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41.
Charged particles exist widely in variety of technological areas as well as in nature. Even a weak charge on the particles can significantly influence their electric interaction. We investigated the phenomenon of time-dependent electric interaction between two conducting spheres in an electrostatic field. A mirror-image method was developed to analyze this system, and the fundamental role of the charges on the spheres was studied. We concluded that charges conducted to the lower sphere through the alumina tube used in our system play a main role in determining the time-dependent interaction, whereas the influence from air ions is negligible. 相似文献
42.
《Communications in Nonlinear Science & Numerical Simulation》2014,19(6):1935-1944
This paper addresses the epidemiological modeling of computer viruses. By incorporating the effect of removable storage media, considering the possibility of connecting infected computers to the Internet, and removing the conservative restriction on the total number of computers connected to the Internet, a new epidemic model is proposed. Unlike most previous models, the proposed model has no virus-free equilibrium and has a unique endemic equilibrium. With the aid of the theory of asymptotically autonomous systems as well as the generalized Poincare–Bendixson theorem, the endemic equilibrium is shown to be globally asymptotically stable. By analyzing the influence of different system parameters on the steady number of infected computers, a collection of policies is recommended to prohibit the virus prevalence. 相似文献
43.
均匀光源被广泛应用于光学成像、遥感仪器的研制与标定等领域。提出了一种具有环形遮挡屏的积分球光源结构,以辐照均匀度分布特性为目标,利用蒙特卡洛(MCM)分析通过改变光源类型、挡板位置、开口大小、光源数量等参数对光源结构进行分析与优化。结果显示,朗伯特光源较之准直型光源辐照均匀度平均提高2.32%;挡板位置靠近积分球边缘时,辐照均匀度略低于其他位置;综合考虑辐射能量与照度均匀度,积分球开口比定在30%~35%区间内更为合适;辐射能量与光源数量呈线性关系,且不均匀度随光源数量在2.46%~3.38%波动。优化后的环形遮挡屏结构,可作为辐照均匀的光源应用于实际场景。 相似文献
44.
Developing efficient and recyclable heterogeneous catalysts for organic reactions in water is important for the sustainable development of chemical industry. In this work, Pd nanoparticles supported on DABCO-functionalized porous organic polymer was successfully prepared through an easy copolymerization and successive immobilization method. Characterization results indicated that the prepared catalyst featured big surface area, hierarchical porous structure, and excellent surface amphiphilicity. We demonstrated the use of this amphiphilic catalyst in two case reactions, i.e. the aqueous hydrodechlorination and Suzuki-Miyaura coupling reactions. Under mild reaction conditions, the catalyst showed high catalytic activities for the two reactions. In addition, the catalyst could be easily recovered and reused for several times. Also, no obvious Pd leaching and aggregation of Pd nanoparticles occurred up during the consecutive reactions. 相似文献
45.
采用高压烧结技术制备了稀土元素Tb掺杂的n型Bi2Te2.7Se0.3基纳米晶块体热电材料.将高压烧结成型的样品于633 K真空退火36 h.研究了Tb掺杂量对样品的晶体结构和热电性能的影响.结果表明,高压烧结制备的样品为纳米结构, Tb掺杂使样品的晶胞体积变大,功率因子增大,热导率降低,从而使ZT值提高.Tb掺杂量为x=0.004是最优的掺杂量,该掺杂量的高压烧结样品经退火处理后,于373 K时ZT值达到最大为0.99,并且在323-473 K范围内, ZT值均大于0.8,这对用于温差发电领域具有重要意义. 相似文献
46.
寻求具有较小晶格热导率klat的高热电性能的二维材料具有重要意义。基于从头计算和声子玻耳兹曼输运理论,该研究首先对二维CdO结构进行优化,并通过计算声子谱验证了单层CdO的动力学稳定性。在此基础上详细研究了单层CdO的声子输运性质。计算表明在室温下单层CdO的晶格热导率klat约为5.7 W/(m·K),低于单层石墨烯、磷烯、黑磷和MoS2等二维材料的晶格热导率。其中,Z方向声学模式(Z-direction acoustic, ZA),横声学支(transverse acoustic,TA),纵声学支(longitudinal acoustic, LA),Z方向光学模式(Z-direction optical, ZO),横光学支(transverse optical, TO),纵光学支(longitudinal optical, LO)对klat的百分比贡献分别为73.7%、13.9%、3.7%、2.8%、4.7%和1.2%。研究发现,ZA、TA、LA声学支和光学支之间的强散射是导致单层CdO低热导率的原因。本文计算结果可用于指导基于CdO的低维热电器件的设计。 相似文献
47.
