Synthesis and structural characterization of novel,fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties

The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (S_NAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl₃, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 10³ to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004     

Reversible nonlinear conduction in high‐density polyethylene/acetylene carbon black composites at various ambient temperatures

The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004     

级联三能级原子与单模场相互作用下的腔场谱

研究了高Q腔内级联三能级原子与单模光场相互作用模型的腔场谱.结果表明,原子初态处于上能级时，随R=g2/g1的增大,真空场的拉比峰个数按2→6→4→2→4的规律变化，在R1时，所有的拉比峰都消失.在初始场较弱时,腔场谱可出现3峰、5峰或7峰.在初始场很强时,腔场谱中只有单一的经典共振峰.如果原子初态处在中能级且R=1,腔场谱为简单的对称双峰结构，与标准J-C模型的谱相似. 关键词： 级联三能级原子 单模光场 腔场谱     

半自由声场的全息重建和预测实验研究

半自由声场环境下的声源重建和声场预测研究对声全息技术走向实际应用具有非常重要的意义.在提出基于分布源边界点法的半自由声场全息重建和预测方法的基础上，对此展开了实验研究.并将重建和预测的结果与常规方法重建和预测的结果进行了比较和讨论，说明了重建预测过程中反射声压的影响和考虑反射声压的必要性，证明了所提出方法在解决半自由声场环境下存在地面反射时的声源重建和声场预测时的有效性和准确性.还提出了采用奇异值截断滤波和Tikhonov正则化方法来削弱测量误差的影响，从而进一步优化了重建结果，提高了全息成像的可信度. 关键词： 声全息 半自由场 边界点 声辐射 反射声     

p型导电掺In的SnO2薄膜的制备及表征

采用溶胶-凝胶提拉法成功地制备了p型导电掺In的SnO2薄膜.x射线衍射测试结果表明，掺In的SnO2薄膜保持SnO2的金红石结构.吸收谱测试结果表明，掺In的SnO2禁带宽度为3.8eV.霍尔测量结果表明，空穴浓度与热处理温度有很大的关系，525℃为最佳热处 理的温度.铟锡原子比在0.05—0.20范围内，空穴的浓度与In的含量有直接的关系，并随In含量的增加而增加. 关键词： SnO2 溶胶-凝胶法 p型导电     

稀土粉末Eu∶Y_2O_3的自由感应衰减量子拍

稀土固体是重要的激光和光电子材料。目前 ,由于以宽带信号和太赫兹比特数据传输率为特征的信息技术的发展 ,稀土固体材料的相干瞬态动力学过程成为宽带与高速信息光子学的基本物理问题之一。研究了室温下稀土粉末样品Eu3+ ∶Y2 O3自由感应衰减的相干瞬态光谱 ,这有助于理解有效的光吸收动力学、激发态弛豫、相干能量传递和超短光脉冲在稀土固体中的传播。用一对紫外飞秒相干光脉冲作用于稀土粉末样品Eu3+ ∶Y2 O3,然后监测物质激发态的布居数随两个激发脉冲之间的延时的变化 ,测量到其自由感应衰减量子拍 (FID) ,从拍频周期分析确定了其能级精细结构 ,能级的退相时间长达皮秒量级。理论分析和实验结果符合得很好。对稀土离子的量子干涉的研究 ,表明其在受激受控光放大方面具有潜在的应用前景     

利用爆磁压缩发生器产生高功率脉冲高电压

 爆磁压缩发生器产生脉冲高电压技术可以用于产生高功率微波及强电磁脉冲的实验研究。给出了利用螺旋型爆磁压缩发生器（HEMG）驱动电爆炸丝功率调节系统产生高功率脉冲高电压的实验方法和主要的结果。在利用HEMG驱动电爆炸丝断路开关（EEOS）产生脉冲高电压实验中，获得了最高电压700~800kV,功率大于20GW的脉冲输出。     

A Novel Cardiac Glycoside from Parepigynum funingesis

From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis.     

Synthesis and Photocytotoxicity of Mono-functionalised Porphyrin with Valine Moiety

A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested.     

Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.