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61.
62.
We investigate the structural behavior of a poly(styrene)-block-poly(acrylic acid) diblock copolymer which forms hexagonally-packed PS cylinders (C-phase) in the melt state. The water dispersion of this structure provides hairy cylinders which comprise a PAA swollen cylindrical brush with a height h tunable via its degree of ionization and the ionic strength in the solution, and a water-free, PS cylindrical core of constant radius RC. Such system constitutes an out-of-equilibrium frustrated model system: the selective swelling of the PAA brush results in a frustration of the interface curvature, which the ratio h/RC allows to quantify. Upon heating at a temperature higher than the glass transition temperature of the PS core, the glassiness of the core is relieved and the mechanical constraints arising from the selective swelling of the structure can be relaxed: the cylinders undergo a cylinder-to-sphere transition upon annealing at high temperature, when above a frustration threshold h/RC 1.8. Thanks to a careful mapping of the transition diagram, an undulating cylindrical morphology (UC) is identified between unchanged cylinders ( h/RC
1.8) and spheres ( h/RC 2.0), which appears to result from a Rayleigh-like pearling instability of the copolymer cylinders. 相似文献
63.
The continuous-wave laser properties of an efficient diode-pumped Nd:GdVO4 crystal operating at formed with a simple plane-concave cavity have been studied. With the incident pump power of 21 W, an output power of 6.9 W was obtained, giving an optical conversion efficiency of 32.8% and a slope efficiency of 35.3%. The laser characterization of two different Nd3+-doped concentration of Nd:GdVO4 crystals were studied. 相似文献
64.
This paper investigates the microscopic features which occur when a four-layered film is ablated using Q-switched Nd:YAG laser. The four-layered films consist of a vacuum-deposited aluminium layer (0.02 μm) upon an oriented polypropylene (OPP) film (30 μm) which has been laminated using an inert adhesive and a second OPP film. Laser radiation is absorbed principally by the aluminium layer, melting and/or vaporising it. Upon cooling, the aluminium layer is rearranged into discrete microscopic particles, which give laser-treated areas of the film a transparent appearance. Within the films are found microscopic features, which can be divided into three distinct types: aluminium demetallisation features, polymer distortion features and particle features. Features from each of these categories can exist within a single laser track depending upon the laser parameters used for transparentisation. 相似文献
65.
G. B. Parravicini A. Stella M. C. Ungureanu P. G. Merli A. Migliori P. Cheyssac R. Kofman 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):219-222
Both theoretical and experimental works give evidence that
gallium exhibits solid phases labelled , , , besides the
stable phase strongly dependent both on the size and the
confinement conditions. An experimental technique was used based
on capacitance and conductance measurements
vs. temperature in the
audiofrequency range. This technique is particularly sensitive
to the conditions of the investigated particle surface that
plays a fundamental role in the melting and more generally in
the phase transition processes. In particular the strict
relation between the derivative of the capacitance with respect
to the temperature, dC/dT, and the entropy of the system is
considered. In gallium nanoparticles 20 nm in radius, only the
phase is shown to occur. Further the transition to liquid phase
was detected. The melting process was found to start about 65 K
below the full melting temperature value. In the case of
particles 10 nm in radius, where different metastable phases may
occur, the capacitance vs.
temperature curve was found to display abrupt changes of the
slope. The singularities are associated to a well defined
transition temperature. 相似文献
66.
通过研究分析钨酸盐晶体Nd∶KY(WO4)2和Nd∶KG(WO4)2在室温下的吸收光谱,发现这2种晶体具有作为激光晶体的优良特性。根据Judd-Ofelt理论和测试所得的吸收光谱及数据,用VC++编程计算出晶体的谱线强度、振子强度、吸收截面等,拟合得Nd3+离子的3个晶场调节参数Ωλ(λ=2,4,6)的值,并从理论上计算了自发跃迁几率、能级寿命、荧光分支比和积分发射截面。从计算得出的荧光分支比β可以看出,Nd∶KY(WO4)2(β1060nm=0.4380)和Nd∶KG(WO4)2(β1060nm=0.4618)晶体荧光分支比都较大,计算了该晶体的X=Ω4/Ω6,并将其X值与其他晶体的X值加以比较,Nd∶KY(WO4)2和Nd∶KG(WO4)2均易于实现1.06μm激光输出,适合作为LD泵浦的钨酸盐晶体激光器。 相似文献
67.
68.
晶粒间界相对纳米Nd_2Fe_(14)B各向异性和矫顽力的影响 总被引:1,自引:0,他引:1
本文采用立方晶粒结构模型研究了晶粒间界相对纳米硬磁材料各向异性和矫顽力的影响.结果表明:晶粒间界相减弱了交换耦合作用.当晶粒尺寸D为定值时,随着晶粒间界相厚度d的增加,晶粒平均各向异性单调增加,而材料的有效各向异性Keff、矫顽力单调减小.我们计算的矫顽力随晶粒尺寸的变化与相关理论和实验结果基本一致. 相似文献
69.
70.
针对kJ级大能量钕玻璃固体脉冲激光器,对比研究了传统恒温水冷方式和采用加热控制的新型热管理技术下的激光棒温度分布情况。结果表明,采用新型热管理技术可大大降低棒内温度梯度,减小泵浦过程中的热效应,确保大能量激光输出;而且加热循环水的最佳升温值在单泵浦脉冲引起的激光棒平均温升值附近,使得径向温差最小,该最佳升温值与脉冲间隔时间有关,比如脉冲间隔15 s时,循环水在每个脉冲过后的最佳升温值为单泵浦脉冲引起的激光棒平均温升值的0.85倍;采用加热控制后水温和激光棒温度整体升高,因此在工作一个脉冲串后,必须恢复激光棒温度到初始状态,然后再进行下一个脉冲串工作。 相似文献