine the experimental data by inducing a molecular dissociative fraction.According to theoretical and experimental date the phase transition was thought to be a molecular dissociative phase transition.     

相互作用玻色子模型中相变特征量的玻色子数N依赖行为

研究了相互作用玻色子模型中各种对相变比较敏感的特征量相对于总玻色子数N的依赖行为. 通过比较这些特征量在U(5)-SU(3)过渡区以及U(5)-O(6)过渡区在不同N情况下的临界行为, 发现BE(2)比值B(E2;4₁→2₁)/B(E2};2₁→0₁)和B(E2;0₂→2₁)/B(E2;2₁→0₁)等可以作为完全区分一级相变和二级相变的有效序参量.     

Calculation of the Specific Heats for the Ⅱ—Ⅲ and Ⅱ—Ⅳ Phase transitions in NH4I

This study gives our calculation for the specific heats CVI due to an Ising model using the observed Cp data for the Ⅱ-Ⅲ and Ⅱ-VI phase transitions in NH4I.By fitting to the CP data we determine the values of the critical exponent for the pressure of 0.14GPa(Ⅱ-Ⅲ phase transition)and for the pressures of 0.75,1.35and 1.97 GPa (II-IV phase transition)in NH4I.Our exponent values values are close to the predicted values of the specific heat in a three-dimensional Ising model.Our calculated CVI are in good agreement with the experimental CP for NH4I in most cases.     

蓝光相变光盘的多层膜结构设计

为了使光盘获得优良的记录／读出性能并能够长期稳定地使用，必须优化设计相变光盘的多层膜结构。采用自行设计的模拟分析相变光盘读出过程设计软件，从光学角度出发模拟计算了蓝光(405nm)相变光盘的膜层结构，研究了多层膜系的反射率和反射率对比度等光学参量与各层膜厚度和槽深的关系。研究得出的最佳多层膜结构为：下介电层／记录层／上介电层／反射层的厚度对于台记录为100nm／10nm／25nm，／60nm，而对于槽记录则为140nm／15nm／30nm，／60nm，槽深为50nm。模拟计算结果对于将来高密度蓝光相变光盘的制备具有一定的指导意义。     

三羟甲基甲胺、季戊四醇及其二元体系固-固相变的变温红外光谱研究

利用傅里叶变温红外光谱仪分别测定了三羟甲基甲胺（TAM）、季戊四醇（PE）及其二元体系变温红外谱。实验表明，多元醇分子中羟基吸收峰随温度升高耐发生位移向高波数移动，此结果既能反映多元醇及其二体系固－固相变的温度区间，又与转变热相对应，从而揭示了多元醇及其二元体系固－固相变贮热的机理。     

室温下压致铁钴镍合金的bcc→hcp相变

 本文采用高压X光衍射方法在金刚石对顶压砧中在位地（in situ）研究了Fe₆₈Co₂₄Ni₈（wt%）合金在室温下的压致bcc→hcp结构相变和直到40.5 GPa的等温压缩行为。实验结果表明该合金在常压下为bcc结构，晶格常数a₀=(0.287 0±0.000 1) nm，体积V₀=(7.119±0.007) cm³/mol，密度ρ₀=(7.981±0.008) g/cm³；在20.9 GPa附近出现bcc→hcp结构相变，两相共存压力区约10 GPa，在此区域内有晶面间距d(002)_hcp=d(110)_bcc，且原子平面(002)_hcp//(110)_bcc，hcp相比bcc相体积减小(0.33±0.02) cm³/mol；高压相hcp结构的晶格参数比值c/a=1.608±0.004；相变后原子配位数的增加使得hcp相(002)平面内及(002)平面间的最近邻原子间距比bcc相最近邻原子间距分别增大约1.6%和0.5%；用Murnaghan状态方程对实验数据进行最小二乘法拟合，得到bcc相B₀=(130±13) GPa，B₀'=12.6±0.5；hcp相V₀=(6.62±0.04) cm³/mol，B₀=(243±21) GPa，B₀'=6.8±0.3；对于该合金的bcc→fcp相变时的结构转变机制做了详细的讨论。     

混合流体浸润相变的研究(Ⅲ)——二元系统的四相共存态

本文讨论二元Sullivan系统的一个特殊状态——二元四相系的浸润相变性质,该系统的许多性质可以通过对两个二元二相系的讨论而得到。结果表明:这一系统同时存在一级相变和二级相变。 关键词：     

键座渗流与稀磁体系的相变

本文首先将键渗流和座渗流中的普适关系加以推广,建立了键座渗流的相界关系;接着研究了稀磁体系的相变问题,应用Potts模型,推出稀磁体系的铁磁-顺磁和反铁磁-顺磁相交的相界关系。与已往文献中处理这类问题所采用的级数法、有限集团近似、数值模拟和重整化群等方法相比,本文所给出的解析式具有使用方便、简单、物理概念清晰,且较为精确等优点.