天麻的化学研究Ⅱ.天麻苷及其类似物的合成

本文报告以溴代2',3',4',6'-四乙酰-α-D-吡喃葡萄糖及对羟基苯甲醛为原料合成天麻苷(1),按溴代四乙酰葡萄糖计算,总产率24%.还合成了天麻苷的类似物:2-甲氧基-4-羟甲苯基-β-D-吡喃葡萄糖苷(2),2-甲氧基-4-甲酰苯基-β-D-吡喃葡萄糖苷(3)及4-甲酰苯基-β-D-吡喃葡萄糖苷(4).合成天麻苷与天然天麻苷的熔点、红外光谱、核磁共振谱完全一致,药理作用也完全一致.     

γ辐照 聚全氟乙丙烯(F46)的电子自旋共振研究 I.真空中俘获自由基的定量研究

A method for determining respectively the concentration of free radicials...CF2-CF2.(RI), ...CF2-CF-CF2...(RII)and...CF2- C(CF3)-CF2...(RIII) trapped in γ-irradiated F46 in vacuum at room temperature by analysing the ESR overlapping spectra is proposed. A quantitative relation between the concentration of free readicals and the total dose of γ-irradiation has been studied. The generating rate o free radicals caused by irradiation, i.e. G-value, has been calculated; it is 2.0 for RIII, 1.2 for RI, and 0.59 for RII. the magnitude of G value of free radicals is in the reverse order of their stability. Hence, we assume that the G value of free radicals in F46 mainly depends on the escaping rate of F2 and other fluorine-containing small molecules from surface of polymer into space. Therefore the looser the molecular chain, the larger becomes the G value of free radical. From that, we consider that both unstable free radicals RIII and RI with larger G-value mainly locate in the amorphous region, and the stable free radical RII with lower G-value is in the crystalline region. Recombinations between free radicals RII and RIII, or between RII and RI are forbidden at the temperature lower than 80C. An explanation for the saturation phenomenon of concentration of free radicals is given.     

THE MEASUREMENT OF THE EXCITATION FUNCTIONS OF ISOTOPES OF Fr AND At,PRODUCED IN THE BOMBARDMENT OF 12C ON 209Bi

Excitation functions for Fr and At isotopes produced in ¹²C on ²⁰⁹Bi had been measured in the energy range 60—72 MeV. It was quite obvious that ²¹³Fr and ²¹⁴Fr were formed by the reactions ²⁰⁹Bi (¹²C,4n) ²¹⁷Ac and ²⁰⁹Bi (¹²C,3n) ²¹⁸Ac following the a decay of the Ac isotopes respectively, and ^214mFr was produced probably by compound nucleus evaporation of neutrons and an α particle, i.e. (¹²C, α 3n). ²¹¹At was mainly contributed by a multi-nucleon transfer reaction （e.g. ⁸Be transfer）. The experimental data for neutron evaporation reaction were fitted by the Jackson formula.     

LaⅡ5d~(21)G_4→4f5d~1F_3超精细结构光谱测量

利用少有的共线快离子激光光谱学方法研究了LaⅡ的超精细结构 ,测量了 5d2 1G4 态→ 4f5d1F3 态的超精细结构光谱 ,分别得出了相应的磁偶极矩和电四极矩的超精细相互作用常数 .     

ChemInform Abstract: Binding of Nitric Oxide to First-Transition-Row Metal Cations: An ab initio Study

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

开发趣味实验 培养创新能力

在化学教学中,我们本着为学生未来着想的宗旨,以趣味化学实验为突破口,对学生的创新能力进行培养,收到了良好的效果。     

离子型共聚单体参与下的全氟丙烯酸酯无皂乳液共聚

离子型共聚单体参与下的全氟丙烯酸酯无皂乳液共聚;全氟烷基丙烯酸酯;无皂乳液;离子型共聚单体     

激光柱形腔靶的X射线温度和X射线转换效率

本文根据实验和数值模拟给出的信息,解析研究激光加热柱形腔靶(简称“腔靶”)X射线温度与激光转换的X射线能之间的定标规律,推断了1989年在神光激光器上做的系列腔靶实验,对于每束激光能量为300—500J,脉冲宽度为0.7—1.0ns,波长λ为1.06μm的高斯型激光源,双束靶的X射线转换效率约为(50—55)%,X射线温度为(1.5—1.7)×10⁶K。 关键词：     

高温超导磁悬浮系统中横向运动对悬浮力和导向力影响的研究

高温超导磁悬浮列车在运行过程中，导轨磁场的不连续或者机电耦合会引起车身的横向偏移．针对这一实际问题，本文研究了横向运动对竖直悬浮力和水平导向力的影响．实验中系统同时测试横向运动过程中不断变化悬浮力和导向力．研究发现运动过程中的悬浮力衰减与最大横向偏移量和往返运动次数有关；但导向力在第一次往返运动之后的往返运动中迟滞曲线基本不变．该工作可能为高温超导磁悬浮列车系统提供一定科学依据．     

两个不同服务台的可修排队系统的矩阵几何解

本文研究了具有不同服务率的两服务台排队系统,其中服务台1完全可靠,服务台2可能发生故障.通过拟生灭过程的方法求出了.系统稳态平衡条件和稳态概率向量的矩阵几何解,并给出了系统的一些性能指标和数值结果.