硅氟唑对映体在直链淀粉手性固定相HPLC上的拆分

硅氟唑;三[(s)-α-甲基苯基氨基甲酸]直链淀粉酯;手性固定相;HPLC;手性拆分     

Upconversion Luminescence of SrTiO3:Er3+ Ultrafine Powders Produced by 785 nm Laser

Er3+ doped SrTiO3 ultrafine powders were prepared by solid state reaction in a molten NaCl flux. The structural properties were characterized by X-ray diffraction, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. The Stokes emission spectra of Er3+ in SrTiO3:Er3+ ranging from green to near infrared region were investigated under 514.5 nm laser excitation. The green and redupconverted luminescence spectra of Er3+ were measured under excitation into the 4I9=2 level by 785 nm laser. The upconversion mechanisms were studied in detail through laser power dependence and Er3+ ion concentration dependence of upconverted emissions, and results show that excited state absorption and energy transfer process are the possible mechanisms for the upconversion. The upconversion properties indicate that SrTiO3:Er3+ may be used in upconversion phosphors.     

Spinodal surface instability of soft elastic thin films

When the thicknesses of thin films reduce to microns or even nanometers, surface energy and surface interaction often play a significant role in their deformation behavior and surface morphology. The spinodal surface instability induced by the van der Waals force in a soft elastic thin film perfectly bonded to a rigid substrate is investigated theoretically using the bifurcation theory of elastic structures. The analytical solution is derived for the critical condition of spinodal surface morphology instability by accounting for the competition of the van der Waals interaction energy, elastic strain energy and surface energy. Detailed examinations on the effect of surface energy, thickness and elastic properties of the film show that the characteristic wavelength of the deformation bifurcation mode depends on the film thickness via an exponential relation, with the power index in the range from 0.749 to 1.0. The theoretical solution has a good agreement with relevant experiment results.     

一种含混合变量结构的可靠性优化设计方法

提出了一种含模糊变量和区间变量的混合模型结构可靠性优化设计方法.基于模糊可靠性理论建立了含混合变量结构的可靠性模型,给出了混合模型可靠度计算方法.进而,以混合模型可靠度为约束务件建立了可靠性优化设计模型,并针对该模型为两级优化嵌套问题,采用序列线性规划法进行了求解.实例计算表明文中方法是有效可行的.     

采用有限单元法计算梁任意形状截面特性

采用将梁截面离散化的方式,用数值积分计算截面的几何特性,并根据梁剪切变形和扭转理论,利用变分原理建立截面的有限元法方程,求解任意形状截面的扭转常数、剪切中心以及剪切面积修正系数等特性.本方法适用于各种形式的截面,具有计算精度高及适应性强的特点.根据上述理论编制了相应程序,按照不同的单元划分方式,分别计算出矩形截面截面特性,与理论解进行比较;又对舟山市定海长峙至岙山预应力混凝土连续箱梁截面进行了计算,并与Ansys结果进行比较,均证明采用本文的计算方法能得到满意的结果,且该方法适用于各种形状的截面形式.     

结构能度可靠性方法研究

结构系统可靠性研究分随机模型、模糊模型和非概率模型.本文分析了传统随机模型的局限性,利用蒙特卡诺的基本思想.提出了一种新的基于区间分析的模糊可靠性度量体系及分析方法.从物理、几何等方面解释了文中理论的合理性.该方法确定的失效可能度综合了更多的结构有用信息,能够反映结构的实际可靠状态.最后还提出了基于本文可靠性度量方法的结构优化设计模型,通过实例介绍了该方法的具体应用.     

多缝道复杂外形粘性绕流计算

使用雷诺平均NS方程、采用Johnson-King紊流模型、嵌套网格和有限体积法研究大迎角下的多缝道的多段翼型绕流。利用嵌合体技术对组合每一部分生成高质量并适于高效求解的贴体网格;将J－K模型发展应用于计算缝道流动以及具有边界层、尾迹流交汇的复杂流动。以具有17％相对厚度的GAW－1翼型带30％襟翼翼型及一个三段翼型为例进行了计算,计算结果与实验结果吻合很好,证实该方法可以较好地预示多段翼型上的粘性绕流、多缝道流动与最大升力。     

用子动力学理论研究介观体系的输运——电导响应函数的计算

从子动力学理论出发,计算了介观体系的输运公式,得到了包含高阶修正的Kubo公式,这对于任意外场的作用下的介观体系具有重要的意义。     

血流动力学数值模拟与动脉粥样硬化研究进展

血流动力学因素被认为与动脉粥样硬化等病理改变密切相关。目前血流动力学数值模拟的对象,主要集中于分支动脉、弯曲动脉以及因血管内膜增生而导致的局部狭窄动脉,这些都是动脉粥样硬化多发的病灶部位。精确的血流动力学数值模拟,必须依赖于解剖精确的血管几何模型和生理真实的血流与管壁有限变形的非线性瞬态流－固耦合。只有在“虚拟血液流动”的基础上,综合考虑血管内的壁面剪应力、粒子滞留时间和氧气的跨血管壁传输等多种因素,血流动力学的数值模拟才能真正有助于人们理解动脉粥样硬化的血流动力学机理,才有可能应用于有关动脉疾病的外科手术规划中。      

Existential theorem of conserved quantities and its inverse for the dynamics of nonholonomic relativistic systems

We present a general approach to the construction of conservation laws for the dynamics of nonholonomic relativistic systems.Firstly,we give the definition of integrating factors for the differential equations of motion of a mechanical system.Next,the necessary conditions for the existemce of the conserved quantities are studied in detail.Then,we establish the existential theorem for the conserved quantities and its inverse for the equations of motion of a nonholonomic relativistic system.Finally,an exampled is given to illustrate the application of the result.