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121.
利用线性组合算符和幺正变换相结合的方法,研究了声子色散对极性晶体中磁极化子基态能量的影响.计及纵光学(LO)声子色散,在抛物近似下导出了极性晶体中磁极化子基态能量随电子-纵光学声子耦合常数、回旋共振频率和声子色散系数的变化关系.数值计算结果表明磁极化子基态能量随声子色散系数和电子-纵光学声子耦合常数的增大而减小,随回旋共振频率增大而增大. 相似文献
122.
Reference spectra of important adsorbed organic and inorganic phosphate binding forms for soil P speciation using synchrotron‐based K‐edge XANES spectroscopy 下载免费PDF全文
Jörg Prietzel Gertraud Harrington Werner Häusler Katja Heister Florian Werner Wantana Klysubun 《Journal of synchrotron radiation》2016,23(2):532-544
Direct speciation of soil phosphorus (P) by linear combination fitting (LCF) of P K‐edge XANES spectra requires a standard set of spectra representing all major P species supposed to be present in the investigated soil. Here, available spectra of free‐ and cation‐bound inositol hexakisphosphate (IHP), representing organic P, and of Fe, Al and Ca phosphate minerals are supplemented with spectra of adsorbed P binding forms. First, various soil constituents assumed to be potentially relevant for P sorption were compared with respect to their retention efficiency for orthophosphate and IHP at P levels typical for soils. Then, P K‐edge XANES spectra for orthophosphate and IHP retained by the most relevant constituents were acquired. The spectra were compared with each other as well as with spectra of Ca, Al or Fe orthophosphate and IHP precipitates. Orthophosphate and IHP were retained particularly efficiently by ferrihydrite, boehmite, Al‐saturated montmorillonite and Al‐saturated soil organic matter (SOM), but far less efficiently by hematite, Ca‐saturated montmorillonite and Ca‐saturated SOM. P retention by dolomite was negligible. Calcite retained a large portion of the applied IHP, but no orthophosphate. The respective P K‐edge XANES spectra of orthophosphate and IHP adsorbed to ferrihydrite, boehmite, Al‐saturated montmorillonite and Al‐saturated SOM differ from each other. They also are different from the spectra of amorphous FePO4, amorphous or crystalline AlPO4, Ca phosphates and free IHP. Inclusion of reference spectra of orthophosphate as well as IHP adsorbed to P‐retaining soil minerals in addition to spectra of free or cation‐bound IHP, AlPO4, FePO4 and Ca phosphate minerals in linear combination fitting exercises results in improved fit quality and a more realistic soil P speciation. A standard set of P K‐edge XANES spectra of the most relevant adsorbed P binding forms in soils is presented. 相似文献
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Structural hydroxyl and deuteroxyl groups within the K4[SiW12O40]/Al2O3 and K6[SiW11PdO39]/Al2O3 systems were studied by diffuse-reflectance FTIR spectroscopy in a spectral range of fundamental stretching vibrations, first
overtones, and combination bands of stretching and bending vibrations. For hydroxyl groups, the region of combination vibrations
is the most informative. The calculated frequencies of bending vibrations of hydroxyl groups (865 and 730 cm−1) are characteristic of acidic OH groups.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2017–2020, October, 1999. 相似文献
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Method of high-order lagrange multiplier and generalized variational principles of elasticity with more general forms of functionals 总被引:7,自引:6,他引:1
钱伟长 《应用数学和力学(英文版)》1983,4(2):143-157
It is known[1]that the minimum principles of potential energy andcomplementary energy are the conditional variation principles underrespective conditions of constraints.By means of the method of La-grange multipliers,we are able to reduce the functionals of condi-tional variation principles to new functionals of non-conditionalvariation principles.This method can be described as follows:Mul-tiply undetermined Lagrange multipliers by various constraints,andadd these products to the original functionals.Considering these un-determined Lagrange multipliers and the original variables in thesenew functionals as independent variables of variation,we can see thatthe stationary conditions of these functionals give these undeter-mined Lagrange multipliers in terms of original variables.The sub-stitutions of these results for Lagrange multipliers into the abovefunctionals lead to the functionals of these non-conditional varia-tion principles.However,in certain cases,some of the undetermined Lagrangemultipliers ma 相似文献
129.
SDS及其与十二烷基三乙基溴化铵混合体系在矿化水中的表面活性 总被引:9,自引:1,他引:8
测定了十二烷基硫酸钠(SDS)、十二烷基三乙基溴化铵(DTEAB)单一体系及不同摩尔比的混合体系在矿化水溶液中的表面活性,并与在纯水和NaCl水溶液中的表面活性作了比较.所得结果表明:(1)阴离子表面活性剂SDS在含Ca^2 ,Mg^2 等的矿化水中有比在纯水和NaCl水溶液中更好的表面活性.这一方面是由于矿化水中的Ca^2 ,Mg^2 对负电胶团和表面吸附层的强烈电性作用,另一方面在大量Na^ 存在时,钠钙盐混合表面活性剂Krafft点提高不多;(2)SDS和DTEAB混合物在矿化水中具有很强的增效作用,其表面活性的变化规律与在纯水和NaCl水溶液中基本相同,表明阴阳离子表面活性剂混合体系具有优异的抗矿化水性能.这些结果可用阴、阳表面活性离子的电性作用解释. 相似文献
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