基于2-硫代海因的氟离子探针

通过异亮氨酸甲酯盐酸盐与4-硝基苯基异硫氰酸酯或4-氰基苯基异硫氰酸酯反应合成2-硫代海因探针1和2.在N,N-二甲基甲酰胺(DMF)中,用系列含阴离子的四正丁基铵盐来评价其阴离子识别能力.加入F-后,1和2的DMF溶液由无色立即变为黄色,而加入Cl-,4HSO-,Br-,3NO-和3 2CH CO-均不变,表明1和2对氟离子显示出良好的识别性能.核磁滴定氢谱揭示了F-与2-硫代海因的氢键作用引发了1和2的识别,结合常数显示1比2对F-更敏感.此外,1作为化学传感器还可以制成试纸检测F-.     

Synthesis,chiroptical properties of a helical polyacetylene derivative carrying urea moieties

A novel phenylacetylene derivative containing urea groups was synthesized and polymerized with a Rh catalyst to give the corresponding polymer, poly（1） with moderate number-average molecular weights. The poly（1） was soluble in toluene, CHCI3, CH2C12, THF, DMF, and DMSO, but insoluble in hexane, diethyl ether and MeOH. The specific rotation and circular dichroism （CD） spectroscopic studies revealed that poly（1） took predominantly one-handed helical structures. The presence of intramolecular hydrogen bonding was confirmed by liquid-state IR spectroscopy. The helicity of poly（1） could be tuned by temperature and anion. The helical conformation of the polymer was stable against Br but susceptible to F.     

Urea-based polyacetylenes as an optical sensor for fluoride ions

Novel acetylenes carrying urea groups, 1-(4-ethynylphenyl)-3-(4-nitrophenyl) urea (1), 1-(4-propargyl)-3-(4-nitrophenyl) urea (2), were synthesized and polymerized with rhodium catalyst. Polymers [poly(1) and poly(2)] with moderate molecular weights were obtained in good yields. The anion sensing ability of poly(1) and poly(2) was estimated using the tetra-n-butylammonium (TBA) salts of a series of anions in DMF. Upon the addition of F-, the color of the DMF solution of poly(1) and poly(2) immediately turned to a different color, while the color of solution changed slightly upon addition of Cl-, HSO4-, Br-, and NO3-, indicating the F- sensing ability of poly(1) and poly(2). The 1H-NMR titrations of poly(1) revealed that the colorimetric response of poly(1) was triggered by the urea/F- interaction through the hydrogen bonding and/or deprotonation process. The absorption spectra titration and Hill plot analysis were carried out to measure the F- binding ability, and the Hill coefficient in the poly(1)/F- complexation was found to be 5.8. This result clearly indicated that this binding mode between poly(1) and F- was based on a positive homotropic allosterism.     

Thiourea based conjugated polymer fluorescent chemosensor for Cu+ and its use for the detection of hydrogen peroxide and glucose

A novel conjugated polymer, poly(1), containing thiourea moieties in main chain is synthesized via Suzuki coupling reaction. The addition of cuprous ion quenches the fluorescence of poly(1), whereas the fluorescence changes slightly upon addition of other metal ions, exhibiting the fluorescent almost turn-off sensing ability towards Cu⁺. When hydrogen peroxide was added to the solution containing poly(1) and Cu⁺, Cu⁺ was oxidized into Cu²⁺, resulting in the fluorescence recovery. The H₂O₂ released from glucose oxidation by glucose oxidase (GOD) also recovered the fluorescence of poly(1)/Cu⁺ solution. The results indicated that the poly(1)/Cu⁺ solution could serve as a sensing platform for hydrogen peroxide and glucose.     

Multiple ground-based observations at Zhongshan Station during the April/May 1998 solar events

Simultaneous observations at Zhongshan Station, Antarctica, during May 1-7, 1998 are presented to show the responses of the polar ionosphere to the April/May 1998 solar events. One of the main geo-effects of the solar events resulted in the major magnetic storm on May 4. At the storm onset on May 2 the ionosphere F2 layer abruptly increased in altitude, the geomagnetic H-component started negative deviation and the spectral amplitude of the ULF wave intensified. Both large isolated riometer absorption and large negative deviation of the geomagnetic H-component occurred at about 0639UT. There was a time lag of about one hour and ten minutes between the storm onset and the IMF southward turning, as measured by the WIND satellite. The polar ionosphere was highly disturbed, as shown by frequent large deviations of the geomagnetic H-component, large riometer absorption events and strong ULF waves in all the courses of the storm. The absorption increased greatly causing the digisonde to be blackout most of the time. However, the data still showed a substantial decrease in the F2 electron density and oscillation of the F2 layer peak height with an amplitude exceeding 200 km.     

The polar ionosphere at Zhongshan Station on May 11, 1999, the day the solar wind almost disappeared

The solar wind almost disappeared on May 11,1999: the solar wind plasma density and dynamic pressure were less than 1cm-3 and 0.1 nPa respectively, while the interplanetary magnetic field was northward. The polar ionospheric data observed by the multi-instruments at Zhongshan Station in Antarctica on such special event day was compared with those of the control day (May 14). It was shown that geomagnetic activity was very quiet on May 11 at Zhongshan. The magnetic pulsation, which usually occurred at about magnetic noon, did not appear. The ionosphere was steady and stratified, and the F2 layer spread very little. The critical frequency of dayside F2 layer, foF2, was larger than that of control day, and the peak of foF2 appeared 2 hours earlier. The ionospheric drift velocity was less than usual. There were intensive auroral Es appearing at magnetic noon. All this indicates that the polar ionosphere was extremely quiet and geomagnetic field was much more dipolar on May 11. There were some signatures of auroral substorm before midnight, such as the negative deviation of the geomagnetic H component, accompanied with auroral Es and weak Pc3 pulsation.     

南极中山站宁静日午后极光事件分析

对１９９７ 年６ 月２ 日１１２７～１７００ ＵＴ,在南极中山站（不变地磁纬度为７４．５Ｓ,ＭＬＴ＝ ＵＴ＋ ２）利用全天空极光摄像机和三波段极光扫描光度计观测到的午后极光进行了分析,发现宁静日午后极光的形态随磁地方时变化．在午后早些时候,辉度较弱的冕状极光出现在中山站的极向侧和日向侧;随后出现的是来自日侧的带状极光,该结构东向传播,赤道向运动;在午后较晚的时候出现的是来自夜侧的带状极光．同时将午后极光与当地地磁观测、ＤＭＳＰ／Ｆ１１ 卫星的粒子观测以及ＷＩＮＤ卫星的ＩＭＦ观测进行了对照分析,认为宁静日午后极光中的分离结构是由来自磁层顶附近的粒子沉降产生的,其变化和运动与地磁Ｈ 分量和ＩＭＦＢｚ 分量的变化相关．     

前向多重散射矩方程的解及其在电离层闪烁中的应用

本文引入了矩空间的概念,在矩空间中研究了前向多重散射(m+n)阶矩方程,得到了形式上与矩的阶数无关的叠代解,井导出了一阶矩、二阶对称矩和四阶对称矩的计算公式。将其应用于电离层闪烁研究得到了闪烁指数S₄的理论公式,与实验结果比较表明,理论公式在比较宽的范围内与实验符合得较好。最后讨论了幅度闪烁的相关函数。