A new type of temperature‐responsive electrochemical sensor was constructed based on a glass carbon electrode modified by the composite containing temperature‐responsive polymer polystyrene‐poly N, N‐diethyl acrylamide‐polystyrene (PS‐PDEA‐PS) and fullerenes‐carboxylate multi‐walled carbon nanotubes (C60‐MWCNTs). The sensor was used for the electrochemical detection of catechol (CC). When the temperature is higher than the critical temperature (LCST) of PS‐PDEA‐PS, the electrochemical behavior of CC can be detected, which it is in the “on” state. When the temperature is lower than LCST, the composite modified film is in the “off” state and the electrochemical behavior of CC was not detected. Under the best experimental conditions, the sensor has a good detection range for catechol from 4.0 to 135.0 μM, with a LOD of 1.45 μM. In addition, the proposed sensor has good stability and reproducibility, and was successfully applied to the determination of catechol in real tap water. 相似文献
In this study, a novel dopamine modified graphene‐based photocatalytic membrane with Bi12O17Cl2 inserted was fabricated to modify the commercial cellulose acetate membrane via vacuum filtration method. Results showed the reduced graphene oxide (RGO)/poly(dopamine) (PDA)/Bi12O17Cl2‐CA photocatalytic composite membrane exhibited 98% removal efficiency for methylene blue (MB) within 100 minutes and 96% removal efficiency for 4‐CP within 160 minutes. Importantly, the photocatalytic composite membrane can simultaneously achieve dye degradation and oil‐water separation in only one device within a short time. And the as‐prepared membrane displayed great antifouling performance and recyclability after 10 cycles. Meanwhile, the membrane showed excellent stability in the agitated water bath or different pH conditions. In summary, the photocatalytic membrane investigated in this study opens new avenue for treatment of wastewater. 相似文献
Graphene oxide (GO) has triggered significant attention as a new type of self‐assembly membrane material. However, the low filtration flux and unstable performance of GO membrane limit its practical application. Hence, in this work, layered double hydroxides (LDHs), as a 2D material with double‐layer channel structure and positive electricity, were self‐assembled with GO at weight ratio of 7:3 by electrostatic interaction. Then, the GO/LDH hybrids combined with polydopamine (PDA) to obtain stable and high‐flux GO‐based membranes through vacuum filtration and the structure and morphology of as‐prepared samples were characterized by FT‐IR, XRD, XPS, and SEM. Furthermore, the separation performance and surface electronegativity of membranes were tested via pure water flux, rejection efficiency, recycle experiments, and zeta potential. Results revealed that the stability and flux of composite membrane were enhanced significantly compared with neat GO‐based membrane. Further, the dye rejection rate of methylene blue (MB) is higher than Congo red (CR) and rhodamine B (Rh B) and reached to 99.8%. 相似文献
Journal of Solid State Electrochemistry - Pd/C and Pd-Co/C nanocatalysts are prepared via a simple and environmentally friendly method and are used as anodic catalyst for direct... 相似文献
Journal of Solid State Electrochemistry - Hollow and porous structures grant fantastic physicochemical properties and widespread application in electrochemical energy storage. Here, hollow/porous... 相似文献
In this study, three different volume expansion ratios of expanded graphite (EG) are prepared and investigated to enhance the heat transfer efficiency of the sodium acetate trihydrate (SAT) composites. A series of SAT composite phase change materials (CPCMs) with EG were prepared. The influence of volume expansion ratio and mass fraction of EG on thermodynamic characteristics of SAT CPCMs was examined, including thermal conductivity, phase change temperature, enthalpy, latent heat storage and release time, and the degree of supercooling. Results showed that SAT CPCMs can be absorbed adequately by EG, and EG could enhance the heat transfer efficiency effectively. But it also brought some problems with the addition of all the three volume expansion ratios of EG, such as the poor enthalpy and serious supercooling. Particularly, the situation gets worse with the increase in mass and expansion ratio of EG. Therefore, it is better to choose the EG with proper expansion ratio or reduce the proportion of the EG which possesses higher expansion ratio. Besides, thermal cycling test and thermogravimetric analysis revealed that the SAT CPCMs with 3 mass% EG showed a good thermal stability.