The polypropylene (PP)/polystyrene (PS)/montmorillonite (MMT) blends were prepared by an innovative eccentric rotor extruder based on continuous elongational flow. Addition of MMT nanoparticles was found to reduce the PS droplet size and improve the compatibility of PP/PS. The MMT nanoparticles had clear intercalation and/or exfoliation structures and were located mostly at the interface of PP/PS. It was found that the intercalation and exfoliation of MMT was finished under the synergy of interfacial interaction and tensile deformation so that we called the mechanism as “MMT exfoliation mechanism induced by synergy of interface and tensile deformation”. The rheological analysis showed that incorporation of MMT led to an increase in complex viscosity to an optimum level (5 wt%), after which any further increase in MMT concentration decreased the complex viscosity. Moreover, the degree of crystallinity of blends was controlled by the heterogeneous nucleation effect of MMT and the inhibition effect of PS. 相似文献
48.
Interactions of cucurbit[7]uril (Q[7] host) with guest adenine (g1), adenosine (g2) and 2′,3′-o-isopropylideneadenosine (g3) were studied in details by 1H NMR, UV absorption spectroscopy, fluorescence spectroscopy and high performance liquid chromatography (HPLC) methods. We found that the suitable pH range for interaction was between 1 and 7, and the optimal pH range was between 2 and 4. The 1H NMR analysis indicated that Q[7] selectively interacted with the adenine moiety of the guests g1 and g2, while Q[7] selectively interacted with the D-ribose sugar ring moiety of the guest g3. Moreover, 1H NMR spectra showed that the exchange between the bound guest and the free guest was fast on the NMR time scale for the Q[7]-g1 and Q[7]-g2 systems. However, an obvious equilibrium between the bound host/guest and the unbound host/guest were observed in the Q[7]-g3 complex. Several methods were used to determine quantitatively the stability of the three host–guest inclusion complexes formed between Q[7] and the guests. The formation constants by UV and fluorescence were 1.90 × 105 L mol? 1 and 1.34 × 105 L mol? 1 for Q[7]-g1, 9.41 × 104 L mol? 1 and 4.24 × 104 L mol? 1 for Q[7]-g2, 4.50 × 104 L mol? 1 and 3.62 × 104 L mol? 1 for Q[7]-g3, respectively. HPLC method was also introduced to explore the interactions between Q[7] and the adenine and its derivatives. The formation constants of the host–guest inclusion complexes, as determined by HPLC, were 6.76 × 104 L mol? 1 for Q[7]-g1, 1.80 × 104 L mol? 1 for Q[7]-g2, 3.01 × 104 L mol? 1 for Q[7]-g3 respectively. Our study suggested that Q[7] could be a suitable host for the delivery of bioactive molecules, such as the adenine and its derivatives. 相似文献
49.
50.
Interaction between tetramethylcucurbit[6]uril (TMeQ[6], host) and the hydrochloride salt of α-furaldehyde-isonicotinyl-hydrazone hydrochloride (FIHH+, guest) was investigated using X-ray crystallography and spectroscopic methods. X-ray crystallography showed that the π–π stacking effect and hydrogen bonding resulted in the formation of a dumbbell-shaped supramolecule which contained two FIHH+@TMeQ[6] host–guest inclusion complexes. The host–guest interaction provided identifiable changes in the vibrational frequencies in the IR spectra. 1H NMR spectral analysis established a similar interaction model and revealed that TMeQ[6] preferred to include the furan moiety over the pyridine moiety of the FIHH+ guest molecule. Absorption spectrophotometric analysis suggested that the host and guest interact in a ratio of 1:1 with a stability constant K s = (3.52 ± 0.74) × 106 l mol? 1.pH titration confirmed that the host–guest interaction led to a clear change in the protonation constant of the title guest. Quantum chemical calculations were used to determine the possible mechanism of formation of the dumbbell-shaped complex. 相似文献