全文获取类型
收费全文 | 2803篇 |
免费 | 952篇 |
国内免费 | 270篇 |
专业分类
化学 | 1171篇 |
晶体学 | 62篇 |
力学 | 201篇 |
综合类 | 26篇 |
数学 | 199篇 |
物理学 | 2366篇 |
出版年
2024年 | 3篇 |
2023年 | 11篇 |
2022年 | 51篇 |
2021年 | 82篇 |
2020年 | 62篇 |
2019年 | 81篇 |
2018年 | 68篇 |
2017年 | 109篇 |
2016年 | 98篇 |
2015年 | 136篇 |
2014年 | 187篇 |
2013年 | 239篇 |
2012年 | 226篇 |
2011年 | 235篇 |
2010年 | 194篇 |
2009年 | 178篇 |
2008年 | 211篇 |
2007年 | 239篇 |
2006年 | 213篇 |
2005年 | 185篇 |
2004年 | 166篇 |
2003年 | 160篇 |
2002年 | 128篇 |
2001年 | 128篇 |
2000年 | 90篇 |
1999年 | 74篇 |
1998年 | 65篇 |
1997年 | 67篇 |
1996年 | 35篇 |
1995年 | 49篇 |
1994年 | 41篇 |
1993年 | 28篇 |
1992年 | 28篇 |
1991年 | 23篇 |
1990年 | 35篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 11篇 |
1985年 | 14篇 |
1984年 | 6篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1959年 | 1篇 |
排序方式: 共有4025条查询结果,搜索用时 15 毫秒
91.
Zh. Bo J. H. Yan X. D. Li Y. Chi K. F. Cen B. G. Chéron 《Plasma Chemistry and Plasma Processing》2007,27(5):546-558
The combined effects of oxygen and water vapor on three typical volatile organic compounds, i.e. tetrachloromethane, n-butane and toluene, decomposition efficiency under gliding arc gas discharge conditions are studied. The electron density
and the density of the reactive radicals such as O and OH are modified by addition of oxygen and water vapor. Consequently,
the decomposition process can be enhanced or suppressed, depending on the involved chemical structures and reaction channels.
The addition of oxygen and water vapor suppresses the tetrachloromethane decomposition which indicates that this process is
mainly controlled by the electron dissociation reactions. By contrast, the n-butane and toluene decompositions are enhanced, which shows that they can be mainly ascribed to the radical induced reactions.
Especially, in a moist atmosphere the OH radicals are supposed to play the most important role in the n-butane decomposition process. 相似文献
92.
93.
晶态氮化碳薄膜的低温合成 总被引:1,自引:0,他引:1
The synthesis of carbon nitride films at low temperature has been investigated using pulsed arc discharge from methanol solution with nitrogen atmosphere. Raman spectra and X-ray diffraction (XRD) analysis suggest that crystalline carbon nitride films may be prepared at low substrate temperature (220 ℃). At same time, the substrate temperature has a significantly effect on the nitrogen content and structure of the films. Increasing substrate temperature (300 ℃) would decrease the content of nitrogen in the films and result in a formation of carbon films. 相似文献
94.
95.
锂离子电池负极合金CoSn和Cu-Sn的制备与表征 总被引:9,自引:0,他引:9
CoSn alloy and Cu-Sn samples were synthesized by H2-reduction following solid-state reaction between Co(Ⅱ), Cu(Ⅱ), Sn(Ⅳ) and NaOH at ambient temperature. The samples were characterized by XRD, SEM. The results showed that CoSn alloy (80~200nm) is globe-shaped, ultrafine hexagonal material, and Cu-Sn alloy powder consists of two phases, i.e. Cu6Sn5 and Cu3Sn. Cu-Sn powder has spherical morphology and the particle size is estimated to be 60~70nm. The electrochemical performances of CoSn alloy and Cu-Sn powder were studied using lithium-ions model cell Li/LiPF6 (EC+DMC)/CoSn (or Cu-Sn). It was demonstrated the reversible discharge capacities for 10 cycles keep above 280mAh·g-1 for nanophase Cu-Sn, and 60mAh·g-1 for CoSn alloy. Differ-ential capacity plots showed that the reaction mechanisms of Cu-Sn with lithium were reversible. 相似文献
96.
The gas–liquid gliding arc discharge plasma is used directly to study degradation and dechlorination of 4-Chlorophenol (4-CP)
in solution. The typical AC waveforms of discharge voltage and current revealed that the discharge behavior was not definitely
periodic. The chemical oxygen demand (COD) abatement of 4-CP solution with stainless steel electrode is higher than that with
aluminum or brass electrode; When air was used as carrier gas the COD abated from 1,679.2 to 190 mg/L (i.e., 88.68% abatement)
after 76 min plasma treatment; Increasing gas–liquid mixing rate could also increase the degradation of 4-CP; adding appropriate
amounts of Fe2+ or iron chips to the solution were found to be favorable for 4-CP degradation. The main intermediates of 4-CP degradation
are p-benzoquinone, hydroquinone, 4-chlorocatechol, p-chloronitrobenzene, and ring cleavage products (acetic acid, glycol,
propanone, and others). Furthermore, possible pathways of 4-CP degradation in solution are proposed. 相似文献
97.
98.
The analytical performance of a glow discharge quadrupole mass spectrometer is demonstrated using sintered tungsten as an example. The inherent problem of molecular interferences in glow discharge mass Spectrometry has been considerably reduced using neon as a complementing discharge gas. Particular attention has been paid to time dependences. Analytical figures of merit are presented. 相似文献
99.
Masao Matsuoka Tsuyoshi Matsuda June Tamaki Yoshifumi Yamamoto Chiaki Iwakura 《Research on Chemical Intermediates》2006,32(5):389-402
Laves-phase hydrogen storage alloy has a high potential for use as negative electrode material as alternative for the misch-metal-based
material. In order to improve the energy density and the rate capability of negative electrode, chemical and mechanical modification
of Lavesphase alloy with different stoichiometric ratios was carried out. Discharge capacity and high-rate dischargeabilty
was evaluated by electrochemical methods and the characterization of Laves-phase alloy was made by X-ray diffraction, SEM
observation and PCT measurement. The best result in discharge capacity could be obtained for stoichiometric Laves-phase alloy
with a composition of Zr0.9Ti0.1Ni1.1Co0.1Mn0.5V0.2Cr0.1 by boiling in 10 M KOH solution. On the other hand, the high-rate dischargeability was increased remarkably by introducing
mechanical grinding before alkali treatment. The cause for improved performance was discussed on the basis of thermodynamic
stability of metal hydride and changes in crystal structure and surface morphology influencing on diffusion coefficient and
diffusion path length of hydrogen. 相似文献
100.
R. D. Apostolova I. V. Kirsanova E. M. Shembel 《Russian Journal of Electrochemistry》2006,42(2):173-182
Electrolytic (e) cobalt oxide of a spinel structure, e-Co3O4, is obtained from the sulfate and nitrate (aqueous, water-alcohol) solutions containing Co2+ with the aim of using it in thin-layer anodes of lithium-ion batteries. The physicochemical and structural properties of the synthesized compounds are examined using thermal and x-ray diffraction analyses, absorption IR spectroscopy, and atomic force microscopy. The electrochemical characteristics of e-Co3O4 are determined in breadboards of lithium power sources and in the lithiumion system LiCoO2/e-Co3O4. 相似文献