Synthesis,chiroptical properties of a helical polyacetylene derivative carrying urea moieties

A novel phenylacetylene derivative containing urea groups was synthesized and polymerized with a Rh catalyst to give the corresponding polymer, poly（1） with moderate number-average molecular weights. The poly（1） was soluble in toluene, CHCI3, CH2C12, THF, DMF, and DMSO, but insoluble in hexane, diethyl ether and MeOH. The specific rotation and circular dichroism （CD） spectroscopic studies revealed that poly（1） took predominantly one-handed helical structures. The presence of intramolecular hydrogen bonding was confirmed by liquid-state IR spectroscopy. The helicity of poly（1） could be tuned by temperature and anion. The helical conformation of the polymer was stable against Br but susceptible to F.     

Theoretical study on decay of the 4d core-excited states of Cs III

In a recent XUV photoabsorption spectrum of Cs Ⅲ ions by Cummings and O＇Sullivan [2001 J. Phys. B 34 199], rather large linewidths were found for the 4d^95s^25p^6 - 4d^105s^25p^5 transition which are quite in disagreement with corresponding quasi-relativistic multiconfiguration Hartree Fock （MCHF） calculation. In the present work, a detailed multiconfiguration Dirac-Fock study has been carried out to explore this discrepancy. Owing to the detailed consideration of electron correlation effects, some ‘forbidden＇ Auger decay channels, such as 4d^105s^25p^35d and 4d^105s^05p^6, would become ‘open＇. As a result, remarkable improvement of the linewidths has been obtained in our calculation. Furthermore, the theoretical Auger spectrum of the 4d^ 95s^25p^6 core-excited states of Cs Ⅲ ions is Riven in the present work.     

Stabilization of spiral wave and turbulence in the excitable media using parameter perturbation scheme

This paper proposes a scheme of parameter perturbation to suppress the stable rotating spiral wave, meandering spiral wave and turbulence in the excitable media, which is described by the modified Fitzhug-Nagumo （MFHN） model. The controllable parameter in the MFHN model is perturbed with a weak pulse and the pulse period is decided by the rotating period of the spiral wave approximatively. It is confirmed that the spiral wave and spiral turbulence can be suppressed greatly. Drift and instability of spiral wave can be observed in the numerical simulation tests before the whole media become homogeneous finally.     

用晶格玻尔兹曼方法研究螺旋波的产生机制和演化行为

采用五速正方晶格玻尔兹曼模型，由晶格玻尔兹曼方程推导得到了反应扩散方程.分析了Selkov反应扩散系统螺旋波的形成机制.零流边界条件下计算机数值模拟螺旋波的形成和破碎过程，发现Selkov反应扩散系统的失稳属于Doppler失稳.改变参数模拟系统的演化行为，发现不同的参数下系统可能到达三种不同的状态：均匀定态、混沌状态和螺旋波. 关键词： 晶格玻尔兹曼方法 螺旋波 计算机模拟     

圆截面弹性螺旋杆的稳定性与振动

基于Kirchhoff理论讨论圆截面弹性螺旋杆的动力学问题.以杆中心线的Frenet坐标系为参考系，建立用欧拉角描述的弹性杆动力学方程.讨论其在端部轴向力和扭矩作用下保持的无扭转螺旋线平衡状态.在静力学和动力学领域内讨论其平衡稳定性问题.还讨论了弹性杆平衡的Lyapunov稳定性和欧拉稳定性两种不同稳定性概念之间的区别和联系.在一次近似意义下证明了螺旋杆在空间域内的欧拉稳定性条件是时域内Lyapunov稳定性的必要条件.导出了解析形式螺旋杆三维弯曲振动的固有频率，为螺旋线倾角和受扰挠性线波数的函数. 关键词： 弹性螺旋杆 Kirchhoff动力学比拟 Lyapunov稳定性 欧拉稳定性     

螺旋槽回旋行波管高频特性分析

 在Foulds等人对螺旋槽结构进行深入分析的基础上，考虑了槽区内高次模式对慢波结构高频特性的影响。结果表明：槽宽较小时，结论与其结论吻合较好； 槽宽较大时，计算结果与其有较大差别。此外，讨论了螺旋槽结构参数对高频特性的影响，结果表明：除槽宽外的其它结构参数固定时，存在一个最佳的δ/L值，可以获得较弱的色散和较大的横向场幅值，适合做回旋行波管互作用结构。     

基于MATLAB的线性调频Z变换及应用

作为数字信号处理的一种算法,线性调频Z变换(Chirp-Z)是适用于更为一般情况下沿螺旋曲线计算有限时宽Z变换的快速变换算法,它使得DFT的运算变得相当灵活,为数字信号处理技术应用于各种高速信号的快速处理创造了良好的条件,从而大大推动了数字信号处理技术的发展.     

Helical Shell Structures of Ni-A1 Alloy Nanowires and Their Electronic Transport Properties

Six kinds of Ni-A1 alloy nanowires are optimized by means of simulated annealing. The optimized structures show that the Ni-A1 alloy nanowires are helical shell structures that are wound by three atomic strands, which is very similar to the case with pure metallic nanowires. The densities of states （DOS）, transmission function T（ E）, current-voltage （I - V） curves, and the conductance spectra of these alloy nanowires are also investigated. Our results indicate that the conductance spectra depend on the geometric structure properties and the ingredients of the alloy nanowires. We observe and study the nonlinear contribution to the I-V characteristics that are due to the quantum size effect and the impurity effect. The addition of Ni atoms decreases the conductance of the Ni-A1 alloy nanowire because the doping atom Ni change the electronic band structures and the charge density distribution. The interesting statistical results shed light on the physics of quantum transport at the nano-scale.     

邻苯二甲酸L—（＋）—2,3—O—亚异丙基苏力糖酯的两种构象式的 …

在晶（固）态下，化合物邻苯二甲酸Ｌ－（＋）－２，３－Ｏ－亚异丙苏力糖酯存在两种不同的构象形式，利用螺旋片段判定规则及ω＾－值，结合Ｘ射线衍线数据及扭转角数据，对这两种构象形式的所有螺旋片段进行了分析，尽管两种构象形式的净值螺旋性相反，但仍然得出总净值螺旋性与旋光方向一致的总论。