二元混合染料在SiO2凝胶膜中的发光光谱

在SiO2凝胶材料中掺杂香豆素102和若丹明6G混合染料后,二元染料之间存在着能量传递,其发光光谱比单一染料的光谱展宽.前者在SiO2凝胶基质中可调谐范围展宽到120 nm,混合染料在SiO2凝胶基质中发光光谱展宽,并且具有更高的能量转移效率.     

关于一类向量场的Picone恒等式和Hardy不等式1

本文给出了构成Baouendi-Grushin算子 的向量场的Picone恒 式,由此导出了Hardy不等式.已有文献中得到的不等式成为本文结果的特殊情形。     

超声波显像管振动清洗机的研制

本文介绍一种无需任何清洗液且有别于常规超声波清洗机理的超声波显像管振动清洗机。从理论上分析说明超声波干振动清洗的机理和方法，阐明各超声参量的选取标准和超声振动系统中应注意的问题。     

ICF中子示波管的实验研究

 介绍了一个旨在将高时间分辨率和高探测灵敏度相结合、用于惯性约束聚变（ICF）研究的时间分辨的中子诊断技术的中子示波管，初步实验获得了技术时间分辨约40ps,可探测中子总产额10⁸。     

齐次群上二阶半线性偏微分方程的一类Picone型恒等式和Sturmian比较定理

本文给出了齐次群上的一类广义Picone型恒等式,由此证明了以下半线性方程组(其中 表示齐次群上的广义梯度)的Sturmian比较定理及一类振荡定理,并用于Heisenberg群上一类半线性方程.然后利用这里的广义Picone型恒等式证明了Heisenberg群上一类更一般的Hardv型不等式     

Two New Lignans from Taxus yunnanensis

The phytochemical investigation on the ethanolic extracts of the barks of Taxus yunnanensis (Taxaceae) led to the isolation of two new neo-lignans, named taxuyunins A (1) and B (2), along with the known diterpenolignan, brevitaxin (3). Their structures were elucidated on the basis of spectroscopic and chemical evidences. Compound 1 is a neo-lignan xyloside while compound 2 belongs to the rare neo-lignan possessing a ramified C3 side chain.     

不同路面激励下车内噪声预测与板件声学贡献量分析

利用有限元模拟计算的方法对不同路面激励下车内噪声进行了预测, 并分析了板件对声 学的贡献量. 使用MATLAB软件生成了B级和C级路面谱. 由NASTRAN软件计算 出车身结构在不同路面谱激励下1$\sim$200\,Hz的频率响应结果, 在LMS Virtual. Lab声学软件中, 根据声传递向量技术预测驾驶员和乘客耳旁声压级响应. 还探讨了 声腔结构表面阻抗特性对车内噪声的影响. 并针对C级路面谱激励, 通过车身各板件对 驾驶员右耳声压的面板贡献量分析, 找出了结构优化的重点区域, 为降低车内声压检测点噪 声进行相关的声学处理提供参考依据.     

电化学测试中溶液电阻的自动测量与补偿

由16位DAC器件作为分压器,设计了恒电位仪以及正反馈补偿电路,实现了对溶液电阻的自动测量和补偿,同时采用高阻抗体系对其溶液电阻测量的准确性和补偿效果进行了验证.结果表明,溶液电阻最高补偿值可达1.0×10(8)Ω,在可补偿电阻范围内,自动电阻测量误差最大不超过1.5%,平均误差小于0.5%.本实验设计的电路可以较精确...     

Determination of tebuconazole, trifloxystrobin and its metabolite in fruit and vegetables by a Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method using gas chromatography with a nitrogen-phosphorus detector and ion trap mass spectrometry

A new analytical method using QuEChERS procedure by gas chromatography with a nitrogen-phosphorus detector (GC-NPD) and ion trap mass spectrometry (GC-IT-MS) for the quantitative determination of tebuconazole, trifloxystrobin and its metabolite trifloxystrobin acid has been developed and validated. The analytes were extracted from five fruit and vegetable matrices using acetonitrile and subsequently cleaned up using primary secondary amine (PSA) or octadecylsilane (C18) as sorbent prior to GC analysis. The present methods provided sufficient sensitivity as reflected by the values of limit of detection (LOD) and limit of quantification (LOQ) of 0.4-7 and 1.2-20 μg/kg for GC-IT-MS/MS and GC-NPD. The recoveries were, on average, 68-117 and 68-121%, respectively, for three compounds by GC-NPD and GC-IT-MS/MS with intra-day precision achieved with an RSD of 2.7-19.1%. The inter-day precision was better than 15.1% as determined by GC-NPD. The QuEChERS procedure, by using two sorbents (PSA and C18) and the matrix-matched standards, gave satisfactory recoveries and RSD values in different matrices. IT-MS acquisition provided higher specificity and selectivity for pesticides and better limit of detection and quantification. However, the repeatability and precision of NPD method were better compared with IT-MS.     

Simultaneous enantioselective determination of fenbuconazole and its main metabolites in soil and water by chiral liquid chromatography/tandem mass spectrometry

A novel and sensitive method was developed for the simultaneous determination of fenbuconazole and its main metabolites enantioselectively using chiral liquid chromatography coupled with tandem mass spectrometry. The separation and determination were performed using reversed-phase chromatography on a cellulose chiral stationary phase, a Chiralcel OD-RH (150 mm×4.6 mm) column, under isocratic conditions at 0.5 mL/min flow rate. The effects of three cellulose-based columns and three amylose-based columns on the separation were also investigated. The elution orders of the eluting enantiomers were identified by an optical rotation detector. The QuEChERS (acronym for Quick, Easy, Cheap, Effective, Rugged and Safe) method and solid-phase extraction (SPE) were used for the extraction and clean-up of the soil and water samples, respectively. Parameters including the matrix effect, linearity, precision, accuracy and stability were evaluated. Under optimal conditions, the mean recoveries for all enantiomers from the soil samples were 82.5-104.1% with 2.7-9.5% intra-day relative standard deviations (RSD) and 5.7-11.2% inter-day RSD at 5, 25 and 50 μg/kg levels; the mean enantiomer recoveries from the water samples were 81.8-104.6% with 2.6-11.4% intra-day RSD and 5.3-10.4% inter-day RSD at 0.25, 0.5 and 2.5 μg/L levels. Coefficients of determination R2≥0.9991 were achieved for each enantiomer in the soil and water matrix calibration curves within the range of 1.0-125 μg/L. The limits of detection (LOD) for all enantiomers in the soil and water were less than 0.8 μg/kg, whereas the limit of quantification (LOQ) did not exceed 2.5 μg/kg. The results of the method validation confirm that this proposed method is convenient and reliable for the enantioselective determination of the enantiomers of fenbuconazole and its main metabolites in soil and water.