Solvothermal synthesis of TiO2: anatase nanocrystals and rutile nanofibres from TiCl4 in acetone

This work reports a new synthetic approach for single‐phase TiO₂ nanomaterials by solvothermal treatment of titanium tetrachloride in acetone at 80–110 °C. Small, uniform, and yet size‐tunable (5–10 nm) anatase titania nanocrystallites were obtained using a low concentration of TiCl₄ in acetone (i.e., at molar ratios of TiCl₄/acetone ≤ 1:15) in the temperature range of 80–110 °C, while rutile nanofibers were synthesized using a high concentration of TiCl₄ (e.g., TiCl₄/acetone = 1:10) at 110 °C. Copyright © 2007 John Wiley & Sons, Ltd.     

Hydrothermal synthesis of FeS2 for lithium batteries

Nanocrystalline FeS₂ cathode material of lithium cell was synthesized from cheap materials of FeSO₄, Na₂S₂O₃, and sulfur by a hydrothermal process. The scanning electron microscopy analysis showed the obtained material was nano-sized, about 500 nm. The X-ray powder diffraction analysis showed that the synthetic FeS₂ material had two phases of the crystalline structure, pyrite and marcasite. The phase of marcasite seems to have no negative effect on the electrochemical performance of the material. The synthetic FeS₂ showed a significant improvement of electrochemical performance for Li/FeS₂ cells.     

微脉冲电子枪的初步实验研究

给出了微脉冲电子枪的模拟计算及其初步实验结果. 该电子枪采用铜铝镁合金作为冷阴极材料, 在以磁控管作为微波功率源的出束实验中得到了100mA/cm²的电流密度.实验结果与次级电子倍增解析计算和SEEG程序的模拟计算结果基本符合, 初步验证了微脉冲电子枪的基本原理, 为今后实验中得到更大的电流密度打下了基础.     

Spin tunneling properties in mesoscopic magnets: effects of a magnetic field

The tunneling of a giant spin at excited levels is studied theoretically in mesoscopic magnets with a magnetic field at an arbitrary angle in the easy plane. Different structures of the tunneling barriers can be generated by the magnetocrystalline anisotropy, the magnitude and the orientation of the field. By calculating the nonvacuum instanton solution explicitly, we obtain the tunnel splittings and the tunneling rates for different angle ranges of the external magnetic field ( θ _H = π/2 and π/2 < θ _H < π). The temperature dependences of the decay rates are clearly shown for each case. It is found that the tunneling rate and the crossover temperature depend on the orientation of the external magnetic field. This feature can be tested with the use of existing experimental techniques. Received 12 March 2001 and Received in final form 18 October 2001     

高功率多脉冲调制器研究

 研制了能产生多脉冲的高功率脉冲调制器，该调制器由初级储能系统、带绕式变压器、水介质Blumlein线和场发射二极管组成。在场发射二极管上获得3个峰值功率大于20 GW，半高脉宽约60 ns，脉冲间隔约15 ms，电压约400 kV的高功率电脉冲。理论计算、模拟计算与实验结果基本一致。分析表明主开关恢复时间是影响调制器输出脉冲时间间隔的主要因素。     

Cntinuity of Some Classes of Functions Related to Degenerate Parabolic Equations and Its Applications

We study some classes of functions satisfying the assumptions similar to but weaker than those for the classical B2 function classes used in the research of quasi-linear parabolic equations as well as the ones used in the research of degenerate parabolic equations including porous medium equationsl.Comsequently,we prove that a function in such a class is continuous.As an application,we obtain the estimate for the continuous modulus of the solutions of a few degenerate parabolic equations in divergence form,including the anisotropic porous equations.     

光子晶体中四能级系统的量子相干效应

研究了处于光子带隙材料中的四能级原子系统的电磁感应透明、自发辐射和光子开关效应，分析了其稳态与瞬态特性, 发现特殊的模密度能够导致反常的吸收、色散、自发辐射及瞬态无反转增益, 并可以通过外加调制场进行控制.详细讨论了特殊频率处模密度的变化对透明窗口和光子开关效应的影响. 关键词： 光子带隙材料 电磁感应透明 模密度 光子开关     

Nonlinear dynamics of a spinor Bose-Einstein condensate in a double-well potential

We examine the nonlinear dynamical behavior of a spinor Bose-Einstein condensate in a double-well potential. Considering a condensate with large number of atoms, such that it can be described using the mean field theory, we separate the spinor dynamics from the spatial dynamics under the single-mode approximation. We limit ourselves to certain initial conditions under which the spatial mode is frozen so that we can focus on the spinor dynamics only. Identifying collective spin variables of our system, we derive the corresponding nonlinear equations of motion for them. Employing standard stability analysis, we find and characterize fixed points of the system. For a wide range of physical parameters such as tunneling strength and non-linear interactions, as well as for various initial preparations of the system, we identify qualitatively different dynamical regimes possible in the system. In particular, complete and incomplete oscillations of spin variables between quantum wells are found. We also show that by bringing some fixed points close to each other in the phase space of the system, it is possible to induce amplitude modulation to those otherwise regular tunneling oscillations.     

光谱色散匀滑技术与衍射光学器件联用性能的空间频谱分析

基于空间频谱分析方法，建立了光谱色散匀滑技术(SSD: Smoothing by Spectral Dispersion)与衍射光学器件(DOE: Diffractive Optical Element)联用性能的简化分析模型，为SSD与DOE联用时，SSD参量的优化提供了理论依据.数值模拟了SSD各参量，包括脉冲时间、调制频率、位相调制系数、光栅线色散系数等对束匀滑性能的影响.模拟结果表明，SSD参量经过优化选取，且波前畸变随时间快速变化时，能获得良好的束匀滑性能.     

用于快点火研究的超短脉冲的相干合成

 利用傅里叶光学方法，建立了一个基于远场的多束超短脉冲相干合成的理论模型。研究了一个口径为50 cm，脉宽为1 ps的超短脉冲相干合成系统的各种误差对脉冲远场时域和空域特性的影响。结果表明：若要求远场的一倍衍射极限区域的积分能量分布达到理想情况下的90％，该系统的相位延迟误差小于0.63，沿x方向角度误差小于0.37 μrad，沿y方向角度误差小于0.34 μrad；若要求远场叠加脉冲的时域展宽小于25％，系统的剩余啁啾因子应小于1.32(不考虑相位延迟)或1.52(考虑0.63的相位延迟)。