全文获取类型
收费全文 | 5906篇 |
免费 | 625篇 |
国内免费 | 5953篇 |
专业分类
化学 | 10740篇 |
晶体学 | 119篇 |
力学 | 57篇 |
综合类 | 230篇 |
数学 | 21篇 |
物理学 | 1317篇 |
出版年
2024年 | 46篇 |
2023年 | 181篇 |
2022年 | 168篇 |
2021年 | 166篇 |
2020年 | 164篇 |
2019年 | 172篇 |
2018年 | 124篇 |
2017年 | 165篇 |
2016年 | 170篇 |
2015年 | 198篇 |
2014年 | 460篇 |
2013年 | 400篇 |
2012年 | 313篇 |
2011年 | 381篇 |
2010年 | 321篇 |
2009年 | 438篇 |
2008年 | 519篇 |
2007年 | 415篇 |
2006年 | 472篇 |
2005年 | 542篇 |
2004年 | 447篇 |
2003年 | 567篇 |
2002年 | 500篇 |
2001年 | 479篇 |
2000年 | 384篇 |
1999年 | 342篇 |
1998年 | 362篇 |
1997年 | 379篇 |
1996年 | 296篇 |
1995年 | 281篇 |
1994年 | 291篇 |
1993年 | 303篇 |
1992年 | 326篇 |
1991年 | 261篇 |
1990年 | 295篇 |
1989年 | 316篇 |
1988年 | 164篇 |
1987年 | 151篇 |
1986年 | 154篇 |
1985年 | 130篇 |
1984年 | 107篇 |
1983年 | 103篇 |
1982年 | 18篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
WangZhenglin MaXinwen 《近代物理研究所和兰州重离子加速器实验室年报》2003,(1):96-97
We have investigated fragment emission from molecularions in H2^r collisions between S^q and H2 with incident energies of 12.5, 15.625, 18.75, 21.875, 25, 28.125, 31.25, 34.375, 37.5, 40.625, and 43.75 keV/u, respectively. The energy distributions of the fragments are measured by time-of-flight techniques. The experimental results show evidences for molecular Coulomb explosion and dissociation. A program[1] is estab-lished based on the Monte Carlo technique to simulate the time-of-flight spectrum of fragment ions with different initialkinetic energy in ion-Molecule collisions. Simulations are done for S^2 H2 collisions and compared with experimental results. 相似文献
12.
黄龙 《新疆大学学报(理工版)》2003,20(2):130-132
用正电子湮没寿命谱技术研究了2.4×1O15/cm2、2.2×1016/cm2注量的85MeV19F离子辐照N型GaP和1.6×1016/cm 2注量的85MeV19F离子辐照P型InP所产生的辐照缺陷.结果表明:两种注量辐照在GaP中均产生较高浓度的单空位.其浓度随着辐照注量的增大而增加;辐照也在InP中产生较高浓度的单空位. 相似文献
13.
YunXiaWANG LinJIA ZhenSHI 《中国化学快报》2003,14(6):561-564
The addition-hydrolysis reaction of benzimidazolium salt with some mono- and bifunctional amine nucleophiles is reported,and a novel method of biomimetic synthesis for formamides and heterocycle compounds is provided. 相似文献
14.
Theoretical Analysis of Characteristics of GaxInl—x NyAsl—y/GaAs Quantum Well Lasers with Different Intermediate Layers 下载免费PDF全文
Based on the band anticrossing model, the effects of the strain-compensated layer and the strain-mediated layero n the band structure, gain and differential gain of GalnNAs/GaAs quantum well lasers have been investigated. The results show that the GaNAs barrier has a disadvantage in increasing the density of states in the conduction band. Meanwhile, the multilayer quantum wells need higher transparency carrier density than the GalnNAs/GaAs single quantum well with the same wavelength. However, they help to suppress the degradation of the differential gain. The calculation also shows that from the viewpoint of band structure, the strain-compensated structure and the strain-mediated structure have similar features. 相似文献
15.
报道了新合成的二氰基二硫纶·菲咯啉-5,6-二酮合铜(Ⅱ)配合物CuLL′(L=mnt2-, 1,2-dicyano-1,2-ethylenedithiolate; L′=phen-5,6-dione, 1,10-phenanthroline-5,6-dione)的变温磁化率和电子顺磁共振波谱表征结果. 发现微晶粉体型的标题配合物CuLL′具有一定的顺磁性,形成四配位的近似于方形的结构. 探讨了这种配合物磁学特性与结构的关系. 相似文献
16.
A New Triterpene from the Orchid Pholidota yunnanensis 总被引:2,自引:0,他引:2
ZhiMingBI ZhengTaoWANG LuoShanXU 《中国化学快报》2004,15(10):1179-1181
A new triterpene, 25-methylenecyclopholidonyl p-hydroxy-trans-cinnamate, was isolated from a orchid Pholidota yunnanensis. The structure elucidation and ^1H, ^13C-NMR assignments were achieved by spectral and chemical method. 相似文献
17.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
18.
Solid Phase Synthesis of 2-Substituted 1,3-Oxazin-6-ones Using Resin-bound Cyclic Malonic Acid Ester
A facile solid phase synthesis of 2-substituted 1,3-oxazin-6-ones using polymer-supported Meldrum‘s acid has been reported. Reaction of the resin-bound cyclic malonic acid ester with triethyl orthoformate and subsequent double substitution with amide, afforded the corresponding polymer-supported acylaminomethylene cyclic malonic acid ester, which upon thermal treatment led to 1, 3-oxazin-6-ones in good yields and with high purity. 相似文献
19.
LinBAI JinXianWANG 《中国化学快报》2004,15(3):286-287
A simple, rapid and environmental friendly method for the synthesis of biaryl compounds under microwave irradiation is reported. 相似文献
20.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献