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Electrolytic Co3O4 for thin-layer anodes of lithium-ion batteries
Authors:R D Apostolova  I V Kirsanova  E M Shembel
Institution:(1) Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine;(2) Ener 1, Ft. Lauderdale, FL 33309, USA
Abstract:Electrolytic (e) cobalt oxide of a spinel structure, e-Co3O4, is obtained from the sulfate and nitrate (aqueous, water-alcohol) solutions containing Co2+ with the aim of using it in thin-layer anodes of lithium-ion batteries. The physicochemical and structural properties of the synthesized compounds are examined using thermal and x-ray diffraction analyses, absorption IR spectroscopy, and atomic force microscopy. The electrochemical characteristics of e-Co3O4 are determined in breadboards of lithium power sources and in the lithiumion system LiCoO2/e-Co3O4.
Keywords:electrolytic Co3O4            cathode  anode  lithium-ion battery  discharge  charge
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